Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2023 |
| Outros Autores: | , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
| Texto Completo: | http://hdl.handle.net/10362/164427 |
Resumo: | Funding Information: This work has been supported by the Fundação para a Ciência e a Tecnologia (FCT) (Portugal), projects UIDB/00100/2020, UIDP/00100/2020 and LA/P/0056/2020 of Centro de Química Estrutural, projects UIDB/50006/2020, UIDP/50006/2020 and LA/P/0008/2020 of the Associate Laboratory for Green Chemistry – LAQV REQUIMTE, and project MIT-EXPL/CS/0052/2021. A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
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Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) ComplexesCatalytic Application in Cycloaddition Reaction of CO2 with EpoxidesChemistry(all)Chemical Engineering(all)Funding Information: This work has been supported by the Fundação para a Ciência e a Tecnologia (FCT) (Portugal), projects UIDB/00100/2020, UIDP/00100/2020 and LA/P/0056/2020 of Centro de Química Estrutural, projects UIDB/50006/2020, UIDP/50006/2020 and LA/P/0008/2020 of the Associate Laboratory for Green Chemistry – LAQV REQUIMTE, and project MIT-EXPL/CS/0052/2021. A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.Three new zinc(II) complexes [Zn(H2L3)2(H2O)3] (Zn2), [Zn(H3L2a)(H2O)3]n (Zn3) (H3L2a = 2,4-diiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl)isophthalate) and [Zn(HL4)(DMF)(H2O)]n (Zn4) were synthesized by the reaction of Zn(II) salts with 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl) isophthalic acid (H3L3), 2,4,6-triiodo-5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene)hydrazineyl) isophthalic acid (H5L2) (in the presence of NH2OH·HCl) and 5-(2-(2,4-dioxopentan-3-ylidene)hydrazineyl)-2,4,6-triiodoisophthalic acid (H3L4), respectively. According to the X-ray structural analysis, the intramolecular resonance-assisted hydrogen bond ring remains intact, with N···O distances of 2.562(5) and 2.573(5) Å in Zn2, 2.603(6) Å in Zn3, and 2.563(8) Å in Zn4. In the crystal packing of Zn3, the cooperation of I···O and I···I types of halogen bonds between tectons leads to a one-dimensional supramolecular polymer, while I···O interactions aggregate 1D chains of coordination polymer Zn4. These new complexes (Zn2, Zn3, and Zn4) and known [Zn(H3L1)(H2O)2]n (Zn1) (H3L1 = 5-(2-(2,4,6-trioxotetrahydropyrimidin-5(2H)-ylidene) hydrazineyl)isophthalate), {[Zn(H3L1)(H2O)3]·3H2O}n (Zn5), [Cd(H3L1)(H2O)2]n (Cd1), {[Cd(HL3)(H2O)2(DMF)]·H2O}n (Cd2), [Cd(H3L3)]n (Cd-3), {[Cd2(μ-H2O)2(μ-H2L4)2(H2L4)2]·2H2O}n (Cd4), and {[Cd(H3L1)(H2O)3]·4H2O}n (Cd5) were tested as catalysts in the cycloaddition reaction of CO2 with epoxides in the presence of tetrabutylammonium halides as the cocatalyst. The halogen-bonded catalyst Zn4 is the most efficient one in the presence of tetrabutylammonium bromide by affording a high yield (85-99%) of cyclic carbonates under solvent-free conditions after 48 h at 40 bar and 80 °C.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNAliyeva, Vusala A.Paninho, Ana B.Nunes, Ana V. M.Karmakar, AnirbanGurbanov, Atash V.Rutigliano, Arianna R.Gallo, EmmaMahmudov, Kamran T.Pombeiro, Armando J. L.2024-03-04T23:57:09Z2023-11-142023-11-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article11application/pdfhttp://hdl.handle.net/10362/164427eng2470-1343PURE: 83889461https://doi.org/10.1021/acsomega.3c04262info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:52:09Zoai:run.unl.pt:10362/164427Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T04:00:10.000288Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
| dc.title.none.fl_str_mv |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes Catalytic Application in Cycloaddition Reaction of CO2 with Epoxides |
| title |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| spellingShingle |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes Aliyeva, Vusala A. Chemistry(all) Chemical Engineering(all) |
| title_short |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_full |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_fullStr |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_full_unstemmed |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| title_sort |
Halogen Bonding in the Decoration of Secondary Coordination Sphere of Zinc(II) and Cadmium(II) Complexes |
| author |
Aliyeva, Vusala A. |
| author_facet |
Aliyeva, Vusala A. Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| author_role |
author |
| author2 |
Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| author2_role |
author author author author author author author author |
| dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
| dc.contributor.author.fl_str_mv |
Aliyeva, Vusala A. Paninho, Ana B. Nunes, Ana V. M. Karmakar, Anirban Gurbanov, Atash V. Rutigliano, Arianna R. Gallo, Emma Mahmudov, Kamran T. Pombeiro, Armando J. L. |
| dc.subject.por.fl_str_mv |
Chemistry(all) Chemical Engineering(all) |
| topic |
Chemistry(all) Chemical Engineering(all) |
| description |
Funding Information: This work has been supported by the Fundação para a Ciência e a Tecnologia (FCT) (Portugal), projects UIDB/00100/2020, UIDP/00100/2020 and LA/P/0056/2020 of Centro de Química Estrutural, projects UIDB/50006/2020, UIDP/50006/2020 and LA/P/0008/2020 of the Associate Laboratory for Green Chemistry – LAQV REQUIMTE, and project MIT-EXPL/CS/0052/2021. A.V.G. and K.T.M. thank FCT and Instituto Superior Técnico (DL 57/2016, L 57/2017 and CEEC Institutional 2018 Programs, Contracts no: IST-ID/110/2018 and IST-ID/85/2018). VAA is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for her research fellowship through grant no: BL110/2022-IST-ID. K.T.M. and A.V.G. acknowledge the support by the Baku State University (Azerbaijan). A.R.R. thanks the Erasmus Program of the University of Milan and the Instituto Superior Técnico for a traineeship at the IST. Authors thank the Portuguese NMR Network (IST-UL Centre) and the IST Node of the Portuguese Network of mass-spectrometry. NMR spectrometers are part of The National NMR Facility, supported by FCT (ROTEIRO/0031/2013-PINFRA/22161/2016) (co- financed by FEDER through COMPETE 2020, POCI, and PORL and FCT through PIDDAC). Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. |
| publishDate |
2023 |
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2023-11-14 2023-11-14T00:00:00Z 2024-03-04T23:57:09Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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publishedVersion |
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http://hdl.handle.net/10362/164427 |
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eng |
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eng |
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2470-1343 PURE: 83889461 https://doi.org/10.1021/acsomega.3c04262 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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11 application/pdf |
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