Regioselective enzymatic acylation of vicinal diols of steroids

Detalhes bibliográficos
Autor(a) principal: Silva, M. Manuel Cruz
Data de Publicação: 2005
Outros Autores: Riva, Sergio, Melo, M. Luísa Sá e
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10316/5756
https://doi.org/10.1016/j.tet.2005.01.104
Resumo: Monoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups.
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spelling Regioselective enzymatic acylation of vicinal diols of steroidsLipasesSteroidsRegioselectivityEnzymatic esterificationMonoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups.http://www.sciencedirect.com/science/article/B6THR-4FGX84H-2/1/c23744db4c590d02acf7c82018be57202005info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5756http://hdl.handle.net/10316/5756https://doi.org/10.1016/j.tet.2005.01.104engTetrahedron. 61:12 (2005) 3065-3073Silva, M. Manuel CruzRiva, SergioMelo, M. Luísa Sá einfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2021-10-28T09:18:58ZPortal AgregadorONG
dc.title.none.fl_str_mv Regioselective enzymatic acylation of vicinal diols of steroids
title Regioselective enzymatic acylation of vicinal diols of steroids
spellingShingle Regioselective enzymatic acylation of vicinal diols of steroids
Silva, M. Manuel Cruz
Lipases
Steroids
Regioselectivity
Enzymatic esterification
title_short Regioselective enzymatic acylation of vicinal diols of steroids
title_full Regioselective enzymatic acylation of vicinal diols of steroids
title_fullStr Regioselective enzymatic acylation of vicinal diols of steroids
title_full_unstemmed Regioselective enzymatic acylation of vicinal diols of steroids
title_sort Regioselective enzymatic acylation of vicinal diols of steroids
author Silva, M. Manuel Cruz
author_facet Silva, M. Manuel Cruz
Riva, Sergio
Melo, M. Luísa Sá e
author_role author
author2 Riva, Sergio
Melo, M. Luísa Sá e
author2_role author
author
dc.contributor.author.fl_str_mv Silva, M. Manuel Cruz
Riva, Sergio
Melo, M. Luísa Sá e
dc.subject.por.fl_str_mv Lipases
Steroids
Regioselectivity
Enzymatic esterification
topic Lipases
Steroids
Regioselectivity
Enzymatic esterification
description Monoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups.
publishDate 2005
dc.date.none.fl_str_mv 2005
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10316/5756
http://hdl.handle.net/10316/5756
https://doi.org/10.1016/j.tet.2005.01.104
url http://hdl.handle.net/10316/5756
https://doi.org/10.1016/j.tet.2005.01.104
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Tetrahedron. 61:12 (2005) 3065-3073
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv aplication/PDF
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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instacron_str RCAAP
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repository.mail.fl_str_mv
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