IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700725 |
Resumo: | Zirconium-based metal-organic framework, UiO-67, was synthesized and used as support for the immobilization of the [RuCl2(ENAPY)] (ENAPY = N,N'-bis(7-metyl-2-pyridylmethylene)-1,2-diiminoethane)). The immobilized system exhibited violet-blue color. The {UiO-67/[RuCl2(ENAPY)]} was characterized by cyclic voltammetry, X-ray diffraction, UV-Vis, FTIR and X-ray photoelectron spectroscopy. The electrochemistry of the immobilized system is characterized by a reversible pair of waves at +0.40 V (vs NHE), ascribed to the Ru3+/2+ redox process. The electronic spectrum of the immobilized system is characterized by bands at 520 and 380 nm ascribed to a ligand-to-metal charge-transfer transitions {Ru2+(dπ) → ENAPY(pπ*)}. The IR bands of immobilized complex {1630 cm-1 (νasC=C), 1590 cm-1 (νasC=N), 1450 cm-1 (νsC=C), 1340 cm-1 (νsC=C)} are weak in comparison with the neat complex due to their low concentration in MOF cages. X-ray diffractogram of the immobilized system indicated that the crystallinity and morphology of UiO-67 was preserved during inclusion of ruthenium complex. The XPS spectra of UiO-67 and UiO-67/ruthenium complex shows a signal at 462 eV that can be ascribed to Ru 3p3/2 and at 400 eV ascribed to N 1s core level of the ruthenium Schiff base complex immobilized into MOF. |
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Química Nova (Online) |
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IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67porous materialspost-synthetic modificationN4 donor ligandspectroscopic propertiesZirconium-based metal-organic framework, UiO-67, was synthesized and used as support for the immobilization of the [RuCl2(ENAPY)] (ENAPY = N,N'-bis(7-metyl-2-pyridylmethylene)-1,2-diiminoethane)). The immobilized system exhibited violet-blue color. The {UiO-67/[RuCl2(ENAPY)]} was characterized by cyclic voltammetry, X-ray diffraction, UV-Vis, FTIR and X-ray photoelectron spectroscopy. The electrochemistry of the immobilized system is characterized by a reversible pair of waves at +0.40 V (vs NHE), ascribed to the Ru3+/2+ redox process. The electronic spectrum of the immobilized system is characterized by bands at 520 and 380 nm ascribed to a ligand-to-metal charge-transfer transitions {Ru2+(dπ) → ENAPY(pπ*)}. The IR bands of immobilized complex {1630 cm-1 (νasC=C), 1590 cm-1 (νasC=N), 1450 cm-1 (νsC=C), 1340 cm-1 (νsC=C)} are weak in comparison with the neat complex due to their low concentration in MOF cages. X-ray diffractogram of the immobilized system indicated that the crystallinity and morphology of UiO-67 was preserved during inclusion of ruthenium complex. The XPS spectra of UiO-67 and UiO-67/ruthenium complex shows a signal at 462 eV that can be ascribed to Ru 3p3/2 and at 400 eV ascribed to N 1s core level of the ruthenium Schiff base complex immobilized into MOF.Sociedade Brasileira de Química2018-07-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700725Química Nova v.41 n.7 2018reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170238info:eu-repo/semantics/openAccessJorge,Herculys B.Silva,Cleiser T. P. daNakatani,Helena S.Rinaldi,Andrelson W.Souza,Vagner R. Depor2018-08-02T00:00:00Zoai:scielo:S0100-40422018000700725Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2018-08-02T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
title |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
spellingShingle |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 Jorge,Herculys B. porous materials post-synthetic modification N4 donor ligand spectroscopic properties |
title_short |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
title_full |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
title_fullStr |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
title_full_unstemmed |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
title_sort |
IMOBILIZAÇÃO DE COMPLEXO DE RUTÊNIO CONTENDO BASE DE SCHIFF NA UNIDADE METALOORGÂNICA UiO-67 |
author |
Jorge,Herculys B. |
author_facet |
Jorge,Herculys B. Silva,Cleiser T. P. da Nakatani,Helena S. Rinaldi,Andrelson W. Souza,Vagner R. De |
author_role |
author |
author2 |
Silva,Cleiser T. P. da Nakatani,Helena S. Rinaldi,Andrelson W. Souza,Vagner R. De |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Jorge,Herculys B. Silva,Cleiser T. P. da Nakatani,Helena S. Rinaldi,Andrelson W. Souza,Vagner R. De |
dc.subject.por.fl_str_mv |
porous materials post-synthetic modification N4 donor ligand spectroscopic properties |
topic |
porous materials post-synthetic modification N4 donor ligand spectroscopic properties |
description |
Zirconium-based metal-organic framework, UiO-67, was synthesized and used as support for the immobilization of the [RuCl2(ENAPY)] (ENAPY = N,N'-bis(7-metyl-2-pyridylmethylene)-1,2-diiminoethane)). The immobilized system exhibited violet-blue color. The {UiO-67/[RuCl2(ENAPY)]} was characterized by cyclic voltammetry, X-ray diffraction, UV-Vis, FTIR and X-ray photoelectron spectroscopy. The electrochemistry of the immobilized system is characterized by a reversible pair of waves at +0.40 V (vs NHE), ascribed to the Ru3+/2+ redox process. The electronic spectrum of the immobilized system is characterized by bands at 520 and 380 nm ascribed to a ligand-to-metal charge-transfer transitions {Ru2+(dπ) → ENAPY(pπ*)}. The IR bands of immobilized complex {1630 cm-1 (νasC=C), 1590 cm-1 (νasC=N), 1450 cm-1 (νsC=C), 1340 cm-1 (νsC=C)} are weak in comparison with the neat complex due to their low concentration in MOF cages. X-ray diffractogram of the immobilized system indicated that the crystallinity and morphology of UiO-67 was preserved during inclusion of ruthenium complex. The XPS spectra of UiO-67 and UiO-67/ruthenium complex shows a signal at 462 eV that can be ascribed to Ru 3p3/2 and at 400 eV ascribed to N 1s core level of the ruthenium Schiff base complex immobilized into MOF. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-07-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700725 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000700725 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
10.21577/0100-4042.20170238 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.41 n.7 2018 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318119183712256 |