Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design
Main Author: | |
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Publication Date: | 2013 |
Other Authors: | , , , , |
Format: | Article |
Language: | eng |
Source: | Journal of the Brazilian Chemical Society (Online) |
Download full: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300016 |
Summary: | An optimization procedure for the extraction of the herbicide atrazine (AT), and the main degradation products deethylatrazine (DEA) and deisopropylatrazine (DIA) from an oxisol soil sample was carried out, for a soil from the Southwest of Paraná State in Brazil, where AT is among the most largely employed herbicide. A comparison between shaking and ultrasound extraction was performed, to define a simple and fast extraction procedure, followed by the quantification using high performance liquid chromatography. It is important to inform that a factorial planning was employed, that was very important to define the best conditions of extraction by shaking. Appropriate recovery values were observed using soil samples from three different depths, as well as the relative standard deviation, suggesting the possibility to employ the proposed extraction method for quantification of AT, DEA and DIA in oxisol samples. |
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Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial designtriazinesdegradation productsoxisolHPLCAn optimization procedure for the extraction of the herbicide atrazine (AT), and the main degradation products deethylatrazine (DEA) and deisopropylatrazine (DIA) from an oxisol soil sample was carried out, for a soil from the Southwest of Paraná State in Brazil, where AT is among the most largely employed herbicide. A comparison between shaking and ultrasound extraction was performed, to define a simple and fast extraction procedure, followed by the quantification using high performance liquid chromatography. It is important to inform that a factorial planning was employed, that was very important to define the best conditions of extraction by shaking. Appropriate recovery values were observed using soil samples from three different depths, as well as the relative standard deviation, suggesting the possibility to employ the proposed extraction method for quantification of AT, DEA and DIA in oxisol samples.Sociedade Brasileira de Química2013-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300016Journal of the Brazilian Chemical Society v.24 n.3 2013reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20130058info:eu-repo/semantics/openAccessAmadori,Maristela F.Cordeiro,Gilcélia A.Rebouças,Caio C.Peralta-Zamora,Patricio G.Grassi,Marco T.Abate,Gilbertoeng2013-05-24T00:00:00Zoai:scielo:S0103-50532013000300016Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2013-05-24T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
title |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
spellingShingle |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design Amadori,Maristela F. triazines degradation products oxisol HPLC |
title_short |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
title_full |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
title_fullStr |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
title_full_unstemmed |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
title_sort |
Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design |
author |
Amadori,Maristela F. |
author_facet |
Amadori,Maristela F. Cordeiro,Gilcélia A. Rebouças,Caio C. Peralta-Zamora,Patricio G. Grassi,Marco T. Abate,Gilberto |
author_role |
author |
author2 |
Cordeiro,Gilcélia A. Rebouças,Caio C. Peralta-Zamora,Patricio G. Grassi,Marco T. Abate,Gilberto |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Amadori,Maristela F. Cordeiro,Gilcélia A. Rebouças,Caio C. Peralta-Zamora,Patricio G. Grassi,Marco T. Abate,Gilberto |
dc.subject.por.fl_str_mv |
triazines degradation products oxisol HPLC |
topic |
triazines degradation products oxisol HPLC |
description |
An optimization procedure for the extraction of the herbicide atrazine (AT), and the main degradation products deethylatrazine (DEA) and deisopropylatrazine (DIA) from an oxisol soil sample was carried out, for a soil from the Southwest of Paraná State in Brazil, where AT is among the most largely employed herbicide. A comparison between shaking and ultrasound extraction was performed, to define a simple and fast extraction procedure, followed by the quantification using high performance liquid chromatography. It is important to inform that a factorial planning was employed, that was very important to define the best conditions of extraction by shaking. Appropriate recovery values were observed using soil samples from three different depths, as well as the relative standard deviation, suggesting the possibility to employ the proposed extraction method for quantification of AT, DEA and DIA in oxisol samples. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-03-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300016 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000300016 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20130058 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.24 n.3 2013 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
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1750318174797037568 |