Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate

Detalhes bibliográficos
Autor(a) principal: Yang, Ting-Hai
Data de Publicação: 2013
Outros Autores: Han, Yin-Feng, Shi, Fa-Nian
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/19566
Resumo: A novel complex, Zn-2(Hpdc)(2)(Ox)(H2O)(4)] (H(2)pdc = pyridine-2,5-dicarboxylic acid, Ox = oxalate), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. Crystal structure analysis reveals that the compound crystallizes in monoclinic space group P2(1)/n, features an interesting 3D-supramolecular network via hydrogen bonding and pi-pi stacking interactions. Cell unit parameter for the compound: a = 10.2152(3) angstrom, b = 9.6535(3) angstrom, c = 10.3594(2) angstrom, beta = 105.664 degrees, V = 983.63(5) angstrom(3), Z = 2, M-r = 623.05, D-c = 2.104 g/cm(3), mu = 2.536 mm(-1), F-(000) = 628, T = 150(2) K, R = 0.0356, wR = 0.0612 for 2510 reflections with I > 2 sigma(I).
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spelling Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and OxalateLANTHANIDE COORDINATION POLYMERSHYDROTHERMAL SYNTHESISLUMINESCENCEACIDPRTBEUA novel complex, Zn-2(Hpdc)(2)(Ox)(H2O)(4)] (H(2)pdc = pyridine-2,5-dicarboxylic acid, Ox = oxalate), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. Crystal structure analysis reveals that the compound crystallizes in monoclinic space group P2(1)/n, features an interesting 3D-supramolecular network via hydrogen bonding and pi-pi stacking interactions. Cell unit parameter for the compound: a = 10.2152(3) angstrom, b = 9.6535(3) angstrom, c = 10.3594(2) angstrom, beta = 105.664 degrees, V = 983.63(5) angstrom(3), Z = 2, M-r = 623.05, D-c = 2.104 g/cm(3), mu = 2.536 mm(-1), F-(000) = 628, T = 150(2) K, R = 0.0356, wR = 0.0612 for 2510 reflections with I > 2 sigma(I).ASIAN JOURNAL OF CHEMISTRY2017-12-07T19:17:04Z2013-01-01T00:00:00Z2013info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/19566eng0970-707710.14233/ajchem.2013.14925Yang, Ting-HaiHan, Yin-FengShi, Fa-Nianinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-17T03:49:28ZPortal AgregadorONG
dc.title.none.fl_str_mv Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
title Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
spellingShingle Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
Yang, Ting-Hai
LANTHANIDE COORDINATION POLYMERS
HYDROTHERMAL SYNTHESIS
LUMINESCENCE
ACID
PR
TB
EU
title_short Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
title_full Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
title_fullStr Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
title_full_unstemmed Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
title_sort Synthesis and Crystal Structure of 3D-Superamolecular Zinc Complex Derived from Pyridine-2,5-dicarboxylate and Oxalate
author Yang, Ting-Hai
author_facet Yang, Ting-Hai
Han, Yin-Feng
Shi, Fa-Nian
author_role author
author2 Han, Yin-Feng
Shi, Fa-Nian
author2_role author
author
dc.contributor.author.fl_str_mv Yang, Ting-Hai
Han, Yin-Feng
Shi, Fa-Nian
dc.subject.por.fl_str_mv LANTHANIDE COORDINATION POLYMERS
HYDROTHERMAL SYNTHESIS
LUMINESCENCE
ACID
PR
TB
EU
topic LANTHANIDE COORDINATION POLYMERS
HYDROTHERMAL SYNTHESIS
LUMINESCENCE
ACID
PR
TB
EU
description A novel complex, Zn-2(Hpdc)(2)(Ox)(H2O)(4)] (H(2)pdc = pyridine-2,5-dicarboxylic acid, Ox = oxalate), has been hydrothermally synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction. Crystal structure analysis reveals that the compound crystallizes in monoclinic space group P2(1)/n, features an interesting 3D-supramolecular network via hydrogen bonding and pi-pi stacking interactions. Cell unit parameter for the compound: a = 10.2152(3) angstrom, b = 9.6535(3) angstrom, c = 10.3594(2) angstrom, beta = 105.664 degrees, V = 983.63(5) angstrom(3), Z = 2, M-r = 623.05, D-c = 2.104 g/cm(3), mu = 2.536 mm(-1), F-(000) = 628, T = 150(2) K, R = 0.0356, wR = 0.0612 for 2510 reflections with I > 2 sigma(I).
publishDate 2013
dc.date.none.fl_str_mv 2013-01-01T00:00:00Z
2013
2017-12-07T19:17:04Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/19566
url http://hdl.handle.net/10773/19566
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0970-7077
10.14233/ajchem.2013.14925
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ASIAN JOURNAL OF CHEMISTRY
publisher.none.fl_str_mv ASIAN JOURNAL OF CHEMISTRY
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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