Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil

Detalhes bibliográficos
Autor(a) principal: Machado,Mauro C. S.
Data de Publicação: 2009
Outros Autores: Loyola,Josiane, Quiterio,Simone L., Rocha,Gisele O. da, Andrade,Jailson B. de, Arbilla,Graciela
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000900002
Resumo: Total particulate matter and PM10 samples were collected from August 2006 to February 2007 in Mayor José Carlos Lacerda bus station. 16 priority PAHs compounds emitted by heavy-duty vehicles on typical conditions of operation were analyzed by using GC/MS. ΣPAH accounted for 0.0018% of the TSP mass and 0.0012% of the PM10 mass. Total PAH contents on the particle phase were 3.57 ng m-3 and 2.59 ng m-3 for TSP and PM10, respectively. Contributions of carcinogenic USEPA priority PAHs (B[a]An, B[b]F, B[k]F, B[a]Py, IPy and DB[ah]A) were 1.86 ng m-3 (52% of total PAHs) and 1.40 ng m-3 (54% of total PAHs), for TSP and PM10 samples, respectively. Diagnostic ratios and multivariate statistical analysis were, in general, similar to those reported for soil dust except for the Flt/Flt+Py) ratio, 0.34, compatible with diesel emissions. Dry deposition fluxes were in the range of 0.022-0.603 and 0.016-0.436 μg m-2 day-1 for compounds in TSP and PM10, respectively.
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spelling Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazilpolycyclic aromatic hydrocarbonsTSPPM10diagnostic ratiosbus stationdry depositiondiesel emissionsTotal particulate matter and PM10 samples were collected from August 2006 to February 2007 in Mayor José Carlos Lacerda bus station. 16 priority PAHs compounds emitted by heavy-duty vehicles on typical conditions of operation were analyzed by using GC/MS. ΣPAH accounted for 0.0018% of the TSP mass and 0.0012% of the PM10 mass. Total PAH contents on the particle phase were 3.57 ng m-3 and 2.59 ng m-3 for TSP and PM10, respectively. Contributions of carcinogenic USEPA priority PAHs (B[a]An, B[b]F, B[k]F, B[a]Py, IPy and DB[ah]A) were 1.86 ng m-3 (52% of total PAHs) and 1.40 ng m-3 (54% of total PAHs), for TSP and PM10 samples, respectively. Diagnostic ratios and multivariate statistical analysis were, in general, similar to those reported for soil dust except for the Flt/Flt+Py) ratio, 0.34, compatible with diesel emissions. Dry deposition fluxes were in the range of 0.022-0.603 and 0.016-0.436 μg m-2 day-1 for compounds in TSP and PM10, respectively.Sociedade Brasileira de Química2009-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000900002Journal of the Brazilian Chemical Society v.20 n.9 2009reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532009000900002info:eu-repo/semantics/openAccessMachado,Mauro C. S.Loyola,JosianeQuiterio,Simone L.Rocha,Gisele O. daAndrade,Jailson B. deArbilla,Gracielaeng2011-10-14T00:00:00Zoai:scielo:S0103-50532009000900002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2011-10-14T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
title Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
spellingShingle Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
Machado,Mauro C. S.
polycyclic aromatic hydrocarbons
TSP
PM10
diagnostic ratios
bus station
dry deposition
diesel emissions
title_short Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
title_full Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
title_fullStr Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
title_full_unstemmed Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
title_sort Particle-associated polycyclic aromatic hydrocarbons and their dry deposition fluxes from a bus-station in the Rio de Janeiro metropolitan area, Brazil
author Machado,Mauro C. S.
author_facet Machado,Mauro C. S.
Loyola,Josiane
Quiterio,Simone L.
Rocha,Gisele O. da
Andrade,Jailson B. de
Arbilla,Graciela
author_role author
author2 Loyola,Josiane
Quiterio,Simone L.
Rocha,Gisele O. da
Andrade,Jailson B. de
Arbilla,Graciela
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Machado,Mauro C. S.
Loyola,Josiane
Quiterio,Simone L.
Rocha,Gisele O. da
Andrade,Jailson B. de
Arbilla,Graciela
dc.subject.por.fl_str_mv polycyclic aromatic hydrocarbons
TSP
PM10
diagnostic ratios
bus station
dry deposition
diesel emissions
topic polycyclic aromatic hydrocarbons
TSP
PM10
diagnostic ratios
bus station
dry deposition
diesel emissions
description Total particulate matter and PM10 samples were collected from August 2006 to February 2007 in Mayor José Carlos Lacerda bus station. 16 priority PAHs compounds emitted by heavy-duty vehicles on typical conditions of operation were analyzed by using GC/MS. ΣPAH accounted for 0.0018% of the TSP mass and 0.0012% of the PM10 mass. Total PAH contents on the particle phase were 3.57 ng m-3 and 2.59 ng m-3 for TSP and PM10, respectively. Contributions of carcinogenic USEPA priority PAHs (B[a]An, B[b]F, B[k]F, B[a]Py, IPy and DB[ah]A) were 1.86 ng m-3 (52% of total PAHs) and 1.40 ng m-3 (54% of total PAHs), for TSP and PM10 samples, respectively. Diagnostic ratios and multivariate statistical analysis were, in general, similar to those reported for soil dust except for the Flt/Flt+Py) ratio, 0.34, compatible with diesel emissions. Dry deposition fluxes were in the range of 0.022-0.603 and 0.016-0.436 μg m-2 day-1 for compounds in TSP and PM10, respectively.
publishDate 2009
dc.date.none.fl_str_mv 2009-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000900002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000900002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532009000900002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.20 n.9 2009
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
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instname_str Sociedade Brasileira de Química (SBQ)
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reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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