Saponins and Sapogenins from Brachiaria decumbens Stapf
Autor(a) principal: | |
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Data de Publicação: | 2002 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200002 |
Resumo: | Four steroidal saponins and three sapogenins were identified from aerial parts of Brachiaria decumbens. Their structures were established by chemical and spectroscopic means (¹H and 13C NMR, HMBC, HMQC) as 3beta-methoxy-lanost-9(11)-ene (1), diosgenin (2a), yamogenin (2b), 3-O-beta-D-glucopyranosyl-24(S)-ethyl-22E -dihydrocholesterol (3a), 3-O-beta-D-glucopyranosyl-24(R)-ethyl-22E -dihydrocholesterol (3b), dioscin (4a) and 3-O-{alpha-L-rhamnopyranosyl-(1->4)-[alpha-L-rhamnopyranosyl-(1 ->2)]-beta-D-glucopyranosyl}-25(S)-spirost-5-en-3 beta-ol (4b). All these compounds were isolated for the first time from B. decumbens and compound 4b is described for the first time as far as we know. |
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Saponins and Sapogenins from Brachiaria decumbens StapfBrachiaria decumbenssteroidal saponinsdioscindiosgeninyamogenintriterpeneFour steroidal saponins and three sapogenins were identified from aerial parts of Brachiaria decumbens. Their structures were established by chemical and spectroscopic means (¹H and 13C NMR, HMBC, HMQC) as 3beta-methoxy-lanost-9(11)-ene (1), diosgenin (2a), yamogenin (2b), 3-O-beta-D-glucopyranosyl-24(S)-ethyl-22E -dihydrocholesterol (3a), 3-O-beta-D-glucopyranosyl-24(R)-ethyl-22E -dihydrocholesterol (3b), dioscin (4a) and 3-O-{alpha-L-rhamnopyranosyl-(1->4)-[alpha-L-rhamnopyranosyl-(1 ->2)]-beta-D-glucopyranosyl}-25(S)-spirost-5-en-3 beta-ol (4b). All these compounds were isolated for the first time from B. decumbens and compound 4b is described for the first time as far as we know.Sociedade Brasileira de Química2002-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200002Journal of the Brazilian Chemical Society v.13 n.2 2002reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532002000200002info:eu-repo/semantics/openAccessPires,Viviane S.Taketa,Alexandre T. C.Gosmann,GraceSchenkel,Eloir P.eng2002-06-25T00:00:00Zoai:scielo:S0103-50532002000200002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-06-25T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
title |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
spellingShingle |
Saponins and Sapogenins from Brachiaria decumbens Stapf Pires,Viviane S. Brachiaria decumbens steroidal saponins dioscin diosgenin yamogenin triterpene |
title_short |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
title_full |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
title_fullStr |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
title_full_unstemmed |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
title_sort |
Saponins and Sapogenins from Brachiaria decumbens Stapf |
author |
Pires,Viviane S. |
author_facet |
Pires,Viviane S. Taketa,Alexandre T. C. Gosmann,Grace Schenkel,Eloir P. |
author_role |
author |
author2 |
Taketa,Alexandre T. C. Gosmann,Grace Schenkel,Eloir P. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Pires,Viviane S. Taketa,Alexandre T. C. Gosmann,Grace Schenkel,Eloir P. |
dc.subject.por.fl_str_mv |
Brachiaria decumbens steroidal saponins dioscin diosgenin yamogenin triterpene |
topic |
Brachiaria decumbens steroidal saponins dioscin diosgenin yamogenin triterpene |
description |
Four steroidal saponins and three sapogenins were identified from aerial parts of Brachiaria decumbens. Their structures were established by chemical and spectroscopic means (¹H and 13C NMR, HMBC, HMQC) as 3beta-methoxy-lanost-9(11)-ene (1), diosgenin (2a), yamogenin (2b), 3-O-beta-D-glucopyranosyl-24(S)-ethyl-22E -dihydrocholesterol (3a), 3-O-beta-D-glucopyranosyl-24(R)-ethyl-22E -dihydrocholesterol (3b), dioscin (4a) and 3-O-{alpha-L-rhamnopyranosyl-(1->4)-[alpha-L-rhamnopyranosyl-(1 ->2)]-beta-D-glucopyranosyl}-25(S)-spirost-5-en-3 beta-ol (4b). All these compounds were isolated for the first time from B. decumbens and compound 4b is described for the first time as far as we know. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200002 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000200002 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532002000200002 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.13 n.2 2002 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318164597538816 |