Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]

Detalhes bibliográficos
Autor(a) principal: Alegria,Elisabete C.B.A.
Data de Publicação: 2004
Outros Autores: Cunha,Sónia M.P.R.M., Martins,Luísa M.D.R.S., Silva,M. Fátima C. Guedes da, Pombeiro,Armando J.L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003
Resumo: The bis(cyanoimide) complex trans-[Mo(NCN)2(dppe)2] (dppe = Ph2PCH2CH2PPh2) is susceptible of electrophilic attack to form the acylated and aroylated derivatives trans-[MO(NCN){NCNC(O)R}(dppe)2]Cl (R = Et 2a or Ph 2b). Herein, we report a preliminary study on the electrochemical behaviour of complexes 2 and the derivative trans-[Mo(NCN)Cl(dppe)2][BF4] 3, as investigated by cyclic voltammetry (CV) and controlled-potential electrolysis (CPE), what has allowed a comparison of the electron-donor ability of the ligands.
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spelling Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]Molybdenum complexescyanoimide complexesacylationaroylationderivativeelectrophilic attackelectron richnessThe bis(cyanoimide) complex trans-[Mo(NCN)2(dppe)2] (dppe = Ph2PCH2CH2PPh2) is susceptible of electrophilic attack to form the acylated and aroylated derivatives trans-[MO(NCN){NCNC(O)R}(dppe)2]Cl (R = Et 2a or Ph 2b). Herein, we report a preliminary study on the electrochemical behaviour of complexes 2 and the derivative trans-[Mo(NCN)Cl(dppe)2][BF4] 3, as investigated by cyclic voltammetry (CV) and controlled-potential electrolysis (CPE), what has allowed a comparison of the electron-donor ability of the ligands.Sociedade Portuguesa de Electroquímica2004-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003Portugaliae Electrochimica Acta v.22 n.1 2004reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003Alegria,Elisabete C.B.A.Cunha,Sónia M.P.R.M.Martins,Luísa M.D.R.S.Silva,M. Fátima C. Guedes daPombeiro,Armando J.L.info:eu-repo/semantics/openAccess2024-02-06T17:06:42Zoai:scielo:S0872-19042004000100003Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:19:57.038047Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
title Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
spellingShingle Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
Alegria,Elisabete C.B.A.
Molybdenum complexes
cyanoimide complexes
acylation
aroylation
derivative
electrophilic attack
electron richness
title_short Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
title_full Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
title_fullStr Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
title_full_unstemmed Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
title_sort Comparative Electrochemical Behaviour of the Complexes trans-[Mo(NCN){NCNC(O)R}(dppe)2]Cl (R = Et or Ph) and trans-[Mo(NCN)CI(dppe)2][BF4]
author Alegria,Elisabete C.B.A.
author_facet Alegria,Elisabete C.B.A.
Cunha,Sónia M.P.R.M.
Martins,Luísa M.D.R.S.
Silva,M. Fátima C. Guedes da
Pombeiro,Armando J.L.
author_role author
author2 Cunha,Sónia M.P.R.M.
Martins,Luísa M.D.R.S.
Silva,M. Fátima C. Guedes da
Pombeiro,Armando J.L.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Alegria,Elisabete C.B.A.
Cunha,Sónia M.P.R.M.
Martins,Luísa M.D.R.S.
Silva,M. Fátima C. Guedes da
Pombeiro,Armando J.L.
dc.subject.por.fl_str_mv Molybdenum complexes
cyanoimide complexes
acylation
aroylation
derivative
electrophilic attack
electron richness
topic Molybdenum complexes
cyanoimide complexes
acylation
aroylation
derivative
electrophilic attack
electron richness
description The bis(cyanoimide) complex trans-[Mo(NCN)2(dppe)2] (dppe = Ph2PCH2CH2PPh2) is susceptible of electrophilic attack to form the acylated and aroylated derivatives trans-[MO(NCN){NCNC(O)R}(dppe)2]Cl (R = Et 2a or Ph 2b). Herein, we report a preliminary study on the electrochemical behaviour of complexes 2 and the derivative trans-[Mo(NCN)Cl(dppe)2][BF4] 3, as investigated by cyclic voltammetry (CV) and controlled-potential electrolysis (CPE), what has allowed a comparison of the electron-donor ability of the ligands.
publishDate 2004
dc.date.none.fl_str_mv 2004-01-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003
url http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042004000100003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
publisher.none.fl_str_mv Sociedade Portuguesa de Electroquímica
dc.source.none.fl_str_mv Portugaliae Electrochimica Acta v.22 n.1 2004
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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