Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901657 |
Resumo: | A method for digestion of plastics from waste of electrical and electronic equipment (WEEE) was developed using the microwave-assisted wet digestion in single reaction chamber (MAWD-SRC). The determination of As, Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES) was carried out after sample digestion. Mercury was determined by flow-injection cold vapor generation coupled to inductively coupled plasma mass spectrometry (FI-CVG-ICP-MS). Results obtained using MAWD-SRC for sample preparation were compared with those obtained using microwave-assisted wet digestion (MAWD) at high pressure. Acid mixtures (HNO3 or HNO3 + HCl) were evaluated and feasibility for further inorganic contaminants determination by ICP-MS and ICP OES was demonstrated. Sample preparation by MAWD-SRC using HNO3 + HCl mixture resulted in better digestion efficiency in comparison to MAWD. In addition, lower limits of quantification were obtained using MAWD-SRC due to the higher sample mass that can be digested (500 mg). The combination of HNO3 and HCl for digestion showed to be crucial for quantitative recovery of some elements, as Cr and Sb. Agreement with certified values was better than 96%. |
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Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction ChamberWEEEsample preparationcontaminantsspectrometric techniquesRoHS DirectiveA method for digestion of plastics from waste of electrical and electronic equipment (WEEE) was developed using the microwave-assisted wet digestion in single reaction chamber (MAWD-SRC). The determination of As, Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES) was carried out after sample digestion. Mercury was determined by flow-injection cold vapor generation coupled to inductively coupled plasma mass spectrometry (FI-CVG-ICP-MS). Results obtained using MAWD-SRC for sample preparation were compared with those obtained using microwave-assisted wet digestion (MAWD) at high pressure. Acid mixtures (HNO3 or HNO3 + HCl) were evaluated and feasibility for further inorganic contaminants determination by ICP-MS and ICP OES was demonstrated. Sample preparation by MAWD-SRC using HNO3 + HCl mixture resulted in better digestion efficiency in comparison to MAWD. In addition, lower limits of quantification were obtained using MAWD-SRC due to the higher sample mass that can be digested (500 mg). The combination of HNO3 and HCl for digestion showed to be crucial for quantitative recovery of some elements, as Cr and Sb. Agreement with certified values was better than 96%.Sociedade Brasileira de Química2017-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901657Journal of the Brazilian Chemical Society v.28 n.9 2017reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20160317info:eu-repo/semantics/openAccessOliveira,Jussiane S. S.Krzyzaniak,Sindy R.Picoloto,Rochele S.Bolzan,Rodrigo C.Mello,Paola A.eng2017-07-28T00:00:00Zoai:scielo:S0103-50532017000901657Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2017-07-28T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
title |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
spellingShingle |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber Oliveira,Jussiane S. S. WEEE sample preparation contaminants spectrometric techniques RoHS Directive |
title_short |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
title_full |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
title_fullStr |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
title_full_unstemmed |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
title_sort |
Determination of Inorganic Contaminants in Electrical and Electronic Equipment after Digestion Using Microwave-Assisted Single Reaction Chamber |
author |
Oliveira,Jussiane S. S. |
author_facet |
Oliveira,Jussiane S. S. Krzyzaniak,Sindy R. Picoloto,Rochele S. Bolzan,Rodrigo C. Mello,Paola A. |
author_role |
author |
author2 |
Krzyzaniak,Sindy R. Picoloto,Rochele S. Bolzan,Rodrigo C. Mello,Paola A. |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Oliveira,Jussiane S. S. Krzyzaniak,Sindy R. Picoloto,Rochele S. Bolzan,Rodrigo C. Mello,Paola A. |
dc.subject.por.fl_str_mv |
WEEE sample preparation contaminants spectrometric techniques RoHS Directive |
topic |
WEEE sample preparation contaminants spectrometric techniques RoHS Directive |
description |
A method for digestion of plastics from waste of electrical and electronic equipment (WEEE) was developed using the microwave-assisted wet digestion in single reaction chamber (MAWD-SRC). The determination of As, Cd, Co, Cr, Cu, Ni, Pb, Sb and Zn by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES) was carried out after sample digestion. Mercury was determined by flow-injection cold vapor generation coupled to inductively coupled plasma mass spectrometry (FI-CVG-ICP-MS). Results obtained using MAWD-SRC for sample preparation were compared with those obtained using microwave-assisted wet digestion (MAWD) at high pressure. Acid mixtures (HNO3 or HNO3 + HCl) were evaluated and feasibility for further inorganic contaminants determination by ICP-MS and ICP OES was demonstrated. Sample preparation by MAWD-SRC using HNO3 + HCl mixture resulted in better digestion efficiency in comparison to MAWD. In addition, lower limits of quantification were obtained using MAWD-SRC due to the higher sample mass that can be digested (500 mg). The combination of HNO3 and HCl for digestion showed to be crucial for quantitative recovery of some elements, as Cr and Sb. Agreement with certified values was better than 96%. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-09-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901657 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532017000901657 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.21577/0103-5053.20160317 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.28 n.9 2017 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
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1750318179936108544 |