Review of the synthesis of layered double hydroxides: a thermodynamic approach

Detalhes bibliográficos
Autor(a) principal: Bravo-Suárez,Juan J.
Data de Publicação: 2004
Outros Autores: Páez-Mozo,Edgar A., Oyama,S. Ted
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400015
Resumo: The synthesis of layered double hydroxides (LDHs) by hydrothermal-LDH reconstruction and coprecipitation methods is reviewed using a thermodynamic approach. A mixture model was used for the estimation of the thermodynamics of formation of LDHs. The synthesis and solubility of LDHs are discussed in terms of standard molar Gibbs free energy change of reaction. Data for numerous divalent and trivalent metals as well as for some monovalent and tetravalent metals that may be part of the LDH structure have been compiled. Good agreement is found between theoretical and experimental data. Diagrams and tables for the prediction of possible new LDH materials are provided.
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spelling Review of the synthesis of layered double hydroxides: a thermodynamic approachlayered double hydroxidessynthesisthermodynamicsThe synthesis of layered double hydroxides (LDHs) by hydrothermal-LDH reconstruction and coprecipitation methods is reviewed using a thermodynamic approach. A mixture model was used for the estimation of the thermodynamics of formation of LDHs. The synthesis and solubility of LDHs are discussed in terms of standard molar Gibbs free energy change of reaction. Data for numerous divalent and trivalent metals as well as for some monovalent and tetravalent metals that may be part of the LDH structure have been compiled. Good agreement is found between theoretical and experimental data. Diagrams and tables for the prediction of possible new LDH materials are provided.Sociedade Brasileira de Química2004-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400015Química Nova v.27 n.4 2004reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422004000400015info:eu-repo/semantics/openAccessBravo-Suárez,Juan J.Páez-Mozo,Edgar A.Oyama,S. Tedeng2004-07-31T00:00:00Zoai:scielo:S0100-40422004000400015Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2004-07-31T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Review of the synthesis of layered double hydroxides: a thermodynamic approach
title Review of the synthesis of layered double hydroxides: a thermodynamic approach
spellingShingle Review of the synthesis of layered double hydroxides: a thermodynamic approach
Bravo-Suárez,Juan J.
layered double hydroxides
synthesis
thermodynamics
title_short Review of the synthesis of layered double hydroxides: a thermodynamic approach
title_full Review of the synthesis of layered double hydroxides: a thermodynamic approach
title_fullStr Review of the synthesis of layered double hydroxides: a thermodynamic approach
title_full_unstemmed Review of the synthesis of layered double hydroxides: a thermodynamic approach
title_sort Review of the synthesis of layered double hydroxides: a thermodynamic approach
author Bravo-Suárez,Juan J.
author_facet Bravo-Suárez,Juan J.
Páez-Mozo,Edgar A.
Oyama,S. Ted
author_role author
author2 Páez-Mozo,Edgar A.
Oyama,S. Ted
author2_role author
author
dc.contributor.author.fl_str_mv Bravo-Suárez,Juan J.
Páez-Mozo,Edgar A.
Oyama,S. Ted
dc.subject.por.fl_str_mv layered double hydroxides
synthesis
thermodynamics
topic layered double hydroxides
synthesis
thermodynamics
description The synthesis of layered double hydroxides (LDHs) by hydrothermal-LDH reconstruction and coprecipitation methods is reviewed using a thermodynamic approach. A mixture model was used for the estimation of the thermodynamics of formation of LDHs. The synthesis and solubility of LDHs are discussed in terms of standard molar Gibbs free energy change of reaction. Data for numerous divalent and trivalent metals as well as for some monovalent and tetravalent metals that may be part of the LDH structure have been compiled. Good agreement is found between theoretical and experimental data. Diagrams and tables for the prediction of possible new LDH materials are provided.
publishDate 2004
dc.date.none.fl_str_mv 2004-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400015
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422004000400015
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40422004000400015
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.27 n.4 2004
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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