Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2009 |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10284/3294 |
Resumo: | Inductive effects account for 1/3 of the enhanced acidity of phenol versus cyclohexanol, 2/5 of the enhanced acidity of enol versus methanol, and l/4 of the enhanced acidity of carbonyl α-hydrogens versus methane. |
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Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogensInductive effects account for 1/3 of the enhanced acidity of phenol versus cyclohexanol, 2/5 of the enhanced acidity of enol versus methanol, and l/4 of the enhanced acidity of carbonyl α-hydrogens versus methane.American Chemical SocietyRepositório Institucional da Universidade Fernando PessoaSilva, Pedro J.2012-08-02T15:01:34Z2009-01-01T00:00:00Z2009-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10284/3294engSilva, Pedro Jorge (2009). Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens. The Journal of Organic Chemistry, 74 (2), 914-916. DOI: 10.1021/jo8018736. ISSN 1520-6904.1520-6904info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-06T02:02:36Zoai:bdigital.ufp.pt:10284/3294Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:40:12.050885Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| title |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| spellingShingle |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens Silva, Pedro J. |
| title_short |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| title_full |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| title_fullStr |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| title_full_unstemmed |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| title_sort |
Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens |
| author |
Silva, Pedro J. |
| author_facet |
Silva, Pedro J. |
| author_role |
author |
| dc.contributor.none.fl_str_mv |
Repositório Institucional da Universidade Fernando Pessoa |
| dc.contributor.author.fl_str_mv |
Silva, Pedro J. |
| description |
Inductive effects account for 1/3 of the enhanced acidity of phenol versus cyclohexanol, 2/5 of the enhanced acidity of enol versus methanol, and l/4 of the enhanced acidity of carbonyl α-hydrogens versus methane. |
| publishDate |
2009 |
| dc.date.none.fl_str_mv |
2009-01-01T00:00:00Z 2009-01-01T00:00:00Z 2012-08-02T15:01:34Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10284/3294 |
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http://hdl.handle.net/10284/3294 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.none.fl_str_mv |
Silva, Pedro Jorge (2009). Inductive and resonance effects on the acidities of phenol, enols, and carbonyl r-hydrogens. The Journal of Organic Chemistry, 74 (2), 914-916. DOI: 10.1021/jo8018736. ISSN 1520-6904. 1520-6904 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
| dc.publisher.none.fl_str_mv |
American Chemical Society |
| publisher.none.fl_str_mv |
American Chemical Society |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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