Semiconductive properties of anodic niobium oxides

• Autor(a) principal: Sá,A.I. de
• Data de Publicação: 2006
• Outros Autores: Rangel,C.M., Skeldon,P., Thompson,G.E.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042006000200012
• topic: niobium oxides; anodic oxides; Mott-Schottky behaviour

The semiconductive properties of anodic niobium oxides formed at constant potential and constant current density to different final voltages have been examined by Mott-Schottky analysis. Thin anodic oxides were formed on sputtered niobium specimens at constant potential in the range of 2.5 to 10 V Ag/AgCl in a borate buffer solution. Thicker oxides were formed, also on sputtered niobium specimens, at a constant current density of 5 mA cm-2 in 0.1 M ammonium pentaborate solution to final voltages of 10, 50 and 100 V. Capacitance measurements were performed in a borate buffer solution of pH 8.8, at a frequency range of 200 to 2000 Hz, at a sweep rate of 5 mV s-1 from +2.5 to -1 V Ag/AgCl. The results obtained show n-type semiconductor behaviour with a carrier density in the range of 8 ´ 10(18) - 6 ´ 10(19) cm-3 on films formed to 10 V. Thicker films showed lower carrier densities in the range of 1 ´ 10(18) - 2 ´ 10(18) cm-3 with a calculated charge depletion layer of 33-36 nm.