Photochemistry and photophysics of thienocarbazoles
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10198/816 |
Resumo: | Two methylated thienocarbazoles and two of their synthetic nitro-precursors have been examined by absorption, luminescence, laser flash photolysis and photoacoustic techniques. Their spectroscopic and photophysical characterization involves fluorescence spectra, fluorescence quantum yields and lifetimes, and phosphorescence spectra and phosphorescence lifetimes for all the compounds. Triplet–singlet difference absorption spectra, triplet molar absorption coefficients, triplet lifetimes, intersystem crossing S1 ~~→T1 and singlet molecular oxygen yields were obtained for the thienocarbazoles. In the case of the thienocarbazoles it was found that the lowest-lying singlet and triplet excited states, S1 and T1, are of ╥, ╥* origin, whereas for their precursors S1 is n,╥*, and T1 is ╥, ╥*. In both thienocarbazoles it appears that the thianaphthene ring dictates the S1 ~~→T1 yield, albeit there is less predominance of that ring in the triplet state of the linear thienocarbazole, which leads to a decrease in the observed /T value |
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Photochemistry and photophysics of thienocarbazolesTwo methylated thienocarbazoles and two of their synthetic nitro-precursors have been examined by absorption, luminescence, laser flash photolysis and photoacoustic techniques. Their spectroscopic and photophysical characterization involves fluorescence spectra, fluorescence quantum yields and lifetimes, and phosphorescence spectra and phosphorescence lifetimes for all the compounds. Triplet–singlet difference absorption spectra, triplet molar absorption coefficients, triplet lifetimes, intersystem crossing S1 ~~→T1 and singlet molecular oxygen yields were obtained for the thienocarbazoles. In the case of the thienocarbazoles it was found that the lowest-lying singlet and triplet excited states, S1 and T1, are of ╥, ╥* origin, whereas for their precursors S1 is n,╥*, and T1 is ╥, ╥*. In both thienocarbazoles it appears that the thianaphthene ring dictates the S1 ~~→T1 yield, albeit there is less predominance of that ring in the triplet state of the linear thienocarbazole, which leads to a decrease in the observed /T valueWiley IntersicenceBiblioteca Digital do IPBMelo, J. Seixas deRodrigues, L.M.Serpa, C.Arnaut, L.G.Ferreira, Isabel C.F.R.Queiroz, Maria João R.P.2008-09-12T11:11:10Z20032003-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/816engMelo, J. Seixas de; Rodrigues, L.M.; Serpa, C.; Arnaut, L.G.; Ferreira, Isabel C.F.R.; Queiroz, Maria João R.P. (2003). Photochemistry and photophysics of thienocarbazoles. Photochemistry and Photobiology. ISSN 1751-1097. p. 121-1281751-109710.1562/0031-8655(2003)0770121PAPOT2.0.CO2info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-06-21T01:18:19ZPortal AgregadorONG |
dc.title.none.fl_str_mv |
Photochemistry and photophysics of thienocarbazoles |
title |
Photochemistry and photophysics of thienocarbazoles |
spellingShingle |
Photochemistry and photophysics of thienocarbazoles Melo, J. Seixas de |
title_short |
Photochemistry and photophysics of thienocarbazoles |
title_full |
Photochemistry and photophysics of thienocarbazoles |
title_fullStr |
Photochemistry and photophysics of thienocarbazoles |
title_full_unstemmed |
Photochemistry and photophysics of thienocarbazoles |
title_sort |
Photochemistry and photophysics of thienocarbazoles |
author |
Melo, J. Seixas de |
author_facet |
Melo, J. Seixas de Rodrigues, L.M. Serpa, C. Arnaut, L.G. Ferreira, Isabel C.F.R. Queiroz, Maria João R.P. |
author_role |
author |
author2 |
Rodrigues, L.M. Serpa, C. Arnaut, L.G. Ferreira, Isabel C.F.R. Queiroz, Maria João R.P. |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Biblioteca Digital do IPB |
dc.contributor.author.fl_str_mv |
Melo, J. Seixas de Rodrigues, L.M. Serpa, C. Arnaut, L.G. Ferreira, Isabel C.F.R. Queiroz, Maria João R.P. |
description |
Two methylated thienocarbazoles and two of their synthetic nitro-precursors have been examined by absorption, luminescence, laser flash photolysis and photoacoustic techniques. Their spectroscopic and photophysical characterization involves fluorescence spectra, fluorescence quantum yields and lifetimes, and phosphorescence spectra and phosphorescence lifetimes for all the compounds. Triplet–singlet difference absorption spectra, triplet molar absorption coefficients, triplet lifetimes, intersystem crossing S1 ~~→T1 and singlet molecular oxygen yields were obtained for the thienocarbazoles. In the case of the thienocarbazoles it was found that the lowest-lying singlet and triplet excited states, S1 and T1, are of ╥, ╥* origin, whereas for their precursors S1 is n,╥*, and T1 is ╥, ╥*. In both thienocarbazoles it appears that the thianaphthene ring dictates the S1 ~~→T1 yield, albeit there is less predominance of that ring in the triplet state of the linear thienocarbazole, which leads to a decrease in the observed /T value |
publishDate |
2003 |
dc.date.none.fl_str_mv |
2003 2003-01-01T00:00:00Z 2008-09-12T11:11:10Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10198/816 |
url |
http://hdl.handle.net/10198/816 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Melo, J. Seixas de; Rodrigues, L.M.; Serpa, C.; Arnaut, L.G.; Ferreira, Isabel C.F.R.; Queiroz, Maria João R.P. (2003). Photochemistry and photophysics of thienocarbazoles. Photochemistry and Photobiology. ISSN 1751-1097. p. 121-128 1751-1097 10.1562/0031-8655(2003)0770121PAPOT2.0.CO2 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Wiley Intersicence |
publisher.none.fl_str_mv |
Wiley Intersicence |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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1777301782941138944 |