Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://hdl.handle.net/1822/81271 |
Resumo: | In the last decade orthorhombic hafnia and zirconia films have attracted tremendous attention arising from the discovery of ferroelectricity at the nanoscale. However, an initial wake-up pre-cycling is usually needed to achieve a ferroelectric behaviour in these films. Recently, different strategies, such as microstructure tailoring, defect, bulk and interface engineering, doping, NH3 plasma treatment and epitaxial growth, have been employed to obtain wake-up free orthorhombic ferroelectric hafnia and zirconia films. In this work we review recent developments in obtaining polar hafnia and zirconia-based thin films without the need of any wake-up cycling. In particular, we discuss the rhombohedral phase of hafnia/ zirconia, which under a constrained environment exhibits wake-up-free ferroelectric behaviour. This phase could have a strong impact on the current investigations of ferroelectric binary oxide materials and pave the way toward exploiting ferroelectric behaviour for next-generation memory and logic gate applications. |
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Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films(Pseudo-)binary oxidesFerroelectricityWake-up effectEpitaxial growthCiências Naturais::Ciências FísicasScience & TechnologyIn the last decade orthorhombic hafnia and zirconia films have attracted tremendous attention arising from the discovery of ferroelectricity at the nanoscale. However, an initial wake-up pre-cycling is usually needed to achieve a ferroelectric behaviour in these films. Recently, different strategies, such as microstructure tailoring, defect, bulk and interface engineering, doping, NH3 plasma treatment and epitaxial growth, have been employed to obtain wake-up free orthorhombic ferroelectric hafnia and zirconia films. In this work we review recent developments in obtaining polar hafnia and zirconia-based thin films without the need of any wake-up cycling. In particular, we discuss the rhombohedral phase of hafnia/ zirconia, which under a constrained environment exhibits wake-up-free ferroelectric behaviour. This phase could have a strong impact on the current investigations of ferroelectric binary oxide materials and pave the way toward exploiting ferroelectric behaviour for next-generation memory and logic gate applications.This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding Contract UIDB/04650/2020 and by DST-SERB, Govt. of India through Grant Nr. ECR/2017/00006. R. F. Negrea and L. Pintilie acknowledge funding through project CEPROFER/ PN-III-P4-ID-PCCF-2016-0047 (contract 16/2018, funded by UEFISCDI). J.L.M-D. thanks the Royal Academy of Engineering Chair in Emerging Technologies Grant, CIET1819_24, the EPSRC grant EP/T012218/1- ECCS – EPSRC, and the grant EU-H2020-ERC-ADG # 882929, EROS.ElsevierUniversidade do MinhoSilva, José Pedro BastoSekhar, K. C.Negrea, R. F.MacManus-Driscoll, J. L.Pintilie, L.20222022-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/1822/81271engSilva, J. P. B., Sekhar, K. C., Negrea, R. F., MacManus-Driscoll, J. L., & Pintilie, L. (2022, March). Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films. Applied Materials Today. Elsevier BV. http://doi.org/10.1016/j.apmt.2022.1013942352-940710.1016/j.apmt.2022.101394https://www.sciencedirect.com/science/article/pii/S2352940722000336info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:37:24ZPortal AgregadorONG |
dc.title.none.fl_str_mv |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
title |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
spellingShingle |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films Silva, José Pedro Basto (Pseudo-)binary oxides Ferroelectricity Wake-up effect Epitaxial growth Ciências Naturais::Ciências Físicas Science & Technology |
title_short |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
title_full |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
title_fullStr |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
title_full_unstemmed |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
title_sort |
Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films |
author |
Silva, José Pedro Basto |
author_facet |
Silva, José Pedro Basto Sekhar, K. C. Negrea, R. F. MacManus-Driscoll, J. L. Pintilie, L. |
author_role |
author |
author2 |
Sekhar, K. C. Negrea, R. F. MacManus-Driscoll, J. L. Pintilie, L. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade do Minho |
dc.contributor.author.fl_str_mv |
Silva, José Pedro Basto Sekhar, K. C. Negrea, R. F. MacManus-Driscoll, J. L. Pintilie, L. |
dc.subject.por.fl_str_mv |
(Pseudo-)binary oxides Ferroelectricity Wake-up effect Epitaxial growth Ciências Naturais::Ciências Físicas Science & Technology |
topic |
(Pseudo-)binary oxides Ferroelectricity Wake-up effect Epitaxial growth Ciências Naturais::Ciências Físicas Science & Technology |
description |
In the last decade orthorhombic hafnia and zirconia films have attracted tremendous attention arising from the discovery of ferroelectricity at the nanoscale. However, an initial wake-up pre-cycling is usually needed to achieve a ferroelectric behaviour in these films. Recently, different strategies, such as microstructure tailoring, defect, bulk and interface engineering, doping, NH3 plasma treatment and epitaxial growth, have been employed to obtain wake-up free orthorhombic ferroelectric hafnia and zirconia films. In this work we review recent developments in obtaining polar hafnia and zirconia-based thin films without the need of any wake-up cycling. In particular, we discuss the rhombohedral phase of hafnia/ zirconia, which under a constrained environment exhibits wake-up-free ferroelectric behaviour. This phase could have a strong impact on the current investigations of ferroelectric binary oxide materials and pave the way toward exploiting ferroelectric behaviour for next-generation memory and logic gate applications. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022 2022-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://hdl.handle.net/1822/81271 |
url |
https://hdl.handle.net/1822/81271 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Silva, J. P. B., Sekhar, K. C., Negrea, R. F., MacManus-Driscoll, J. L., & Pintilie, L. (2022, March). Progress and perspective on different strategies to achieve wake-up-free ferroelectric hafnia and zirconia-based thin films. Applied Materials Today. Elsevier BV. http://doi.org/10.1016/j.apmt.2022.101394 2352-9407 10.1016/j.apmt.2022.101394 https://www.sciencedirect.com/science/article/pii/S2352940722000336 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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