Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate

Detalhes bibliográficos
Autor(a) principal: Lemos, A.
Data de Publicação: 2003
Outros Autores: Guimaraes, Emanuel, Fortes, Gil, Alves, Maria José Chão
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.1/1023
Resumo: The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.
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spelling Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylateAzirinasHeterocyclesIntermolecular radical additionTriethylboraneAlfa-aminoestersThe 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.SapientiaLemos, A.Guimaraes, EmanuelFortes, GilAlves, Maria José Chão2012-04-13T10:29:55Z20032012-02-27T17:47:20Z2003-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.1/1023engSynlett, 10, 1403-1406, 2003.AUT: ALE01411;info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-24T10:11:47Zoai:sapientia.ualg.pt:10400.1/1023Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:55:11.690746Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
title Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
spellingShingle Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
Lemos, A.
Azirinas
Heterocycles
Intermolecular radical addition
Triethylborane
Alfa-aminoesters
title_short Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
title_full Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
title_fullStr Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
title_full_unstemmed Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
title_sort Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate
author Lemos, A.
author_facet Lemos, A.
Guimaraes, Emanuel
Fortes, Gil
Alves, Maria José Chão
author_role author
author2 Guimaraes, Emanuel
Fortes, Gil
Alves, Maria José Chão
author2_role author
author
author
dc.contributor.none.fl_str_mv Sapientia
dc.contributor.author.fl_str_mv Lemos, A.
Guimaraes, Emanuel
Fortes, Gil
Alves, Maria José Chão
dc.subject.por.fl_str_mv Azirinas
Heterocycles
Intermolecular radical addition
Triethylborane
Alfa-aminoesters
topic Azirinas
Heterocycles
Intermolecular radical addition
Triethylborane
Alfa-aminoesters
description The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.
publishDate 2003
dc.date.none.fl_str_mv 2003
2003-01-01T00:00:00Z
2012-04-13T10:29:55Z
2012-02-27T17:47:20Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.1/1023
url http://hdl.handle.net/10400.1/1023
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Synlett, 10, 1403-1406, 2003.
AUT: ALE01411;
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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