Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate

Detalhes bibliográficos
Autor(a) principal: Yang, Ting-Hai
Data de Publicação: 2014
Outros Autores: Ferreira, Rute A. S., Carlos, Luis D., Rocha, Joao, Shi, Fa-Nian
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10773/19682
Resumo: Reaction of lanthanide oxides, cadmium acetate and 3,5-pyrazoledicarboxylic acid under hydrothermal conditions afforded five new isostructural 4d-4f hetero-metal organic frameworks, [Cd(3)Ln(pdc)(3)(H2O)] {H(3)pdc = 3,5-pyrazoledicarboxylic acid, Ln = La (1), Pr (2), Nd (3), Sm (4) and Eu (5)}. All compounds were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. The compounds feature a very interesting 3D structure built up from a secondary building unit, [Cd(12)Ln(8)(pdc)(6)], and possess a new topology type and complicated unique tiling. The solid state photoluminescence properties of compounds 3-5 were investigated at room temperature.
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spelling Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylateHETEROMETALLIC COORDINATION POLYMERSCU(II)LN(III) DINUCLEAR UNITSSINGLE-MOLECULE MAGNETINORGANIC SUBNETWORKBUILDING-BLOCKSEXTENDED ARRAYSCOMPLEXES LNLUMINESCENCECLUSTERACIDReaction of lanthanide oxides, cadmium acetate and 3,5-pyrazoledicarboxylic acid under hydrothermal conditions afforded five new isostructural 4d-4f hetero-metal organic frameworks, [Cd(3)Ln(pdc)(3)(H2O)] {H(3)pdc = 3,5-pyrazoledicarboxylic acid, Ln = La (1), Pr (2), Nd (3), Sm (4) and Eu (5)}. All compounds were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. The compounds feature a very interesting 3D structure built up from a secondary building unit, [Cd(12)Ln(8)(pdc)(6)], and possess a new topology type and complicated unique tiling. The solid state photoluminescence properties of compounds 3-5 were investigated at room temperature.ROYAL SOC CHEMISTRY2017-12-07T19:21:21Z2014-01-01T00:00:00Z2014info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/19682eng2046-206910.1039/c3ra47686cYang, Ting-HaiFerreira, Rute A. S.Carlos, Luis D.Rocha, JoaoShi, Fa-Nianinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-17T03:49:42ZPortal AgregadorONG
dc.title.none.fl_str_mv Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
title Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
spellingShingle Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
Yang, Ting-Hai
HETEROMETALLIC COORDINATION POLYMERS
CU(II)LN(III) DINUCLEAR UNITS
SINGLE-MOLECULE MAGNET
INORGANIC SUBNETWORK
BUILDING-BLOCKS
EXTENDED ARRAYS
COMPLEXES LN
LUMINESCENCE
CLUSTER
ACID
title_short Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
title_full Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
title_fullStr Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
title_full_unstemmed Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
title_sort Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate
author Yang, Ting-Hai
author_facet Yang, Ting-Hai
Ferreira, Rute A. S.
Carlos, Luis D.
Rocha, Joao
Shi, Fa-Nian
author_role author
author2 Ferreira, Rute A. S.
Carlos, Luis D.
Rocha, Joao
Shi, Fa-Nian
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Yang, Ting-Hai
Ferreira, Rute A. S.
Carlos, Luis D.
Rocha, Joao
Shi, Fa-Nian
dc.subject.por.fl_str_mv HETEROMETALLIC COORDINATION POLYMERS
CU(II)LN(III) DINUCLEAR UNITS
SINGLE-MOLECULE MAGNET
INORGANIC SUBNETWORK
BUILDING-BLOCKS
EXTENDED ARRAYS
COMPLEXES LN
LUMINESCENCE
CLUSTER
ACID
topic HETEROMETALLIC COORDINATION POLYMERS
CU(II)LN(III) DINUCLEAR UNITS
SINGLE-MOLECULE MAGNET
INORGANIC SUBNETWORK
BUILDING-BLOCKS
EXTENDED ARRAYS
COMPLEXES LN
LUMINESCENCE
CLUSTER
ACID
description Reaction of lanthanide oxides, cadmium acetate and 3,5-pyrazoledicarboxylic acid under hydrothermal conditions afforded five new isostructural 4d-4f hetero-metal organic frameworks, [Cd(3)Ln(pdc)(3)(H2O)] {H(3)pdc = 3,5-pyrazoledicarboxylic acid, Ln = La (1), Pr (2), Nd (3), Sm (4) and Eu (5)}. All compounds were characterized by elemental analysis, infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. The compounds feature a very interesting 3D structure built up from a secondary building unit, [Cd(12)Ln(8)(pdc)(6)], and possess a new topology type and complicated unique tiling. The solid state photoluminescence properties of compounds 3-5 were investigated at room temperature.
publishDate 2014
dc.date.none.fl_str_mv 2014-01-01T00:00:00Z
2014
2017-12-07T19:21:21Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10773/19682
url http://hdl.handle.net/10773/19682
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2046-2069
10.1039/c3ra47686c
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ROYAL SOC CHEMISTRY
publisher.none.fl_str_mv ROYAL SOC CHEMISTRY
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv
repository.mail.fl_str_mv
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