Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments
Autor(a) principal: | |
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Data de Publicação: | 2012 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://repositorio.ufba.br/ri/handle/ri/15241 |
Resumo: | Texto completo: acesso restrito. p. 1084–1088 |
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Moura, Jadson SantosLima, Robson SantanaAraújo, Genira Carneiro deMateus, Viviana de OliveiraSouza, Marluce Oliveira da GuardaMoura, Jadson SantosLima, Robson SantanaAraújo, Genira Carneiro deMateus, Viviana de OliveiraSouza, Marluce Oliveira da Guarda2014-07-21T12:52:24Z20120254-0584http://repositorio.ufba.br/ri/handle/ri/15241v. 135, n. 2Texto completo: acesso restrito. p. 1084–1088This work investigated the properties and phase composition of nickel-based systems supported on mixed oxides of lanthanum and magnesium (in different proportions) that were submitted to different thermal treatments. Catalysts were obtained by co-precipitation and were characterised using different techniques. The diffractograms of the nickel and lanthanum oxide catalysts show more intense peaks associated with a perovskite-type phase. The presence of magnesium leads to a decrease in the intensity of the peaks that correspond to the perovskite phase. The mixed system showed a higher specific surface area compared with that of the system formed by nickel and lanthanum oxides. The specific surface area of the mixed system was proportional to the magnesium content. The reduction profiles showed interactions in these systems. Metallic nickel is formed at temperatures greater than 873 K after reduction with hydrogen. The La2O2CO3 phase is formed under hydrogen-production reaction conditions. In conclusion, the systems formed by nickel, lanthanum and magnesium exhibit properties that render them suitable for application in hydrogen production reactions.Submitted by Edileide Reis (leyde-landy@hotmail.com) on 2014-07-21T12:52:24Z No. of bitstreams: 1 Jadson Santos Moura.pdf: 489912 bytes, checksum: 022f1496924fd01542242511b522964d (MD5)Made available in DSpace on 2014-07-21T12:52:24Z (GMT). No. of bitstreams: 1 Jadson Santos Moura.pdf: 489912 bytes, checksum: 022f1496924fd01542242511b522964d (MD5) Previous issue date: 2012http://dx.doi.org/ 10.1016/j.matchemphys.2012.06.021reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAMixed systemNickel CatalystLantanum oxideMagnesium oxideProperties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatmentsMaterials Chemistry and Physicsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01info:eu-repo/semantics/openAccessengORIGINALJadson Santos Moura.pdfJadson Santos Moura.pdfapplication/pdf489912https://repositorio.ufba.br/bitstream/ri/15241/1/Jadson%20Santos%20Moura.pdf022f1496924fd01542242511b522964dMD51LICENSElicense.txtlicense.txttext/plain1345https://repositorio.ufba.br/bitstream/ri/15241/2/license.txt0d4b811ef71182510d2015daa7c8a900MD52TEXTJadson Santos Moura.pdf.txtJadson Santos Moura.pdf.txtExtracted texttext/plain22749https://repositorio.ufba.br/bitstream/ri/15241/3/Jadson%20Santos%20Moura.pdf.txtbbaec41454d37246991c5c21412bbfc8MD53ri/152412022-07-05 14:03:31.684oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:31Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
dc.title.alternative.pt_BR.fl_str_mv |
Materials Chemistry and Physics |
title |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
spellingShingle |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments Moura, Jadson Santos Mixed system Nickel Catalyst Lantanum oxide Magnesium oxide |
title_short |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
title_full |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
title_fullStr |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
title_full_unstemmed |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
title_sort |
Properties and phase composition of Ni–MgO–La2O3 systems submitted to different thermal treatments |
author |
Moura, Jadson Santos |
author_facet |
Moura, Jadson Santos Lima, Robson Santana Araújo, Genira Carneiro de Mateus, Viviana de Oliveira Souza, Marluce Oliveira da Guarda |
author_role |
author |
author2 |
Lima, Robson Santana Araújo, Genira Carneiro de Mateus, Viviana de Oliveira Souza, Marluce Oliveira da Guarda |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Moura, Jadson Santos Lima, Robson Santana Araújo, Genira Carneiro de Mateus, Viviana de Oliveira Souza, Marluce Oliveira da Guarda Moura, Jadson Santos Lima, Robson Santana Araújo, Genira Carneiro de Mateus, Viviana de Oliveira Souza, Marluce Oliveira da Guarda |
dc.subject.por.fl_str_mv |
Mixed system Nickel Catalyst Lantanum oxide Magnesium oxide |
topic |
Mixed system Nickel Catalyst Lantanum oxide Magnesium oxide |
description |
Texto completo: acesso restrito. p. 1084–1088 |
publishDate |
2012 |
dc.date.issued.fl_str_mv |
2012 |
dc.date.accessioned.fl_str_mv |
2014-07-21T12:52:24Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
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article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufba.br/ri/handle/ri/15241 |
dc.identifier.issn.none.fl_str_mv |
0254-0584 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 135, n. 2 |
identifier_str_mv |
0254-0584 v. 135, n. 2 |
url |
http://repositorio.ufba.br/ri/handle/ri/15241 |
dc.language.iso.fl_str_mv |
eng |
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eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
dc.source.pt_BR.fl_str_mv |
http://dx.doi.org/ 10.1016/j.matchemphys.2012.06.021 |
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reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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Repositório Institucional da UFBA |
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Repositório Institucional da UFBA |
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