New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/26978 |
Resumo: | Cellulosic fibre/silica hybrid materials functionalized with Keggin-type polyoxometalates ([PV2Mo10O40]52, [PVMo11O40]42, ([PMo12O40]32 or [PW12O40]32) were prepared by a sol–gel method at room temperature. The novel materials are composed of ca. 56 wt% of polysaccharides, ca. 37 wt% of propylamine-modified silica, 2 wt% of polyoxometalate, and 5% of hydration water. The silica network of these hybrids exhibits relatively high degree of condensation being distributed mainly on the surface of the cellulosic fibres as a dense film. The functionalization of silica with polyoxometalates via electrostatic interactions with protonated propylamino groups of modified silica was unambiguously confirmed. Despite their high silica content cellulose/silica hybrids retained basic cellulosic pulp properties—supramolecular and fibrous structure, porosity, relatively low density, etc. The novel bio-based material functionalized with 2% of [PVMo11O40]42 shows particularly high activity towards the oxidation of volatile organic compounds (VOCs) present in urban air thus anticipating future environmental applications. |
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New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applicationsCellulosic fibre/silica hybrid materials functionalized with Keggin-type polyoxometalates ([PV2Mo10O40]52, [PVMo11O40]42, ([PMo12O40]32 or [PW12O40]32) were prepared by a sol–gel method at room temperature. The novel materials are composed of ca. 56 wt% of polysaccharides, ca. 37 wt% of propylamine-modified silica, 2 wt% of polyoxometalate, and 5% of hydration water. The silica network of these hybrids exhibits relatively high degree of condensation being distributed mainly on the surface of the cellulosic fibres as a dense film. The functionalization of silica with polyoxometalates via electrostatic interactions with protonated propylamino groups of modified silica was unambiguously confirmed. Despite their high silica content cellulose/silica hybrids retained basic cellulosic pulp properties—supramolecular and fibrous structure, porosity, relatively low density, etc. The novel bio-based material functionalized with 2% of [PVMo11O40]42 shows particularly high activity towards the oxidation of volatile organic compounds (VOCs) present in urban air thus anticipating future environmental applications.Royal Society of Chemistry2019-11-18T14:27:26Z2012-01-01T00:00:00Z2012info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/26978eng2046-206910.1039/C1RA00371BGamelas, J. A. F.Evtyugina, M. G.Portugal, I.Evtuguin, D. V.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T11:52:17Zoai:ria.ua.pt:10773/26978Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:59:52.274327Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
title |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
spellingShingle |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications Gamelas, J. A. F. |
title_short |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
title_full |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
title_fullStr |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
title_full_unstemmed |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
title_sort |
New polyoxometalate-functionalized cellulosic fibre/silica hybrids for environmental applications |
author |
Gamelas, J. A. F. |
author_facet |
Gamelas, J. A. F. Evtyugina, M. G. Portugal, I. Evtuguin, D. V. |
author_role |
author |
author2 |
Evtyugina, M. G. Portugal, I. Evtuguin, D. V. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Gamelas, J. A. F. Evtyugina, M. G. Portugal, I. Evtuguin, D. V. |
description |
Cellulosic fibre/silica hybrid materials functionalized with Keggin-type polyoxometalates ([PV2Mo10O40]52, [PVMo11O40]42, ([PMo12O40]32 or [PW12O40]32) were prepared by a sol–gel method at room temperature. The novel materials are composed of ca. 56 wt% of polysaccharides, ca. 37 wt% of propylamine-modified silica, 2 wt% of polyoxometalate, and 5% of hydration water. The silica network of these hybrids exhibits relatively high degree of condensation being distributed mainly on the surface of the cellulosic fibres as a dense film. The functionalization of silica with polyoxometalates via electrostatic interactions with protonated propylamino groups of modified silica was unambiguously confirmed. Despite their high silica content cellulose/silica hybrids retained basic cellulosic pulp properties—supramolecular and fibrous structure, porosity, relatively low density, etc. The novel bio-based material functionalized with 2% of [PVMo11O40]42 shows particularly high activity towards the oxidation of volatile organic compounds (VOCs) present in urban air thus anticipating future environmental applications. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01-01T00:00:00Z 2012 2019-11-18T14:27:26Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/26978 |
url |
http://hdl.handle.net/10773/26978 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2046-2069 10.1039/C1RA00371B |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Royal Society of Chemistry |
publisher.none.fl_str_mv |
Royal Society of Chemistry |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799137653473411072 |