Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis

Detalhes bibliográficos
Autor(a) principal: Brett, Christopher M. A.
Data de Publicação: 1999
Outros Autores: Fungaro, Denise A., Morgado, José M., Gil, M. Helena
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/5262
https://doi.org/10.1016/S0022-0728(99)00061-3
Resumo: Various polymer coatings have been investigated for the protection of mercury thin-film electrodes in the square wave anodic stripping voltammetry of environmental samples using batch injection analysis, with injection of untreated samples of volume 50 [mu]l directly over the sensing electrode. Polymer coatings studied include those with controlled porosity, and cation-exchange polymers based on sulphonated polymers. Of the polymers tested, films of ca. 1 [mu]m thickness made from Nafion® mixed with 5% poly(vinyl sulphonic acid) were found to give the best results in tests with the model surfactants Triton-X-100 detergent, sodium dodecyl sulphate and protein standard. The validity of the approach is demonstrated by application to real samples.
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spelling Novel polymer-modified electrodes for batch injection sensors and application to environmental analysisAnodic stripping voltammetryPolymer-coated electrodesBatch injection analysisEnvironmental electroanalysisVarious polymer coatings have been investigated for the protection of mercury thin-film electrodes in the square wave anodic stripping voltammetry of environmental samples using batch injection analysis, with injection of untreated samples of volume 50 [mu]l directly over the sensing electrode. Polymer coatings studied include those with controlled porosity, and cation-exchange polymers based on sulphonated polymers. Of the polymers tested, films of ca. 1 [mu]m thickness made from Nafion® mixed with 5% poly(vinyl sulphonic acid) were found to give the best results in tests with the model surfactants Triton-X-100 detergent, sodium dodecyl sulphate and protein standard. The validity of the approach is demonstrated by application to real samples.http://www.sciencedirect.com/science/article/B6TGB-3WS69WY-1G/1/482035fd36bbbdaace32d2213fe935291999info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5262http://hdl.handle.net/10316/5262https://doi.org/10.1016/S0022-0728(99)00061-3engJournal of Electroanalytical Chemistry. 468:1 (1999) 26-33Brett, Christopher M. A.Fungaro, Denise A.Morgado, José M.Gil, M. Helenainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-11-06T16:59:31Zoai:estudogeral.uc.pt:10316/5262Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:23.510362Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
title Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
spellingShingle Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
Brett, Christopher M. A.
Anodic stripping voltammetry
Polymer-coated electrodes
Batch injection analysis
Environmental electroanalysis
title_short Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
title_full Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
title_fullStr Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
title_full_unstemmed Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
title_sort Novel polymer-modified electrodes for batch injection sensors and application to environmental analysis
author Brett, Christopher M. A.
author_facet Brett, Christopher M. A.
Fungaro, Denise A.
Morgado, José M.
Gil, M. Helena
author_role author
author2 Fungaro, Denise A.
Morgado, José M.
Gil, M. Helena
author2_role author
author
author
dc.contributor.author.fl_str_mv Brett, Christopher M. A.
Fungaro, Denise A.
Morgado, José M.
Gil, M. Helena
dc.subject.por.fl_str_mv Anodic stripping voltammetry
Polymer-coated electrodes
Batch injection analysis
Environmental electroanalysis
topic Anodic stripping voltammetry
Polymer-coated electrodes
Batch injection analysis
Environmental electroanalysis
description Various polymer coatings have been investigated for the protection of mercury thin-film electrodes in the square wave anodic stripping voltammetry of environmental samples using batch injection analysis, with injection of untreated samples of volume 50 [mu]l directly over the sensing electrode. Polymer coatings studied include those with controlled porosity, and cation-exchange polymers based on sulphonated polymers. Of the polymers tested, films of ca. 1 [mu]m thickness made from Nafion® mixed with 5% poly(vinyl sulphonic acid) were found to give the best results in tests with the model surfactants Triton-X-100 detergent, sodium dodecyl sulphate and protein standard. The validity of the approach is demonstrated by application to real samples.
publishDate 1999
dc.date.none.fl_str_mv 1999
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/5262
http://hdl.handle.net/10316/5262
https://doi.org/10.1016/S0022-0728(99)00061-3
url http://hdl.handle.net/10316/5262
https://doi.org/10.1016/S0022-0728(99)00061-3
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Electroanalytical Chemistry. 468:1 (1999) 26-33
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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