Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina
Main Author: | |
---|---|
Publication Date: | 2017 |
Other Authors: | , , , , , , |
Format: | Article |
Language: | eng |
Source: | Journal of the Brazilian Chemical Society (Online) |
Download full: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000200336 |
Summary: | This work deals with preparation and characterization of H3PW12O40 (H3PW) supported on silica-alumina. Impregnation of H3PW (15, 20, 30 and 40 wt.%) on commercial silica-alumina support in acidic aqueous solution is effective for preparing this catalyst keeping its Keggin structure, according to different methods of characterization. The catalysts were tested in a model reaction of acetic acid with ethanol and 30 wt.% H3PW/SiO2-Al2O3 had the highest activity under the conditions: catalyst calcination at 300 ºC, temperature of 100 ºC, acetic acid:ethanol molar ratio of 2:1 and catalyst:acetic acid mass ratio of 10 wt.%. The reaction yield was 79 and 100% selectivity for ethyl acetate over three reutilizations, for reaction time of 2 h. The calculated total acid site distribution was 0.299 mmol g-1 (97% of the theoretical probed by pyridine), and most of these (0.236 mmol g-1) were Brønsted weak-medium strength (pyridine desorption between 300 and 500 ºC). |
id |
SBQ-2_b3e387514e344e9dcc4f5ec7187ca4e5 |
---|---|
oai_identifier_str |
oai:scielo:S0103-50532017000200336 |
network_acronym_str |
SBQ-2 |
network_name_str |
Journal of the Brazilian Chemical Society (Online) |
repository_id_str |
|
spelling |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Aluminasupported heteropolyacid12-tungstophosphoric acidsilica-aluminaethanolesterification of acetic acid with ethanolThis work deals with preparation and characterization of H3PW12O40 (H3PW) supported on silica-alumina. Impregnation of H3PW (15, 20, 30 and 40 wt.%) on commercial silica-alumina support in acidic aqueous solution is effective for preparing this catalyst keeping its Keggin structure, according to different methods of characterization. The catalysts were tested in a model reaction of acetic acid with ethanol and 30 wt.% H3PW/SiO2-Al2O3 had the highest activity under the conditions: catalyst calcination at 300 ºC, temperature of 100 ºC, acetic acid:ethanol molar ratio of 2:1 and catalyst:acetic acid mass ratio of 10 wt.%. The reaction yield was 79 and 100% selectivity for ethyl acetate over three reutilizations, for reaction time of 2 h. The calculated total acid site distribution was 0.299 mmol g-1 (97% of the theoretical probed by pyridine), and most of these (0.236 mmol g-1) were Brønsted weak-medium strength (pyridine desorption between 300 and 500 ºC).Sociedade Brasileira de Química2017-02-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000200336Journal of the Brazilian Chemical Society v.28 n.2 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20160183info:eu-repo/semantics/openAccessMattos,Flávia C. G. deCarvalho,Eduardo N. C. B. deFreitas,Elon F. dePaiva,Mateus F.Ghesti,Grace F.Macedo,Julio L. deDias,Sílvia C. L.Dias,José A.eng2017-01-10T00:00:00Zoai:scielo:S0103-50532017000200336Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-01-10T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
title |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
spellingShingle |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina Mattos,Flávia C. G. de supported heteropolyacid 12-tungstophosphoric acid silica-alumina ethanol esterification of acetic acid with ethanol |
title_short |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
title_full |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
title_fullStr |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
title_full_unstemmed |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
title_sort |
Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica-Alumina |
author |
Mattos,Flávia C. G. de |
author_facet |
Mattos,Flávia C. G. de Carvalho,Eduardo N. C. B. de Freitas,Elon F. de Paiva,Mateus F. Ghesti,Grace F. Macedo,Julio L. de Dias,Sílvia C. L. Dias,José A. |
author_role |
author |
author2 |
Carvalho,Eduardo N. C. B. de Freitas,Elon F. de Paiva,Mateus F. Ghesti,Grace F. Macedo,Julio L. de Dias,Sílvia C. L. Dias,José A. |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Mattos,Flávia C. G. de Carvalho,Eduardo N. C. B. de Freitas,Elon F. de Paiva,Mateus F. Ghesti,Grace F. Macedo,Julio L. de Dias,Sílvia C. L. Dias,José A. |
dc.subject.por.fl_str_mv |
supported heteropolyacid 12-tungstophosphoric acid silica-alumina ethanol esterification of acetic acid with ethanol |
topic |
supported heteropolyacid 12-tungstophosphoric acid silica-alumina ethanol esterification of acetic acid with ethanol |
description |
This work deals with preparation and characterization of H3PW12O40 (H3PW) supported on silica-alumina. Impregnation of H3PW (15, 20, 30 and 40 wt.%) on commercial silica-alumina support in acidic aqueous solution is effective for preparing this catalyst keeping its Keggin structure, according to different methods of characterization. The catalysts were tested in a model reaction of acetic acid with ethanol and 30 wt.% H3PW/SiO2-Al2O3 had the highest activity under the conditions: catalyst calcination at 300 ºC, temperature of 100 ºC, acetic acid:ethanol molar ratio of 2:1 and catalyst:acetic acid mass ratio of 10 wt.%. The reaction yield was 79 and 100% selectivity for ethyl acetate over three reutilizations, for reaction time of 2 h. The calculated total acid site distribution was 0.299 mmol g-1 (97% of the theoretical probed by pyridine), and most of these (0.236 mmol g-1) were Brønsted weak-medium strength (pyridine desorption between 300 and 500 ºC). |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-02-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000200336 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000200336 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20160183 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.28 n.2 2017 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318179172745216 |