Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries

Detalhes bibliográficos
Autor(a) principal: Gurusamy,Hirankumar
Data de Publicação: 2022
Outros Autores: Ayyasamy,Sakunthala, Bella,Daries
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Matéria (Rio de Janeiro. Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762022000100332
Resumo: ABSTRACT The non-aqueous electrolyte system comprising of the lithium nonafluoro-1-butane sulfonate (LiNfO) as a potential lithium ion-conducting salt in an equivalent binary mixture of propylene carbonate (PC) and 1, 2-dimethoxyethane (DME) as the solvent was explored for the lithium battery applications. The LiNfO based non-aqueous liquid electrolyte (NALE) system showed the highest ionic conductivity of 2.66 x 10-3 S cm-1 at ambient temperature, and a potential window stability of ~5 V. The lithium ion cells, Li/NALE//LiCoO2 were fabricated with the proposed non-aqueous electrolyte. The cell with particular composition of electrolyte delivered a high specific discharge capacity of 154 mA h g-1 at ambient temperature. The potential advantages of the proposed NALE are discussed in detail.
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spelling Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batterieselectrolytelithium ionic conductivityelectrochemical propertiesimpedance spectroscopyABSTRACT The non-aqueous electrolyte system comprising of the lithium nonafluoro-1-butane sulfonate (LiNfO) as a potential lithium ion-conducting salt in an equivalent binary mixture of propylene carbonate (PC) and 1, 2-dimethoxyethane (DME) as the solvent was explored for the lithium battery applications. The LiNfO based non-aqueous liquid electrolyte (NALE) system showed the highest ionic conductivity of 2.66 x 10-3 S cm-1 at ambient temperature, and a potential window stability of ~5 V. The lithium ion cells, Li/NALE//LiCoO2 were fabricated with the proposed non-aqueous electrolyte. The cell with particular composition of electrolyte delivered a high specific discharge capacity of 154 mA h g-1 at ambient temperature. The potential advantages of the proposed NALE are discussed in detail.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22022-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762022000100332Matéria (Rio de Janeiro) v.27 n.1 2022reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620220001.1358info:eu-repo/semantics/openAccessGurusamy,HirankumarAyyasamy,SakunthalaBella,Darieseng2022-05-12T00:00:00Zoai:scielo:S1517-70762022000100332Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2022-05-12T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false
dc.title.none.fl_str_mv Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
title Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
spellingShingle Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
Gurusamy,Hirankumar
electrolyte
lithium ionic conductivity
electrochemical properties
impedance spectroscopy
title_short Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
title_full Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
title_fullStr Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
title_full_unstemmed Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
title_sort Application of lithium nonafluoro-1-butane sulfonate (nonaflate) based non-aqueous liquid electrolytes (NALE) in lithium-ion batteries
author Gurusamy,Hirankumar
author_facet Gurusamy,Hirankumar
Ayyasamy,Sakunthala
Bella,Daries
author_role author
author2 Ayyasamy,Sakunthala
Bella,Daries
author2_role author
author
dc.contributor.author.fl_str_mv Gurusamy,Hirankumar
Ayyasamy,Sakunthala
Bella,Daries
dc.subject.por.fl_str_mv electrolyte
lithium ionic conductivity
electrochemical properties
impedance spectroscopy
topic electrolyte
lithium ionic conductivity
electrochemical properties
impedance spectroscopy
description ABSTRACT The non-aqueous electrolyte system comprising of the lithium nonafluoro-1-butane sulfonate (LiNfO) as a potential lithium ion-conducting salt in an equivalent binary mixture of propylene carbonate (PC) and 1, 2-dimethoxyethane (DME) as the solvent was explored for the lithium battery applications. The LiNfO based non-aqueous liquid electrolyte (NALE) system showed the highest ionic conductivity of 2.66 x 10-3 S cm-1 at ambient temperature, and a potential window stability of ~5 V. The lithium ion cells, Li/NALE//LiCoO2 were fabricated with the proposed non-aqueous electrolyte. The cell with particular composition of electrolyte delivered a high specific discharge capacity of 154 mA h g-1 at ambient temperature. The potential advantages of the proposed NALE are discussed in detail.
publishDate 2022
dc.date.none.fl_str_mv 2022-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762022000100332
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762022000100332
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/s1517-707620220001.1358
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
publisher.none.fl_str_mv Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro
em cooperação com a Associação Brasileira do Hidrogênio, ABH2
dc.source.none.fl_str_mv Matéria (Rio de Janeiro) v.27 n.1 2022
reponame:Matéria (Rio de Janeiro. Online)
instname:Matéria (Rio de Janeiro. Online)
instacron:RLAM
instname_str Matéria (Rio de Janeiro. Online)
instacron_str RLAM
institution RLAM
reponame_str Matéria (Rio de Janeiro. Online)
collection Matéria (Rio de Janeiro. Online)
repository.name.fl_str_mv Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)
repository.mail.fl_str_mv ||materia@labh2.coppe.ufrj.br
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