PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Matéria (Rio de Janeiro. Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762017000200504 |
Resumo: | ABSTRACT In this work, nanobiocomposites of poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) reinforced with cellulose nanofibrils (CNFs) were produced by electrospinning and solution casting process. CNFs were obtained by sulfuric acid hydrolysis from Imperata brasiliensis fibers. Nanocomposites loaded with 1 (wt. %) of CNFs were prepared using a mixture of solvents chloroform (CHCl3): N, N-dimethylformamide (DMF), in the ratio of 78:22 with 30 h of solubilization. Films by solution casting were obtained in a petri dish, at 50 °C for 1 hour, using drying casting temperature of 153 °C. Mats by electrospinning were obtained with a needle 20x10, drum collector rotation 27 rpm, and working distance of 10 cm. Films and mats were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and Differential Scanning Calorimetry (DSC). It was possible to conclude that for nanobiocomposites obtained by solution casting, the addition of CNFs did not affect the transparency of the films, but provided a significant increase in the crystallization rate as observed by DSC analysis, while for electrospinning nanobiocomposites a considerable improvement in process increasing electrospinning time and quality of the mats manufactured, were observed. |
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PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning processcellulose nanofibrilsPHBVelectrospinningsolution castingABSTRACT In this work, nanobiocomposites of poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) reinforced with cellulose nanofibrils (CNFs) were produced by electrospinning and solution casting process. CNFs were obtained by sulfuric acid hydrolysis from Imperata brasiliensis fibers. Nanocomposites loaded with 1 (wt. %) of CNFs were prepared using a mixture of solvents chloroform (CHCl3): N, N-dimethylformamide (DMF), in the ratio of 78:22 with 30 h of solubilization. Films by solution casting were obtained in a petri dish, at 50 °C for 1 hour, using drying casting temperature of 153 °C. Mats by electrospinning were obtained with a needle 20x10, drum collector rotation 27 rpm, and working distance of 10 cm. Films and mats were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and Differential Scanning Calorimetry (DSC). It was possible to conclude that for nanobiocomposites obtained by solution casting, the addition of CNFs did not affect the transparency of the films, but provided a significant increase in the crystallization rate as observed by DSC analysis, while for electrospinning nanobiocomposites a considerable improvement in process increasing electrospinning time and quality of the mats manufactured, were observed.Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiroem cooperação com a Associação Brasileira do Hidrogênio, ABH22017-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762017000200504Matéria (Rio de Janeiro) v.22 n.2 2017reponame:Matéria (Rio de Janeiro. Online)instname:Matéria (Rio de Janeiro. Online)instacron:RLAM10.1590/s1517-707620170002.0170info:eu-repo/semantics/openAccessBenini,Kelly C. C. de CarvalhoCioffi,Maria Odila HilárioVoorwald,Herman Jacobus Corneliseng2017-09-13T00:00:00Zoai:scielo:S1517-70762017000200504Revistahttp://www.materia.coppe.ufrj.br/https://old.scielo.br/oai/scielo-oai.php||materia@labh2.coppe.ufrj.br1517-70761517-7076opendoar:2017-09-13T00:00Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online)false |
dc.title.none.fl_str_mv |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
title |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
spellingShingle |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process Benini,Kelly C. C. de Carvalho cellulose nanofibrils PHBV electrospinning solution casting |
title_short |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
title_full |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
title_fullStr |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
title_full_unstemmed |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
title_sort |
PHBV/cellulose nanofibrils composites obtained by solution casting and electrospinning process |
author |
Benini,Kelly C. C. de Carvalho |
author_facet |
Benini,Kelly C. C. de Carvalho Cioffi,Maria Odila Hilário Voorwald,Herman Jacobus Cornelis |
author_role |
author |
author2 |
Cioffi,Maria Odila Hilário Voorwald,Herman Jacobus Cornelis |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Benini,Kelly C. C. de Carvalho Cioffi,Maria Odila Hilário Voorwald,Herman Jacobus Cornelis |
dc.subject.por.fl_str_mv |
cellulose nanofibrils PHBV electrospinning solution casting |
topic |
cellulose nanofibrils PHBV electrospinning solution casting |
description |
ABSTRACT In this work, nanobiocomposites of poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) reinforced with cellulose nanofibrils (CNFs) were produced by electrospinning and solution casting process. CNFs were obtained by sulfuric acid hydrolysis from Imperata brasiliensis fibers. Nanocomposites loaded with 1 (wt. %) of CNFs were prepared using a mixture of solvents chloroform (CHCl3): N, N-dimethylformamide (DMF), in the ratio of 78:22 with 30 h of solubilization. Films by solution casting were obtained in a petri dish, at 50 °C for 1 hour, using drying casting temperature of 153 °C. Mats by electrospinning were obtained with a needle 20x10, drum collector rotation 27 rpm, and working distance of 10 cm. Films and mats were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and Differential Scanning Calorimetry (DSC). It was possible to conclude that for nanobiocomposites obtained by solution casting, the addition of CNFs did not affect the transparency of the films, but provided a significant increase in the crystallization rate as observed by DSC analysis, while for electrospinning nanobiocomposites a considerable improvement in process increasing electrospinning time and quality of the mats manufactured, were observed. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762017000200504 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S1517-70762017000200504 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/s1517-707620170002.0170 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
publisher.none.fl_str_mv |
Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro em cooperação com a Associação Brasileira do Hidrogênio, ABH2 |
dc.source.none.fl_str_mv |
Matéria (Rio de Janeiro) v.22 n.2 2017 reponame:Matéria (Rio de Janeiro. Online) instname:Matéria (Rio de Janeiro. Online) instacron:RLAM |
instname_str |
Matéria (Rio de Janeiro. Online) |
instacron_str |
RLAM |
institution |
RLAM |
reponame_str |
Matéria (Rio de Janeiro. Online) |
collection |
Matéria (Rio de Janeiro. Online) |
repository.name.fl_str_mv |
Matéria (Rio de Janeiro. Online) - Matéria (Rio de Janeiro. Online) |
repository.mail.fl_str_mv |
||materia@labh2.coppe.ufrj.br |
_version_ |
1752126689749499904 |