Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2
Autor(a) principal: | |
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Data de Publicação: | 2004 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/5140 https://doi.org/10.1063/1.1676429 |
Resumo: | Fluorescence from the second excited singlet state (S2) of 3-hydroxyflavone (3HF) has been observed for the first time in supercritical carbon dioxide (sc-CO2) environment. Steady-state experiments reveal that the intramolecular proton transfer is less effective from the S2 state of 3HF compared to that from the S1 state. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2Fluorescence from the second excited singlet state (S2) of 3-hydroxyflavone (3HF) has been observed for the first time in supercritical carbon dioxide (sc-CO2) environment. Steady-state experiments reveal that the intramolecular proton transfer is less effective from the S2 state of 3HF compared to that from the S1 state.http://www.sciencedirect.com/science/article/B6TFN-4BVP7G9-5/1/fe6fe6a663b47e1a622241a93ef55a872004info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5140http://hdl.handle.net/10316/5140https://doi.org/10.1063/1.1676429engChemical Physics Letters. 387:4-6 (2004) 258-262Chattopadhyay, NitinBarroso, MónicaSerpa, CarlosArnaut, Luís G.Formosinho, Sebastião J.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-11-06T17:00:01ZPortal AgregadorONG |
dc.title.none.fl_str_mv |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
title |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
spellingShingle |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 Chattopadhyay, Nitin |
title_short |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
title_full |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
title_fullStr |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
title_full_unstemmed |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
title_sort |
Fluorescence from the second excited singlet state of 3-hydroxyflavone in supercritical CO2 |
author |
Chattopadhyay, Nitin |
author_facet |
Chattopadhyay, Nitin Barroso, Mónica Serpa, Carlos Arnaut, Luís G. Formosinho, Sebastião J. |
author_role |
author |
author2 |
Barroso, Mónica Serpa, Carlos Arnaut, Luís G. Formosinho, Sebastião J. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Chattopadhyay, Nitin Barroso, Mónica Serpa, Carlos Arnaut, Luís G. Formosinho, Sebastião J. |
description |
Fluorescence from the second excited singlet state (S2) of 3-hydroxyflavone (3HF) has been observed for the first time in supercritical carbon dioxide (sc-CO2) environment. Steady-state experiments reveal that the intramolecular proton transfer is less effective from the S2 state of 3HF compared to that from the S1 state. |
publishDate |
2004 |
dc.date.none.fl_str_mv |
2004 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/5140 http://hdl.handle.net/10316/5140 https://doi.org/10.1063/1.1676429 |
url |
http://hdl.handle.net/10316/5140 https://doi.org/10.1063/1.1676429 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Chemical Physics Letters. 387:4-6 (2004) 258-262 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
aplication/PDF |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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