Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017 |
Resumo: | PtRu/C electrocatalysts were prepared by hydrothermal carbonization process using starch as carbon sources and reducing agents and platinum and ruthenium salts as catalysts of carbonization process and metals source. pH of the reaction medium was adjusted using KOH or TPAOH (tetrapropylammonium hydroxide). The obtained PtRu/C electrocatalysts were characterized by SEM/EDX, TGA, XRD and cyclic voltammetry. The electro-oxidation of methanol was studied by cyclic voltammetry and chronoamperometry. The PtRu/C electrocatalyst prepared using TPAOH was more active for methanol electro-oxidation than the material prepared with KOH. |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidationstarchhydrothermal carbonizationPtRu/C electrocatalystmethanolfuel cellPtRu/C electrocatalysts were prepared by hydrothermal carbonization process using starch as carbon sources and reducing agents and platinum and ruthenium salts as catalysts of carbonization process and metals source. pH of the reaction medium was adjusted using KOH or TPAOH (tetrapropylammonium hydroxide). The obtained PtRu/C electrocatalysts were characterized by SEM/EDX, TGA, XRD and cyclic voltammetry. The electro-oxidation of methanol was studied by cyclic voltammetry and chronoamperometry. The PtRu/C electrocatalyst prepared using TPAOH was more active for methanol electro-oxidation than the material prepared with KOH.Sociedade Portuguesa de Electroquímica2009-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017Portugaliae Electrochimica Acta v.27 n.3 2009reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017Tusi,M. M.Brandalise,M.Correa,O. V.Neto,A. O.Linardi,M.Spinacé,E. V.info:eu-repo/semantics/openAccess2023-07-27T12:23:22ZPortal AgregadorONG |
dc.title.none.fl_str_mv |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
title |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
spellingShingle |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation Tusi,M. M. starch hydrothermal carbonization PtRu/C electrocatalyst methanol fuel cell |
title_short |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
title_full |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
title_fullStr |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
title_full_unstemmed |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
title_sort |
Preparation of PtRu/C Electrocatalysts by Hydrothermal Carbonization Process for Methanol Electro-oxidation |
author |
Tusi,M. M. |
author_facet |
Tusi,M. M. Brandalise,M. Correa,O. V. Neto,A. O. Linardi,M. Spinacé,E. V. |
author_role |
author |
author2 |
Brandalise,M. Correa,O. V. Neto,A. O. Linardi,M. Spinacé,E. V. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Tusi,M. M. Brandalise,M. Correa,O. V. Neto,A. O. Linardi,M. Spinacé,E. V. |
dc.subject.por.fl_str_mv |
starch hydrothermal carbonization PtRu/C electrocatalyst methanol fuel cell |
topic |
starch hydrothermal carbonization PtRu/C electrocatalyst methanol fuel cell |
description |
PtRu/C electrocatalysts were prepared by hydrothermal carbonization process using starch as carbon sources and reducing agents and platinum and ruthenium salts as catalysts of carbonization process and metals source. pH of the reaction medium was adjusted using KOH or TPAOH (tetrapropylammonium hydroxide). The obtained PtRu/C electrocatalysts were characterized by SEM/EDX, TGA, XRD and cyclic voltammetry. The electro-oxidation of methanol was studied by cyclic voltammetry and chronoamperometry. The PtRu/C electrocatalyst prepared using TPAOH was more active for methanol electro-oxidation than the material prepared with KOH. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042009000300017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.27 n.3 2009 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
|
repository.mail.fl_str_mv |
|
_version_ |
1777304406692200448 |