Plasma-treated Bombyx mori cocoon separators for high-performance and sustainable lithium-ion batteries

• Main Author: Pereira, Rui Francisco Gonçalves Pinto Fernandes
• Publication Date: 2020
• Other Authors: Gonçalves, Renato, Rodrigues, Helena, Correia, Daniela M., Costa, Carlos Miguel Silva, Silva, Maria M., Lanceros-Méndez, S., Zea Bermudez, V
• Format: Article
• Language: eng
• Source: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Download full: https://hdl.handle.net/1822/69505
• topic: Bombyx mori cocoon separators; Plasma treatment; Lithium-ion batteries; Performance; Safety; Sustainability; Biomimetic; Natural materials; Silk; Science & Technology

The success of lithium ion batteries (LIBs) and their unique advantages for electrochemical energy storage have speed up research in this field. A critical component of LIBs is the separator. Here, Bombyx mori silk cocoon separators have been treated with oxygen (O2) and nitrogen (N2) plasmas at different exposure times. The goal was to improve the electrochemical characteristics of these natural separators without jeopardizing the major attributes of silk fibers. Major physical and chemical modifications have been identified at the submicrometer scale upon the application of the plasmas: (1) Etching of the silk nanofibrils and concomitant increase of roughness (more effective with O2 plasma), corresponding to the destruction of the 5 th structural hierarchy level of the silk fibers. (2) Creation of oxygen-containing functional groups carrying negatives charges at the surface, causing a superhydrophic-to-superhydrophilic transition, and favoring Li+ transport. The optimized cocoon separator exposed to O2 plasma for 30 s exhibited high electrolyte uptake (289%), high ionic conductivity (2.33 mS cm−1 at 25 ºC) and low overall resistance. A cathodic half-cell of carbon-coated lithium iron phosphate incorporating this separator sample soaked in the ethylene carbonate/dimethyl carbonate/lithium hexafluorophosphate electrolyte demonstrated a performance boost with respect to the battery including a raw cocoon separator: an outstanding increase (ca. 270%) of the discharge capacity (from 26.1 to 96.7 mAh g−1 at 5C-rate) and an impressive increase (291%) of the capacity retention (from 22.3 to 87.2%, from C/5 to 5C). This work proves that the O2 plasma exposure is a valid, simple, fast, clean and safe top-down methodology to improve the properties of Bombyx mori cocoon separators. The features of these plasma-treated separators, which surpass those of commercial separators, help upgrading the performance of LIBs. This plasma-enhanced natural biomaterial separator technological platform pushes LIBs to the next performance-level, while guaranteeing the eco-friendly, sustainability and safety labels.