Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols

Detalhes bibliográficos
Autor(a) principal: Narayanaperumal,Senthil
Data de Publicação: 2012
Outros Autores: Silva,Rodrigo César da, Monteiro,Julia L., Corrêa,Arlene G., Paixão,Márcio W.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012001100004
Resumo: In this work, the use of ferric chloride as an efficient catalyst in glycosylation reactions of sugars in the presence of allyl and alkynyl alcohols is described. The corresponding glycosides were obtained with moderate to good yields. This new procedure presented greater selectivity when compared to classic methods found in the literature. Principal features of this simple method include non-hazardous reaction conditions, low-catalyst loading, good yields and high anomeric selectivity.
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spelling Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcoholsglycosylationiron(III) chloridestereoselectivecarbohydrategreen chemistryIn this work, the use of ferric chloride as an efficient catalyst in glycosylation reactions of sugars in the presence of allyl and alkynyl alcohols is described. The corresponding glycosides were obtained with moderate to good yields. This new procedure presented greater selectivity when compared to classic methods found in the literature. Principal features of this simple method include non-hazardous reaction conditions, low-catalyst loading, good yields and high anomeric selectivity.Sociedade Brasileira de Química2012-11-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012001100004Journal of the Brazilian Chemical Society v.23 n.11 2012reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532012005000070info:eu-repo/semantics/openAccessNarayanaperumal,SenthilSilva,Rodrigo César daMonteiro,Julia L.Corrêa,Arlene G.Paixão,Márcio W.eng2013-01-03T00:00:00Zoai:scielo:S0103-50532012001100004Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2013-01-03T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
title Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
spellingShingle Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
Narayanaperumal,Senthil
glycosylation
iron(III) chloride
stereoselective
carbohydrate
green chemistry
title_short Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
title_full Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
title_fullStr Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
title_full_unstemmed Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
title_sort Iron(III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
author Narayanaperumal,Senthil
author_facet Narayanaperumal,Senthil
Silva,Rodrigo César da
Monteiro,Julia L.
Corrêa,Arlene G.
Paixão,Márcio W.
author_role author
author2 Silva,Rodrigo César da
Monteiro,Julia L.
Corrêa,Arlene G.
Paixão,Márcio W.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Narayanaperumal,Senthil
Silva,Rodrigo César da
Monteiro,Julia L.
Corrêa,Arlene G.
Paixão,Márcio W.
dc.subject.por.fl_str_mv glycosylation
iron(III) chloride
stereoselective
carbohydrate
green chemistry
topic glycosylation
iron(III) chloride
stereoselective
carbohydrate
green chemistry
description In this work, the use of ferric chloride as an efficient catalyst in glycosylation reactions of sugars in the presence of allyl and alkynyl alcohols is described. The corresponding glycosides were obtained with moderate to good yields. This new procedure presented greater selectivity when compared to classic methods found in the literature. Principal features of this simple method include non-hazardous reaction conditions, low-catalyst loading, good yields and high anomeric selectivity.
publishDate 2012
dc.date.none.fl_str_mv 2012-11-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012001100004
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012001100004
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532012005000070
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.23 n.11 2012
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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