Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics

Detalhes bibliográficos
Autor(a) principal: Silva,Maurício A.P.
Data de Publicação: 2002
Outros Autores: Messaddeq,Younes, Briois,Valerie, Poulain,Marcel, Ribeiro,Sidney J. L.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200011
Resumo: The vitreous domain was established in the PbF2-CdF2-B2O 3 system from melting and quenching experiments. Er3+ containing glasses were prepared and glass ceramics were obtained by selected heat-treatments. Lead fluoride was identified (beta-PbF2) as the crystalline phase. Structural studies were performed in some glassy and partially crystallized samples by means of X-ray Diffraction (XRD) and Extended X-ray Absorption Fine Structure (EXAFS) measurements. The role of Cd2+ and Pb2+ atoms on the glass network formation and also on the crystallization behavior was put forward by these techniques. After crystallization Er3+ atoms segregated in the crystal phase.
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spelling Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramicsoxifluoride glassesglass-ceramicsx-ray absorption spectroscopyThe vitreous domain was established in the PbF2-CdF2-B2O 3 system from melting and quenching experiments. Er3+ containing glasses were prepared and glass ceramics were obtained by selected heat-treatments. Lead fluoride was identified (beta-PbF2) as the crystalline phase. Structural studies were performed in some glassy and partially crystallized samples by means of X-ray Diffraction (XRD) and Extended X-ray Absorption Fine Structure (EXAFS) measurements. The role of Cd2+ and Pb2+ atoms on the glass network formation and also on the crystallization behavior was put forward by these techniques. After crystallization Er3+ atoms segregated in the crystal phase.Sociedade Brasileira de Química2002-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200011Journal of the Brazilian Chemical Society v.13 n.2 2002reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532002000200011info:eu-repo/semantics/openAccessSilva,Maurício A.P.Messaddeq,YounesBriois,ValeriePoulain,MarcelRibeiro,Sidney J. L.eng2002-06-25T00:00:00Zoai:scielo:S0103-50532002000200011Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-06-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
title Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
spellingShingle Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
Silva,Maurício A.P.
oxifluoride glasses
glass-ceramics
x-ray absorption spectroscopy
title_short Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
title_full Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
title_fullStr Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
title_full_unstemmed Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
title_sort Synthesis and Structural Studies of Er3+ Containing Lead Cadmium Fluoroborate Glasses and Glass-Ceramics
author Silva,Maurício A.P.
author_facet Silva,Maurício A.P.
Messaddeq,Younes
Briois,Valerie
Poulain,Marcel
Ribeiro,Sidney J. L.
author_role author
author2 Messaddeq,Younes
Briois,Valerie
Poulain,Marcel
Ribeiro,Sidney J. L.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Silva,Maurício A.P.
Messaddeq,Younes
Briois,Valerie
Poulain,Marcel
Ribeiro,Sidney J. L.
dc.subject.por.fl_str_mv oxifluoride glasses
glass-ceramics
x-ray absorption spectroscopy
topic oxifluoride glasses
glass-ceramics
x-ray absorption spectroscopy
description The vitreous domain was established in the PbF2-CdF2-B2O 3 system from melting and quenching experiments. Er3+ containing glasses were prepared and glass ceramics were obtained by selected heat-treatments. Lead fluoride was identified (beta-PbF2) as the crystalline phase. Structural studies were performed in some glassy and partially crystallized samples by means of X-ray Diffraction (XRD) and Extended X-ray Absorption Fine Structure (EXAFS) measurements. The role of Cd2+ and Pb2+ atoms on the glass network formation and also on the crystallization behavior was put forward by these techniques. After crystallization Er3+ atoms segregated in the crystal phase.
publishDate 2002
dc.date.none.fl_str_mv 2002-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200011
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200011
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532002000200011
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.13 n.2 2002
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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