Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil

Detalhes bibliográficos
Autor(a) principal: Nunes, L. S. S.
Data de Publicação: 2005
Outros Autores: Tavares, Tânia Mascarenhas, Dippel, J., Jaeschke, W.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/4821
Resumo: p.79-100
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spelling Nunes, L. S. S.Tavares, Tânia MascarenhasDippel, J.Jaeschke, W.Nunes, L. S. S.Tavares, Tânia MascarenhasDippel, J.Jaeschke, W.2011-12-12T16:24:06Z2011-12-12T16:24:06Z2005http://www.repositorio.ufba.br/ri/handle/ri/482150: 79–100p.79-100Atmospheric concentrations of several reduced sulphur compounds (H2S, COS, CH3SH, CH3SCH3, CS2) originating from both natural and anthropogenic sources were measured at a number of locations in the All Saints Bay area and Reconcavo Baiano, Brazil. The volatile reduced sulphur compounds were collected by pre-concentration using cryo-tubes. Analysis of these compounds was carried out at a later date using gas chromatography with a flame photometric detector. In areas dominated by biogenic sources, the COS concentration varied between 0.5 and 1.0 ppbv, consistent with its normal global distribution in the atmosphere. Areas without direct industrial influence showed low atmospheric concentrations for all volatile sulphur compounds (≤0.25 ppbv). The anthropogenic influence of the Petrochemical Complex in Cama¸cari resulted in relatively high levels of some reduced sulphur compounds, such asCOS(8 ppbv),CH3SH(1.50 ppbv),H2S (1.35 ppbv) and CS2 (0.3 ppbv). In mangrove areas, theH2S concentrations (0.2 ppbv) were almost twice as high as those in the air masses arriving from the Atlantic Ocean. The maximum H2S concentrations were found in the industrial area of the Petrochemical Complex in Cama¸cari, but did not reach the limit of human perception (0.14 ppbv) and rarely reached the typical recognizable smelling level (0.40 ppbv). Industrial emissions from the Landulfo Alves Refinery increased the COS, DMS and CS2 concentrations to 2.0, 0.55 and 0.2 ppbv, respectively.Submitted by Rigaud Andréa (andrearigaud16@yahoo.com.br) on 2011-12-12T16:24:06Z No. of bitstreams: 1 v8sr4a.pdf: 1671031 bytes, checksum: d4899e2722330b18212943e7ffcf74cf (MD5)Made available in DSpace on 2011-12-12T16:24:06Z (GMT). No. of bitstreams: 1 v8sr4a.pdf: 1671031 bytes, checksum: d4899e2722330b18212943e7ffcf74cf (MD5) Previous issue date: 2005anthropogenic sourcesatmospheric concentrationsBrazilmangrove areasreduced sulphur compoundsMeasurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, BrazilJournal of Atmospheric Chemistryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAinfo:eu-repo/semantics/openAccessORIGINALv8sr4a.pdfv8sr4a.pdfapplication/pdf1671031https://repositorio.ufba.br/bitstream/ri/4821/1/v8sr4a.pdfd4899e2722330b18212943e7ffcf74cfMD51LICENSElicense.txtlicense.txttext/plain1748https://repositorio.ufba.br/bitstream/ri/4821/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTv8sr4a.pdf.txtv8sr4a.pdf.txtExtracted texttext/plain37293https://repositorio.ufba.br/bitstream/ri/4821/3/v8sr4a.pdf.txt926ae2c7089dc51d27de3abd232309c8MD53ri/48212022-07-05 14:03:18.115oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:18Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
dc.title.alternative.pt_BR.fl_str_mv Journal of Atmospheric Chemistry
title Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
spellingShingle Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
Nunes, L. S. S.
anthropogenic sources
atmospheric concentrations
Brazil
mangrove areas
reduced sulphur compounds
title_short Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
title_full Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
title_fullStr Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
title_full_unstemmed Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
title_sort Measurements of Atmospheric Concentrations of Reduced Sulphur Compounds in the All Saints Bay Area in Bahia, Brazil
author Nunes, L. S. S.
author_facet Nunes, L. S. S.
Tavares, Tânia Mascarenhas
Dippel, J.
Jaeschke, W.
author_role author
author2 Tavares, Tânia Mascarenhas
Dippel, J.
Jaeschke, W.
author2_role author
author
author
dc.contributor.author.fl_str_mv Nunes, L. S. S.
Tavares, Tânia Mascarenhas
Dippel, J.
Jaeschke, W.
Nunes, L. S. S.
Tavares, Tânia Mascarenhas
Dippel, J.
Jaeschke, W.
dc.subject.por.fl_str_mv anthropogenic sources
atmospheric concentrations
Brazil
mangrove areas
reduced sulphur compounds
topic anthropogenic sources
atmospheric concentrations
Brazil
mangrove areas
reduced sulphur compounds
description p.79-100
publishDate 2005
dc.date.issued.fl_str_mv 2005
dc.date.accessioned.fl_str_mv 2011-12-12T16:24:06Z
dc.date.available.fl_str_mv 2011-12-12T16:24:06Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/4821
dc.identifier.number.pt_BR.fl_str_mv 50: 79–100
url http://www.repositorio.ufba.br/ri/handle/ri/4821
identifier_str_mv 50: 79–100
dc.language.iso.fl_str_mv eng
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