Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate
Autor(a) principal: | |
---|---|
Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/35515 |
Resumo: | Cholinium-based ionic liquids ([Ch]-based ILs) were investigated as electrolytes in the formation of aqueous biphasic systems (ABS) composed of polyethylene glycol (PEG) and sodium polyacrylate (NaPA) polymers. Both enhancement and decrease in the liquid-liquid demixing ability induced by electrolytes in PEG-NaPA aqueous biphasic systems were observed. It is shown that the ILs that most extensively partition to the PEG-rich phase tend to act as inorganic salts enhancing the two-phase formation ability, while those that display a more significant partition to the NaPA-rich phase decrease the ABS formation capacity. The gathered results allowed us to confirm the tailoring ability of ILs and to identify, for the first time, opposite effects induced by electrolytes on the PEG-NaPA ABS formation ability. The distribution of the electrolyte ions between the coexisting phases and the polyelectrolyte ion compartmentalization are key factors behind the formation of PEG-NaPA-based ABS. |
id |
RCAP_5593cfa98ecd628cf1cb36484893ed4b |
---|---|
oai_identifier_str |
oai:ria.ua.pt:10773/35515 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylateCholinium-based ionic liquids ([Ch]-based ILs) were investigated as electrolytes in the formation of aqueous biphasic systems (ABS) composed of polyethylene glycol (PEG) and sodium polyacrylate (NaPA) polymers. Both enhancement and decrease in the liquid-liquid demixing ability induced by electrolytes in PEG-NaPA aqueous biphasic systems were observed. It is shown that the ILs that most extensively partition to the PEG-rich phase tend to act as inorganic salts enhancing the two-phase formation ability, while those that display a more significant partition to the NaPA-rich phase decrease the ABS formation capacity. The gathered results allowed us to confirm the tailoring ability of ILs and to identify, for the first time, opposite effects induced by electrolytes on the PEG-NaPA ABS formation ability. The distribution of the electrolyte ions between the coexisting phases and the polyelectrolyte ion compartmentalization are key factors behind the formation of PEG-NaPA-based ABS.MDPI2022-12-21T10:17:29Z2021-11-01T00:00:00Z2021-11-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/35515eng1420-304910.3390/molecules26216612Bernardo, Sandra C.Capela, Emanuel V.Pereira, Jorge F. B.Ventura, Sónia P. M.Freire, Mara G.Coutinho, João A. P.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:08:17Zoai:ria.ua.pt:10773/35515Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:06:28.885152Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
title |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
spellingShingle |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate Bernardo, Sandra C. |
title_short |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
title_full |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
title_fullStr |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
title_full_unstemmed |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
title_sort |
Opposite effects induced by cholinium-based ionic liquid electrolytes in the formation of aqueous biphasic systems comprising polyethylene glycol and sodium polyacrylate |
author |
Bernardo, Sandra C. |
author_facet |
Bernardo, Sandra C. Capela, Emanuel V. Pereira, Jorge F. B. Ventura, Sónia P. M. Freire, Mara G. Coutinho, João A. P. |
author_role |
author |
author2 |
Capela, Emanuel V. Pereira, Jorge F. B. Ventura, Sónia P. M. Freire, Mara G. Coutinho, João A. P. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Bernardo, Sandra C. Capela, Emanuel V. Pereira, Jorge F. B. Ventura, Sónia P. M. Freire, Mara G. Coutinho, João A. P. |
description |
Cholinium-based ionic liquids ([Ch]-based ILs) were investigated as electrolytes in the formation of aqueous biphasic systems (ABS) composed of polyethylene glycol (PEG) and sodium polyacrylate (NaPA) polymers. Both enhancement and decrease in the liquid-liquid demixing ability induced by electrolytes in PEG-NaPA aqueous biphasic systems were observed. It is shown that the ILs that most extensively partition to the PEG-rich phase tend to act as inorganic salts enhancing the two-phase formation ability, while those that display a more significant partition to the NaPA-rich phase decrease the ABS formation capacity. The gathered results allowed us to confirm the tailoring ability of ILs and to identify, for the first time, opposite effects induced by electrolytes on the PEG-NaPA ABS formation ability. The distribution of the electrolyte ions between the coexisting phases and the polyelectrolyte ion compartmentalization are key factors behind the formation of PEG-NaPA-based ABS. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-11-01T00:00:00Z 2021-11-01 2022-12-21T10:17:29Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/35515 |
url |
http://hdl.handle.net/10773/35515 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1420-3049 10.3390/molecules26216612 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
_version_ |
1799137719893360640 |