Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2
Autor(a) principal: | |
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Data de Publicação: | 1998 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600004 |
Resumo: | The present paper describes a procedure for separation, preconcentration and sequential determination of trace amounts of copper and zinc in natural water samples, by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The proposed method is based on the complexation of copper(II) and zinc(II) ions by 1-(2-thiazolylazo)-2-naphthol (TAN) and sorption on to Amberlite XAD-2 resin. Parameters such as: TAN amount, pH effect on the complexation and sorption of TAN complexes, agitation time for complete sorption, concentration of metal ion, mass of Amberlite XAD-2, desorption of metal ions from XAD-2 resin and sample volume were studied. The results demonstrated that the copper(II) and zinc(II) ions, in the range of 0.10 to 100.00 mug, contained in a solution sample volume of 400 mL, in the pH range of 5.7 to 8.3, on the form of TAN complexes had been quantitatively retained on to XAD-2 resin. The shaking time required for sorption is 1 h using a resin mass of 1.4 g. The solution for determination of copper and zinc by ICP-AES is obtained, after desorption of the ions from the XAD-2 resin, using 5 mL of 2 mol L-1 hydrochloric acid and shaking the system for 5 min. The procedure was applied to the determination of copper and zinc in several natural water samples. The standard addition technique was applied and the obtained recoveries revealed that the proposed procedure has a good accuracy. A high enrichment factor (80) and simplicity are the main advantages in this analytical protocol. |
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Journal of the Brazilian Chemical Society (Online) |
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Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2copper preconcentrationzinc preconcentrationsolid-phase extractionAmberlite XAD-2natural waterThe present paper describes a procedure for separation, preconcentration and sequential determination of trace amounts of copper and zinc in natural water samples, by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The proposed method is based on the complexation of copper(II) and zinc(II) ions by 1-(2-thiazolylazo)-2-naphthol (TAN) and sorption on to Amberlite XAD-2 resin. Parameters such as: TAN amount, pH effect on the complexation and sorption of TAN complexes, agitation time for complete sorption, concentration of metal ion, mass of Amberlite XAD-2, desorption of metal ions from XAD-2 resin and sample volume were studied. The results demonstrated that the copper(II) and zinc(II) ions, in the range of 0.10 to 100.00 mug, contained in a solution sample volume of 400 mL, in the pH range of 5.7 to 8.3, on the form of TAN complexes had been quantitatively retained on to XAD-2 resin. The shaking time required for sorption is 1 h using a resin mass of 1.4 g. The solution for determination of copper and zinc by ICP-AES is obtained, after desorption of the ions from the XAD-2 resin, using 5 mL of 2 mol L-1 hydrochloric acid and shaking the system for 5 min. The procedure was applied to the determination of copper and zinc in several natural water samples. The standard addition technique was applied and the obtained recoveries revealed that the proposed procedure has a good accuracy. A high enrichment factor (80) and simplicity are the main advantages in this analytical protocol.Sociedade Brasileira de Química1998-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600004Journal of the Brazilian Chemical Society v.9 n.6 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000600004info:eu-repo/semantics/openAccessFerreira,Sérgio Luis CostaSantos,Hilda Costa dosFerreira,Janeide ReisAraújo,Neyla Margarida Lopo deCosta,Antônio Celso SpinolaJesus,Djane Santiago deeng2002-10-25T00:00:00Zoai:scielo:S0103-50531998000600004Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-10-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
title |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
spellingShingle |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 Ferreira,Sérgio Luis Costa copper preconcentration zinc preconcentration solid-phase extraction Amberlite XAD-2 natural water |
title_short |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
title_full |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
title_fullStr |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
title_full_unstemmed |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
title_sort |
Preconcentration and Determination of Copper and Zinc in Natural Water Samples by ICP-AES After Complexation and Sorption on Amberlite XAD-2 |
author |
Ferreira,Sérgio Luis Costa |
author_facet |
Ferreira,Sérgio Luis Costa Santos,Hilda Costa dos Ferreira,Janeide Reis Araújo,Neyla Margarida Lopo de Costa,Antônio Celso Spinola Jesus,Djane Santiago de |
author_role |
author |
author2 |
Santos,Hilda Costa dos Ferreira,Janeide Reis Araújo,Neyla Margarida Lopo de Costa,Antônio Celso Spinola Jesus,Djane Santiago de |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Ferreira,Sérgio Luis Costa Santos,Hilda Costa dos Ferreira,Janeide Reis Araújo,Neyla Margarida Lopo de Costa,Antônio Celso Spinola Jesus,Djane Santiago de |
dc.subject.por.fl_str_mv |
copper preconcentration zinc preconcentration solid-phase extraction Amberlite XAD-2 natural water |
topic |
copper preconcentration zinc preconcentration solid-phase extraction Amberlite XAD-2 natural water |
description |
The present paper describes a procedure for separation, preconcentration and sequential determination of trace amounts of copper and zinc in natural water samples, by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The proposed method is based on the complexation of copper(II) and zinc(II) ions by 1-(2-thiazolylazo)-2-naphthol (TAN) and sorption on to Amberlite XAD-2 resin. Parameters such as: TAN amount, pH effect on the complexation and sorption of TAN complexes, agitation time for complete sorption, concentration of metal ion, mass of Amberlite XAD-2, desorption of metal ions from XAD-2 resin and sample volume were studied. The results demonstrated that the copper(II) and zinc(II) ions, in the range of 0.10 to 100.00 mug, contained in a solution sample volume of 400 mL, in the pH range of 5.7 to 8.3, on the form of TAN complexes had been quantitatively retained on to XAD-2 resin. The shaking time required for sorption is 1 h using a resin mass of 1.4 g. The solution for determination of copper and zinc by ICP-AES is obtained, after desorption of the ions from the XAD-2 resin, using 5 mL of 2 mol L-1 hydrochloric acid and shaking the system for 5 min. The procedure was applied to the determination of copper and zinc in several natural water samples. The standard addition technique was applied and the obtained recoveries revealed that the proposed procedure has a good accuracy. A high enrichment factor (80) and simplicity are the main advantages in this analytical protocol. |
publishDate |
1998 |
dc.date.none.fl_str_mv |
1998-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600004 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000600004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50531998000600004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.9 n.6 1998 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
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1750318163449348096 |