Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/1822/35262 |
Resumo: | Polyester (PES) has been coated with polypyrrole (PPy) to produce conducting fabrics. Graphene oxide (GO) has been used in different concentrations (10, 20 and 30% weight) as counter ion to neutralize the positive charges of the PPy structure. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) of the PPy/GO powders corroborated the incorporation of GO as counter ion due to the presence of O in the EDX spectrum, as well as an excess of C, arising from GO contribution. The doping level (N+/N) decreased with the GO content. Field emission scanning electron microscopy (FESEM) showed the formation of the PPy/GO coating and the incorporation of GO in the composite. Electrochemical impedance spectroscopy (EIS) in solid state and solution, cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to test the electrical properties and electroactivity of the fabrics. There was a decrease in the electrical properties and electroactivity as the GO content increased. The conductivity of the fabrics could be tuned by varying the GO content. |
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Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxidePolypyrroleGraphene oxideConducting fabricX-ray photoelectron spectroscopy (XPS)Electrochemical impedance spectroscopy (EIS)Scanning electrochemical microscopy (SECM)Engenharia e Tecnologia::Engenharia dos MateriaisScience & TechnologyPolyester (PES) has been coated with polypyrrole (PPy) to produce conducting fabrics. Graphene oxide (GO) has been used in different concentrations (10, 20 and 30% weight) as counter ion to neutralize the positive charges of the PPy structure. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) of the PPy/GO powders corroborated the incorporation of GO as counter ion due to the presence of O in the EDX spectrum, as well as an excess of C, arising from GO contribution. The doping level (N+/N) decreased with the GO content. Field emission scanning electron microscopy (FESEM) showed the formation of the PPy/GO coating and the incorporation of GO in the composite. Electrochemical impedance spectroscopy (EIS) in solid state and solution, cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to test the electrical properties and electroactivity of the fabrics. There was a decrease in the electrical properties and electroactivity as the GO content increased. The conductivity of the fabrics could be tuned by varying the GO content.Spanish Ministerio de Ciencia e Innovación (contract CTM2011-23583) for the financial support. Conselleria d'Educació, Formació i Ocupació (Generalitat Valenciana) for the Programa VALi+D Postdoctoral Fellowship. C2011-UMINHO-2C2T-01 FCT funding from Programa Compromisso para a Ciência 2008, Portugal. XPS studies were performed at CEMUP (University of Porto, Portugal) facilities. Electron Microscopy Service of the UPV (Universitat Politècnica de València) is gratefully acknowledged for help with FESEM and EDX characterization.ElsevierUniversidade do MinhoMolina, J.Zille, AndreaFernández, J.Souto, A. PedroBonastre, J.Cases, F.2015-062015-06-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/35262engMolina J, Zille A, Fernández J, Souto AP, Bonastre J, Cases F (2015) Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide. Synthetic Metals. 204:110-1210379-677910.1016/j.synthmet.2015.03.014http://www.sciencedirect.com/science/article/pii/S0379677915001216info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:54:26ZPortal AgregadorONG |
dc.title.none.fl_str_mv |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
title |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
spellingShingle |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide Molina, J. Polypyrrole Graphene oxide Conducting fabric X-ray photoelectron spectroscopy (XPS) Electrochemical impedance spectroscopy (EIS) Scanning electrochemical microscopy (SECM) Engenharia e Tecnologia::Engenharia dos Materiais Science & Technology |
title_short |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
title_full |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
title_fullStr |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
title_full_unstemmed |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
title_sort |
Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide |
author |
Molina, J. |
author_facet |
Molina, J. Zille, Andrea Fernández, J. Souto, A. Pedro Bonastre, J. Cases, F. |
author_role |
author |
author2 |
Zille, Andrea Fernández, J. Souto, A. Pedro Bonastre, J. Cases, F. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Molina, J. Zille, Andrea Fernández, J. Souto, A. Pedro Bonastre, J. Cases, F. |
dc.subject.por.fl_str_mv |
Polypyrrole Graphene oxide Conducting fabric X-ray photoelectron spectroscopy (XPS) Electrochemical impedance spectroscopy (EIS) Scanning electrochemical microscopy (SECM) Engenharia e Tecnologia::Engenharia dos Materiais Science & Technology |
topic |
Polypyrrole Graphene oxide Conducting fabric X-ray photoelectron spectroscopy (XPS) Electrochemical impedance spectroscopy (EIS) Scanning electrochemical microscopy (SECM) Engenharia e Tecnologia::Engenharia dos Materiais Science & Technology |
description |
Polyester (PES) has been coated with polypyrrole (PPy) to produce conducting fabrics. Graphene oxide (GO) has been used in different concentrations (10, 20 and 30% weight) as counter ion to neutralize the positive charges of the PPy structure. Fourier transform infrared spectroscopy with attenuated total reflection (FTIR-ATR), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) of the PPy/GO powders corroborated the incorporation of GO as counter ion due to the presence of O in the EDX spectrum, as well as an excess of C, arising from GO contribution. The doping level (N+/N) decreased with the GO content. Field emission scanning electron microscopy (FESEM) showed the formation of the PPy/GO coating and the incorporation of GO in the composite. Electrochemical impedance spectroscopy (EIS) in solid state and solution, cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to test the electrical properties and electroactivity of the fabrics. There was a decrease in the electrical properties and electroactivity as the GO content increased. The conductivity of the fabrics could be tuned by varying the GO content. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-06 2015-06-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1822/35262 |
url |
http://hdl.handle.net/1822/35262 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Molina J, Zille A, Fernández J, Souto AP, Bonastre J, Cases F (2015) Conducting fabrics of polyester coated with polypyrrole and doped with graphene oxide. Synthetic Metals. 204:110-121 0379-6779 10.1016/j.synthmet.2015.03.014 http://www.sciencedirect.com/science/article/pii/S0379677915001216 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
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repository.mail.fl_str_mv |
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1777303873071874048 |