Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.9/4240 |
Resumo: | ABSTRACT: Exhausted olive pomace (EOP) is a residual biomass from which hydroxytyrosol can be recovered. This compound has applications in the food/pharma sectors, but its extraction yields complex extracts that require further purification for some applications. This work explores purification strategies based on membrane technology, liquid–liquid extraction (LLE), and solid-phase extraction with adsorbents and resins. The hydroxytyrosol content, phenolic profile, antioxidant activity, and inhibition of α-glucosidase and α-amylase were monitored. Hydroxytyrosol stood out in all purified extracts. The best hydroxytyrosol recovery (88.8%) was achieved using LLE with ethyl acetate as the extractant, while the purest extracts in phenolic compounds, including hydroxytyrosol, were obtained using the latter solvent and C18 (529 mg/g), DSC-8 (873 mg/g), and Purosorb PAD910 (523 mg/g). Conversely, mannitol and glucose, at high concentrations in the extract, were selectively retained in the aqueous phases. The developed strategies are discussed regarding their suitability to provide hydroxytyrosol-concentrated extracts, up to 291 mg/g, with antioxidant and antidiabetic functionalities. |
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Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomaceAdsorptionAntidiabeticHydroxytyrosolLiquid-liquid extractionMembrane purificationABSTRACT: Exhausted olive pomace (EOP) is a residual biomass from which hydroxytyrosol can be recovered. This compound has applications in the food/pharma sectors, but its extraction yields complex extracts that require further purification for some applications. This work explores purification strategies based on membrane technology, liquid–liquid extraction (LLE), and solid-phase extraction with adsorbents and resins. The hydroxytyrosol content, phenolic profile, antioxidant activity, and inhibition of α-glucosidase and α-amylase were monitored. Hydroxytyrosol stood out in all purified extracts. The best hydroxytyrosol recovery (88.8%) was achieved using LLE with ethyl acetate as the extractant, while the purest extracts in phenolic compounds, including hydroxytyrosol, were obtained using the latter solvent and C18 (529 mg/g), DSC-8 (873 mg/g), and Purosorb PAD910 (523 mg/g). Conversely, mannitol and glucose, at high concentrations in the extract, were selectively retained in the aqueous phases. The developed strategies are discussed regarding their suitability to provide hydroxytyrosol-concentrated extracts, up to 291 mg/g, with antioxidant and antidiabetic functionalities.ElsevierRepositório do LNEGGómez Cruz, IreneContreras, Maria del MarRomero, InmaculadaRibeiro, BelinaRoseiro, Luisa B.Duarte, Luís C.Carvalheiro, FlorbelaCastro, Eulogio2024-01-31T12:34:28Z2023-072023-07-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.9/4240engGómez-Cruz, Irene... et.al - Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace. In: Separation and Purification Technology, 2023, vol. 325, article nº 1246641383-586610.1016/j.seppur.2023.124664info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-04T07:26:14Zoai:repositorio.lneg.pt:10400.9/4240Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:08:17.510008Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
title |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
spellingShingle |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace Gómez Cruz, Irene Adsorption Antidiabetic Hydroxytyrosol Liquid-liquid extraction Membrane purification |
title_short |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
title_full |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
title_fullStr |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
title_full_unstemmed |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
title_sort |
Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace |
author |
Gómez Cruz, Irene |
author_facet |
Gómez Cruz, Irene Contreras, Maria del Mar Romero, Inmaculada Ribeiro, Belina Roseiro, Luisa B. Duarte, Luís C. Carvalheiro, Florbela Castro, Eulogio |
author_role |
author |
author2 |
Contreras, Maria del Mar Romero, Inmaculada Ribeiro, Belina Roseiro, Luisa B. Duarte, Luís C. Carvalheiro, Florbela Castro, Eulogio |
author2_role |
author author author author author author author |
dc.contributor.none.fl_str_mv |
Repositório do LNEG |
dc.contributor.author.fl_str_mv |
Gómez Cruz, Irene Contreras, Maria del Mar Romero, Inmaculada Ribeiro, Belina Roseiro, Luisa B. Duarte, Luís C. Carvalheiro, Florbela Castro, Eulogio |
dc.subject.por.fl_str_mv |
Adsorption Antidiabetic Hydroxytyrosol Liquid-liquid extraction Membrane purification |
topic |
Adsorption Antidiabetic Hydroxytyrosol Liquid-liquid extraction Membrane purification |
description |
ABSTRACT: Exhausted olive pomace (EOP) is a residual biomass from which hydroxytyrosol can be recovered. This compound has applications in the food/pharma sectors, but its extraction yields complex extracts that require further purification for some applications. This work explores purification strategies based on membrane technology, liquid–liquid extraction (LLE), and solid-phase extraction with adsorbents and resins. The hydroxytyrosol content, phenolic profile, antioxidant activity, and inhibition of α-glucosidase and α-amylase were monitored. Hydroxytyrosol stood out in all purified extracts. The best hydroxytyrosol recovery (88.8%) was achieved using LLE with ethyl acetate as the extractant, while the purest extracts in phenolic compounds, including hydroxytyrosol, were obtained using the latter solvent and C18 (529 mg/g), DSC-8 (873 mg/g), and Purosorb PAD910 (523 mg/g). Conversely, mannitol and glucose, at high concentrations in the extract, were selectively retained in the aqueous phases. The developed strategies are discussed regarding their suitability to provide hydroxytyrosol-concentrated extracts, up to 291 mg/g, with antioxidant and antidiabetic functionalities. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-07 2023-07-01T00:00:00Z 2024-01-31T12:34:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.9/4240 |
url |
http://hdl.handle.net/10400.9/4240 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Gómez-Cruz, Irene... et.al - Strategies for the purification of hydroxytyrosol-rich extracts obtained from exhausted olive pomace. In: Separation and Purification Technology, 2023, vol. 325, article nº 124664 1383-5866 10.1016/j.seppur.2023.124664 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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