Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000400017 |
Resumo: | A sample preparation procedure based on the solid phase extraction and the two-step elution was developed for the determination of the total concentrations of Ca and Mg in bee honeys. The honey samples were treated as follows: the 5.0% (m/v) sample solutions (50 mL) were passed at the flow rate of 20 mL min-1 through the resin beds of Dowex 50W×8-400 to retain the Ca(II) and Mg(II) ions and separate them from the matrix of glucose and fructose in addition to the anionic minerals. Afterwards, 20 mL of a 0.5 mol L-1 HNO3 solution was used to remove the K and Na ions. Finally, Ca and Mg were eluted prior to the measurements of their concentrations by flame atomic absorption spectrometry (FAAS) using 5 mL of a 2.0 mol L-1 HCl solution. The proposed sample preparation procedure was fast (30 min) and enabled to measure the concentrations of Ca and Mg in honey with the precision of 1-5% and the accuracy of 1-3%. The limits of detection of 24 ng g-1 of Ca and 4.4 ng g-1 of Mg were obtained for FAAS with this procedure. |
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Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometryCaMghoneyFAASsolid phase extractionion exchangesequential elutionA sample preparation procedure based on the solid phase extraction and the two-step elution was developed for the determination of the total concentrations of Ca and Mg in bee honeys. The honey samples were treated as follows: the 5.0% (m/v) sample solutions (50 mL) were passed at the flow rate of 20 mL min-1 through the resin beds of Dowex 50W×8-400 to retain the Ca(II) and Mg(II) ions and separate them from the matrix of glucose and fructose in addition to the anionic minerals. Afterwards, 20 mL of a 0.5 mol L-1 HNO3 solution was used to remove the K and Na ions. Finally, Ca and Mg were eluted prior to the measurements of their concentrations by flame atomic absorption spectrometry (FAAS) using 5 mL of a 2.0 mol L-1 HCl solution. The proposed sample preparation procedure was fast (30 min) and enabled to measure the concentrations of Ca and Mg in honey with the precision of 1-5% and the accuracy of 1-3%. The limits of detection of 24 ng g-1 of Ca and 4.4 ng g-1 of Mg were obtained for FAAS with this procedure.Sociedade Brasileira de Química2012-04-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000400017Journal of the Brazilian Chemical Society v.23 n.4 2012reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532012000400017info:eu-repo/semantics/openAccessPohl,PawelStecka,HelenaJamroz,Piotreng2012-04-27T00:00:00Zoai:scielo:S0103-50532012000400017Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2012-04-27T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
title |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
spellingShingle |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry Pohl,Pawel Ca Mg honey FAAS solid phase extraction ion exchange sequential elution |
title_short |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
title_full |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
title_fullStr |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
title_full_unstemmed |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
title_sort |
Fast and interference free determination of calcium and magnesium in honeys by solid phase extraction followed by flame atomic absorption spectrometry |
author |
Pohl,Pawel |
author_facet |
Pohl,Pawel Stecka,Helena Jamroz,Piotr |
author_role |
author |
author2 |
Stecka,Helena Jamroz,Piotr |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Pohl,Pawel Stecka,Helena Jamroz,Piotr |
dc.subject.por.fl_str_mv |
Ca Mg honey FAAS solid phase extraction ion exchange sequential elution |
topic |
Ca Mg honey FAAS solid phase extraction ion exchange sequential elution |
description |
A sample preparation procedure based on the solid phase extraction and the two-step elution was developed for the determination of the total concentrations of Ca and Mg in bee honeys. The honey samples were treated as follows: the 5.0% (m/v) sample solutions (50 mL) were passed at the flow rate of 20 mL min-1 through the resin beds of Dowex 50W×8-400 to retain the Ca(II) and Mg(II) ions and separate them from the matrix of glucose and fructose in addition to the anionic minerals. Afterwards, 20 mL of a 0.5 mol L-1 HNO3 solution was used to remove the K and Na ions. Finally, Ca and Mg were eluted prior to the measurements of their concentrations by flame atomic absorption spectrometry (FAAS) using 5 mL of a 2.0 mol L-1 HCl solution. The proposed sample preparation procedure was fast (30 min) and enabled to measure the concentrations of Ca and Mg in honey with the precision of 1-5% and the accuracy of 1-3%. The limits of detection of 24 ng g-1 of Ca and 4.4 ng g-1 of Mg were obtained for FAAS with this procedure. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-04-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000400017 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532012000400017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532012000400017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.23 n.4 2012 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318173163356160 |