Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/116905 |
Resumo: | This research was funded by EUROPEAN UNION'S SEVENTH FRAMEWORK PROGRAMME for research, technological development and demonstration under grant agreement number 245058, by FUNDACAO PARA A CIENCIA E TECNOLOGIA and PORTUGAL 2020 to the Portuguese Mass Spectrometry Network, grant number LISBOA-01-0145-FEDER-402-022125 and by FUNDACAO PARA A CIENCIA E TECNOLOGIA through IF/01337/2014 FCT Investigator contract (MCVP) and research unit GREEN-IT (UID/Multi/04551/2020). |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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7160 |
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Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize breadBroaDehydrodiferuloyl putrescinesDehydrotriferuloyl putrescinesFerulic acidHydroxycinnamic acid amidesMaizeP‐coumaric acidFood ScienceMicrobiologyHealth(social science)Health Professions (miscellaneous)Plant ScienceThis research was funded by EUROPEAN UNION'S SEVENTH FRAMEWORK PROGRAMME for research, technological development and demonstration under grant agreement number 245058, by FUNDACAO PARA A CIENCIA E TECNOLOGIA and PORTUGAL 2020 to the Portuguese Mass Spectrometry Network, grant number LISBOA-01-0145-FEDER-402-022125 and by FUNDACAO PARA A CIENCIA E TECNOLOGIA through IF/01337/2014 FCT Investigator contract (MCVP) and research unit GREEN-IT (UID/Multi/04551/2020).Maize is one of the most interesting dietary sources of hydroxycinnamic acids, widely known for their beneficial health effects, namely antioxidant properties. This work aims to identify hydroxycinnamic acids and their derivatives in broa, a Portuguese traditional ethnic maize bread, and corresponding maize flours. Soluble and insoluble phenolic fractions of diverse maize flours and corresponding broas were prepared and analysed by HPLC‐DAD‐MS/MS (high‐performance liquid chromatography coupled with diode array detector and tandem mass spectrometry). Besides free hydroxycinnamic acids, mainly ferulic and p‐coumaric acids, several structural isomers and stereoisomers of insoluble ferulic acid dehydrodimers (n = 18) and trimers (n = 11), were also identified. Hydroxycinnamic acid amides consisting of coumaroyl and feruloyl conjugates (n = 22) were present in both soluble and insoluble fractions of maize flours and breads, in different isomeric forms. A new compound was putatively identified as bis‐N,N′‐diferuloyl putrescine. Additionally, more complex and insoluble hydroxycinnamic acid amides, derived from ferulic acid dehydrodimers (n = 47) and trimers (n = 18), were also putatively identified for the first time, suggesting that hydroxycinnamic acid amides are also linked to maize cell walls. Since hydroxycinnamic derivatives were not only identified in maize flours, but also in broas, they can contribute to the antioxidant properties and beneficial health effects of maize‐based foods.Instituto de Tecnologia Química e Biológica António Xavier (ITQB)Faculdade de Ciências e Tecnologia (FCT)RUNBento‐Silva, AndreiaDuarte, NoéliaMecha, ElsaBelo, MariaVaz Patto, Maria Carlotado Rosário Bronze, Maria2021-05-03T22:55:45Z2020-10-152020-10-15T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/116905engPURE: 29351141https://doi.org/10.3390/foods9101471info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:59:47Zoai:run.unl.pt:10362/116905Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:43:21.929337Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
title |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
spellingShingle |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread Bento‐Silva, Andreia Broa Dehydrodiferuloyl putrescines Dehydrotriferuloyl putrescines Ferulic acid Hydroxycinnamic acid amides Maize P‐coumaric acid Food Science Microbiology Health(social science) Health Professions (miscellaneous) Plant Science |
title_short |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
title_full |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
title_fullStr |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
title_full_unstemmed |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
title_sort |
Hydroxycinnamic acids and their derivatives in broa, a traditional ethnic maize bread |
author |
Bento‐Silva, Andreia |
author_facet |
Bento‐Silva, Andreia Duarte, Noélia Mecha, Elsa Belo, Maria Vaz Patto, Maria Carlota do Rosário Bronze, Maria |
author_role |
author |
author2 |
Duarte, Noélia Mecha, Elsa Belo, Maria Vaz Patto, Maria Carlota do Rosário Bronze, Maria |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Instituto de Tecnologia Química e Biológica António Xavier (ITQB) Faculdade de Ciências e Tecnologia (FCT) RUN |
dc.contributor.author.fl_str_mv |
Bento‐Silva, Andreia Duarte, Noélia Mecha, Elsa Belo, Maria Vaz Patto, Maria Carlota do Rosário Bronze, Maria |
dc.subject.por.fl_str_mv |
Broa Dehydrodiferuloyl putrescines Dehydrotriferuloyl putrescines Ferulic acid Hydroxycinnamic acid amides Maize P‐coumaric acid Food Science Microbiology Health(social science) Health Professions (miscellaneous) Plant Science |
topic |
Broa Dehydrodiferuloyl putrescines Dehydrotriferuloyl putrescines Ferulic acid Hydroxycinnamic acid amides Maize P‐coumaric acid Food Science Microbiology Health(social science) Health Professions (miscellaneous) Plant Science |
description |
This research was funded by EUROPEAN UNION'S SEVENTH FRAMEWORK PROGRAMME for research, technological development and demonstration under grant agreement number 245058, by FUNDACAO PARA A CIENCIA E TECNOLOGIA and PORTUGAL 2020 to the Portuguese Mass Spectrometry Network, grant number LISBOA-01-0145-FEDER-402-022125 and by FUNDACAO PARA A CIENCIA E TECNOLOGIA through IF/01337/2014 FCT Investigator contract (MCVP) and research unit GREEN-IT (UID/Multi/04551/2020). |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-10-15 2020-10-15T00:00:00Z 2021-05-03T22:55:45Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/116905 |
url |
http://hdl.handle.net/10362/116905 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
PURE: 29351141 https://doi.org/10.3390/foods9101471 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799138043333967872 |