Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction

Bibliographic Details
Main Author: Campos, Ana M. F. Oliveira
Publication Date: 2003
Other Authors: Carvalho, Luís H. Melo de, Silva, Artur M. S., Martins, Cristina I., Coelho, Paulo J.
Format: Article
Language: eng
Source: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Download full: http://hdl.handle.net/1822/2256
Summary: The structure of the intensely coloured red product obtained through the reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol was reinvestigated. Instead of the expected permanent open form of the naphthopyran, the dye presents the alpha,beta-unsaturated chain at a different position of the naphthalene nucleus. The structure of this compound was elucidated on the basis of detailed spectral analysis, including 2D NMR experiments.
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spelling Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correctionNaphthopyrans1,8-naphthalenediolDyeHydrogen-bondScience & TechnologyThe structure of the intensely coloured red product obtained through the reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol was reinvestigated. Instead of the expected permanent open form of the naphthopyran, the dye presents the alpha,beta-unsaturated chain at a different position of the naphthalene nucleus. The structure of this compound was elucidated on the basis of detailed spectral analysis, including 2D NMR experiments.Fundação para a Ciência e Tecnologia - PRAXIS XXI/P/QUI/10021/1998.ElsevierUniversidade do MinhoCampos, Ana M. F. OliveiraCarvalho, Luís H. Melo deSilva, Artur M. S.Martins, Cristina I.Coelho, Paulo J.20032003-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/2256eng"Tetrahedron letters". 44 (2003) 1903-1905.0040-403910.1016/S0040-4039(03)00118-7info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:07:36Zoai:repositorium.sdum.uminho.pt:1822/2256Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:58:37.199958Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
title Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
spellingShingle Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
Campos, Ana M. F. Oliveira
Naphthopyrans
1,8-naphthalenediol
Dye
Hydrogen-bond
Science & Technology
title_short Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
title_full Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
title_fullStr Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
title_full_unstemmed Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
title_sort Structural elucidation of the red dye obtained from reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol : a correction
author Campos, Ana M. F. Oliveira
author_facet Campos, Ana M. F. Oliveira
Carvalho, Luís H. Melo de
Silva, Artur M. S.
Martins, Cristina I.
Coelho, Paulo J.
author_role author
author2 Carvalho, Luís H. Melo de
Silva, Artur M. S.
Martins, Cristina I.
Coelho, Paulo J.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Campos, Ana M. F. Oliveira
Carvalho, Luís H. Melo de
Silva, Artur M. S.
Martins, Cristina I.
Coelho, Paulo J.
dc.subject.por.fl_str_mv Naphthopyrans
1,8-naphthalenediol
Dye
Hydrogen-bond
Science & Technology
topic Naphthopyrans
1,8-naphthalenediol
Dye
Hydrogen-bond
Science & Technology
description The structure of the intensely coloured red product obtained through the reaction of 1,8-naphthalenediol with 1,1-diphenylprop-2-yn-1-ol was reinvestigated. Instead of the expected permanent open form of the naphthopyran, the dye presents the alpha,beta-unsaturated chain at a different position of the naphthalene nucleus. The structure of this compound was elucidated on the basis of detailed spectral analysis, including 2D NMR experiments.
publishDate 2003
dc.date.none.fl_str_mv 2003
2003-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/2256
url http://hdl.handle.net/1822/2256
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv "Tetrahedron letters". 44 (2003) 1903-1905.
0040-4039
10.1016/S0040-4039(03)00118-7
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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