Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives

Detalhes bibliográficos
Autor(a) principal: Costa, Mariana
Data de Publicação: 2021
Outros Autores: Pinho, Isabel, Loureiro, Monica, Marques, Ana, Simões, Carla, Simoes, Ricardo
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/11110/2230
Resumo: The present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage.
id RCAP_ccf9da03e79a7f441590242cf312a8a0
oai_identifier_str oai:ciencipca.ipca.pt:11110/2230
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str
spelling Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological AdhesivesMicroencapsulationMicrofluidicEco-friendlyAdhesivesThe present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage.Polymer Bulletin2021-11-25T15:30:33Z2021-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/11110/2230oai:ciencipca.ipca.pt:11110/2230engCosta, Mariana; e.a., Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives, Polymer Bulletin (2021) DOI 10.1007/s00289-021-03690-1https://doi.org/10.1007/s00289-021-03690-1http://hdl.handle.net/11110/2230metadata only accessinfo:eu-repo/semantics/openAccessCosta, MarianaPinho, IsabelLoureiro, MonicaMarques, AnaSimões, CarlaSimoes, Ricardoreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-05T12:53:31ZPortal AgregadorONG
dc.title.none.fl_str_mv Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
title Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
spellingShingle Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
Costa, Mariana
Microencapsulation
Microfluidic
Eco-friendly
Adhesives
title_short Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
title_full Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
title_fullStr Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
title_full_unstemmed Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
title_sort Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
author Costa, Mariana
author_facet Costa, Mariana
Pinho, Isabel
Loureiro, Monica
Marques, Ana
Simões, Carla
Simoes, Ricardo
author_role author
author2 Pinho, Isabel
Loureiro, Monica
Marques, Ana
Simões, Carla
Simoes, Ricardo
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Costa, Mariana
Pinho, Isabel
Loureiro, Monica
Marques, Ana
Simões, Carla
Simoes, Ricardo
dc.subject.por.fl_str_mv Microencapsulation
Microfluidic
Eco-friendly
Adhesives
topic Microencapsulation
Microfluidic
Eco-friendly
Adhesives
description The present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage.
publishDate 2021
dc.date.none.fl_str_mv 2021-11-25T15:30:33Z
2021-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/11110/2230
oai:ciencipca.ipca.pt:11110/2230
url http://hdl.handle.net/11110/2230
identifier_str_mv oai:ciencipca.ipca.pt:11110/2230
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Costa, Mariana; e.a., Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives, Polymer Bulletin (2021) DOI 10.1007/s00289-021-03690-1
https://doi.org/10.1007/s00289-021-03690-1
http://hdl.handle.net/11110/2230
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Polymer Bulletin
publisher.none.fl_str_mv Polymer Bulletin
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1777301196689637376

Registros relacionados