Design Bases for Modulated Complexation by Electrochemistry
Autor(a) principal: | |
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Data de Publicação: | 2007 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001 |
Resumo: | The treatment of liquid organic phases to remove undesirable compounds is currently a priority in different industries. In oil refinery, it is necessary to reduce sulphur compounds, in gasolines, to below 50 ppm.The traditional form is catalytic hydrodesulphuration; however, this system is not effective for some compounds, e.g., alkyl substituted dibenzothiophenes. The processes for modulated complexation by electrochemistry are based on the capacity of a complexing agent, in a certain oxidation state, to form a bond with the molecule to be removed from a liquid phase. If the contaminant, the solute, is in an organic phase, the complexant must be soluble in aqueous phase. When the complexant is formed and in contact with both phases the contaminant is extracted. In a second stage, the complexing agent is oxidized (or reduced) to a state of less affinity to the contaminant, and the aqueous phase is placed in contact with a new organic phase where the contaminant will be discharged and concentrated. The complexant agent in aqueous phase is reduced (or oxidized) to its state of higher affinity for the contaminant and recirculated to the extraction stage. In this work, we present the conditions necessary for this process to be feasible, the criteria for the selection of the complexes, the methodology for matter balances, determination of energy consumption and thermodynamic calculations, and also three examples of an organic phase: dibenzotiophene, pyridine, and methyl thioether, using as complexing agent iron tetrakis-(p-sulphonatophenyl) porphyrin. |
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Design Bases for Modulated Complexation by Electrochemistrymodulated complexation by electrochemistryiron tetrakis(p-sulphonatophenyl) porphyrincontaminants treatment in organic solventsThe treatment of liquid organic phases to remove undesirable compounds is currently a priority in different industries. In oil refinery, it is necessary to reduce sulphur compounds, in gasolines, to below 50 ppm.The traditional form is catalytic hydrodesulphuration; however, this system is not effective for some compounds, e.g., alkyl substituted dibenzothiophenes. The processes for modulated complexation by electrochemistry are based on the capacity of a complexing agent, in a certain oxidation state, to form a bond with the molecule to be removed from a liquid phase. If the contaminant, the solute, is in an organic phase, the complexant must be soluble in aqueous phase. When the complexant is formed and in contact with both phases the contaminant is extracted. In a second stage, the complexing agent is oxidized (or reduced) to a state of less affinity to the contaminant, and the aqueous phase is placed in contact with a new organic phase where the contaminant will be discharged and concentrated. The complexant agent in aqueous phase is reduced (or oxidized) to its state of higher affinity for the contaminant and recirculated to the extraction stage. In this work, we present the conditions necessary for this process to be feasible, the criteria for the selection of the complexes, the methodology for matter balances, determination of energy consumption and thermodynamic calculations, and also three examples of an organic phase: dibenzotiophene, pyridine, and methyl thioether, using as complexing agent iron tetrakis-(p-sulphonatophenyl) porphyrin.Sociedade Portuguesa de Electroquímica2007-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articletext/htmlhttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001Portugaliae Electrochimica Acta v.25 n.2 2007reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAPenghttp://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001Sánchez,J.O.Tejeda,P.R.info:eu-repo/semantics/openAccess2024-02-06T17:06:51Zoai:scielo:S0872-19042007000200001Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T02:20:02.301820Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Design Bases for Modulated Complexation by Electrochemistry |
title |
Design Bases for Modulated Complexation by Electrochemistry |
spellingShingle |
Design Bases for Modulated Complexation by Electrochemistry Sánchez,J.O. modulated complexation by electrochemistry iron tetrakis(p-sulphonatophenyl) porphyrin contaminants treatment in organic solvents |
title_short |
Design Bases for Modulated Complexation by Electrochemistry |
title_full |
Design Bases for Modulated Complexation by Electrochemistry |
title_fullStr |
Design Bases for Modulated Complexation by Electrochemistry |
title_full_unstemmed |
Design Bases for Modulated Complexation by Electrochemistry |
title_sort |
Design Bases for Modulated Complexation by Electrochemistry |
author |
Sánchez,J.O. |
author_facet |
Sánchez,J.O. Tejeda,P.R. |
author_role |
author |
author2 |
Tejeda,P.R. |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Sánchez,J.O. Tejeda,P.R. |
dc.subject.por.fl_str_mv |
modulated complexation by electrochemistry iron tetrakis(p-sulphonatophenyl) porphyrin contaminants treatment in organic solvents |
topic |
modulated complexation by electrochemistry iron tetrakis(p-sulphonatophenyl) porphyrin contaminants treatment in organic solvents |
description |
The treatment of liquid organic phases to remove undesirable compounds is currently a priority in different industries. In oil refinery, it is necessary to reduce sulphur compounds, in gasolines, to below 50 ppm.The traditional form is catalytic hydrodesulphuration; however, this system is not effective for some compounds, e.g., alkyl substituted dibenzothiophenes. The processes for modulated complexation by electrochemistry are based on the capacity of a complexing agent, in a certain oxidation state, to form a bond with the molecule to be removed from a liquid phase. If the contaminant, the solute, is in an organic phase, the complexant must be soluble in aqueous phase. When the complexant is formed and in contact with both phases the contaminant is extracted. In a second stage, the complexing agent is oxidized (or reduced) to a state of less affinity to the contaminant, and the aqueous phase is placed in contact with a new organic phase where the contaminant will be discharged and concentrated. The complexant agent in aqueous phase is reduced (or oxidized) to its state of higher affinity for the contaminant and recirculated to the extraction stage. In this work, we present the conditions necessary for this process to be feasible, the criteria for the selection of the complexes, the methodology for matter balances, determination of energy consumption and thermodynamic calculations, and also three examples of an organic phase: dibenzotiophene, pyridine, and methyl thioether, using as complexing agent iron tetrakis-(p-sulphonatophenyl) porphyrin. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001 |
url |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
http://scielo.pt/scielo.php?script=sci_arttext&pid=S0872-19042007000200001 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
publisher.none.fl_str_mv |
Sociedade Portuguesa de Electroquímica |
dc.source.none.fl_str_mv |
Portugaliae Electrochimica Acta v.25 n.2 2007 reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799137289471787008 |