The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems
Autor(a) principal: | |
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Data de Publicação: | 2024 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://hdl.handle.net/1822/88769 |
Resumo: | Composites of poly(vinyl alcohol) (PVA) in the shape of braids, in combination with crystals of hydroxyapatite (HAp), were analyzed to perceive the influence of this bioceramic on both the quasistatic and viscoelastic behavior under tensile loading. Analyses involving energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM) allowed us to conclude that the production of a homogeneous layer of HAp on the braiding surface and the calcium/phosphate atomic ratio were comparable to those of natural bone. The maximum degradation temperature established by thermogravimetric analysis (TGA) showed a modest decrease with the addition of HAp. By adding HAp to PVA braids, an increase in the glass transition temperature (Tg) is noticed, as demonstrated by dynamic mechanical analysis (DMA) and differential thermal analysis (DTA). The PVA/HAp composite braids’ peaks were validated by Fourier transform infrared (FTIR) spectroscopy to be in good agreement with common PVA and HAp patterns. PVA/HAp braids, a solution often used in the textile industry, showed superior overall mechanical characteristics in monotonic tensile tests. Creep and relaxation testing showed that adding HAp to the eight and six-braided yarn architectures was beneficial. By exhibiting good mechanical performance and most likely increased biological qualities that accompany conventional care for bone applications in the fracture healing field, particularly multifragmentary ones, these arrangements can be applied as a fibrous fixation system. |
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The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systemsPoly(vinyl) alcoholHydroxyapatiteBraided compositesMechanical characterizationViscoelasticityDynamic mechanical analysisEngenharia e Tecnologia::Engenharia dos MateriaisComposites of poly(vinyl alcohol) (PVA) in the shape of braids, in combination with crystals of hydroxyapatite (HAp), were analyzed to perceive the influence of this bioceramic on both the quasistatic and viscoelastic behavior under tensile loading. Analyses involving energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM) allowed us to conclude that the production of a homogeneous layer of HAp on the braiding surface and the calcium/phosphate atomic ratio were comparable to those of natural bone. The maximum degradation temperature established by thermogravimetric analysis (TGA) showed a modest decrease with the addition of HAp. By adding HAp to PVA braids, an increase in the glass transition temperature (Tg) is noticed, as demonstrated by dynamic mechanical analysis (DMA) and differential thermal analysis (DTA). The PVA/HAp composite braids’ peaks were validated by Fourier transform infrared (FTIR) spectroscopy to be in good agreement with common PVA and HAp patterns. PVA/HAp braids, a solution often used in the textile industry, showed superior overall mechanical characteristics in monotonic tensile tests. Creep and relaxation testing showed that adding HAp to the eight and six-braided yarn architectures was beneficial. By exhibiting good mechanical performance and most likely increased biological qualities that accompany conventional care for bone applications in the fracture healing field, particularly multifragmentary ones, these arrangements can be applied as a fibrous fixation system.This research was funded by the Portuguese Foundation for Science and Technology (FCT), grant numbers PTDC/EME-SIS/28225/2017 and UID/EEA/04436/2019. The first author and the corresponding author are grateful to FCT for the conceded financial support. M.F.S.M. de Moura acknowledges the “Laboratório Associado de Energia, Transportes e Aeronáutica (LAETA)” for the financial support.Multidisciplinary Digital Publishing Institute (MDPI)Universidade do MinhoQuinaz, Tiago Filipe SimõesFreire, Tânia F.Olmos, Andrea Alexandra RodriguesMartins, MarcosFerreira, FernandoMoura, Marcelo F. S. M. deZille, AndreaQUYEN, NGUYEN-TRONGXavier, joséDourado, N.20242024-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/88769engQuinaz, T.; Freire, T.F.; Olmos, A.; Martins, M.; Ferreira, F.B.N.; de Moura, M.F.S.M.; Zille, A.; Nguyễn, Q.; Xavier, J.; Dourado, N. The Influence of Hydroxyapatite Crystals on the Viscoelastic Behavior of Poly(vinyl alcohol) Braid Systems. Biomimetics 2024, 9, 93. https://doi.org/10.3390/ biomimetics90200932313-767310.3390/biomimetics902009393https://www.mdpi.com/2313-7673/9/2/93info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-17T01:18:06Zoai:repositorium.sdum.uminho.pt:1822/88769Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:38:32.639079Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
title |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
spellingShingle |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems Quinaz, Tiago Filipe Simões Poly(vinyl) alcohol Hydroxyapatite Braided composites Mechanical characterization Viscoelasticity Dynamic mechanical analysis Engenharia e Tecnologia::Engenharia dos Materiais |
title_short |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
title_full |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
title_fullStr |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
title_full_unstemmed |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
title_sort |
The influence of hydroxyapatite crystals on the viscoelastic behavior of poly(vinyl alcohol) braid systems |
author |
Quinaz, Tiago Filipe Simões |
author_facet |
Quinaz, Tiago Filipe Simões Freire, Tânia F. Olmos, Andrea Alexandra Rodrigues Martins, Marcos Ferreira, Fernando Moura, Marcelo F. S. M. de Zille, Andrea QUYEN, NGUYEN-TRONG Xavier, josé Dourado, N. |
author_role |
author |
author2 |
Freire, Tânia F. Olmos, Andrea Alexandra Rodrigues Martins, Marcos Ferreira, Fernando Moura, Marcelo F. S. M. de Zille, Andrea QUYEN, NGUYEN-TRONG Xavier, josé Dourado, N. |
author2_role |
author author author author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Quinaz, Tiago Filipe Simões Freire, Tânia F. Olmos, Andrea Alexandra Rodrigues Martins, Marcos Ferreira, Fernando Moura, Marcelo F. S. M. de Zille, Andrea QUYEN, NGUYEN-TRONG Xavier, josé Dourado, N. |
dc.subject.por.fl_str_mv |
Poly(vinyl) alcohol Hydroxyapatite Braided composites Mechanical characterization Viscoelasticity Dynamic mechanical analysis Engenharia e Tecnologia::Engenharia dos Materiais |
topic |
Poly(vinyl) alcohol Hydroxyapatite Braided composites Mechanical characterization Viscoelasticity Dynamic mechanical analysis Engenharia e Tecnologia::Engenharia dos Materiais |
description |
Composites of poly(vinyl alcohol) (PVA) in the shape of braids, in combination with crystals of hydroxyapatite (HAp), were analyzed to perceive the influence of this bioceramic on both the quasistatic and viscoelastic behavior under tensile loading. Analyses involving energy-dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM) allowed us to conclude that the production of a homogeneous layer of HAp on the braiding surface and the calcium/phosphate atomic ratio were comparable to those of natural bone. The maximum degradation temperature established by thermogravimetric analysis (TGA) showed a modest decrease with the addition of HAp. By adding HAp to PVA braids, an increase in the glass transition temperature (Tg) is noticed, as demonstrated by dynamic mechanical analysis (DMA) and differential thermal analysis (DTA). The PVA/HAp composite braids’ peaks were validated by Fourier transform infrared (FTIR) spectroscopy to be in good agreement with common PVA and HAp patterns. PVA/HAp braids, a solution often used in the textile industry, showed superior overall mechanical characteristics in monotonic tensile tests. Creep and relaxation testing showed that adding HAp to the eight and six-braided yarn architectures was beneficial. By exhibiting good mechanical performance and most likely increased biological qualities that accompany conventional care for bone applications in the fracture healing field, particularly multifragmentary ones, these arrangements can be applied as a fibrous fixation system. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024 2024-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/88769 |
url |
https://hdl.handle.net/1822/88769 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Quinaz, T.; Freire, T.F.; Olmos, A.; Martins, M.; Ferreira, F.B.N.; de Moura, M.F.S.M.; Zille, A.; Nguyễn, Q.; Xavier, J.; Dourado, N. The Influence of Hydroxyapatite Crystals on the Viscoelastic Behavior of Poly(vinyl alcohol) Braid Systems. Biomimetics 2024, 9, 93. https://doi.org/10.3390/ biomimetics9020093 2313-7673 10.3390/biomimetics9020093 93 https://www.mdpi.com/2313-7673/9/2/93 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute (MDPI) |
publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute (MDPI) |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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