Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation

Detalhes bibliográficos
Autor(a) principal: Sales, Emerson Andrade
Data de Publicação: 1998
Outros Autores: Benhamida, Béatrice, Caizergues, Virginie, Lagier, Jean Pierre, Fiévet, Fernand, Bozon Verduraz, François
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/8194
Resumo: Texto completo: acesso restrito. p.273–283
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spelling Sales, Emerson AndradeBenhamida, BéatriceCaizergues, VirginieLagier, Jean PierreFiévet, FernandBozon Verduraz, FrançoisSales, Emerson AndradeBenhamida, BéatriceCaizergues, VirginieLagier, Jean PierreFiévet, FernandBozon Verduraz, François2013-01-28T15:19:48Z19980926-860Xhttp://www.repositorio.ufba.br/ri/handle/ri/8194v. 172, n. 2Texto completo: acesso restrito. p.273–283Palladium and palladium–silver catalysts, supported on γ-alumina, were prepared by precipitation in a liquid polyol and characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The catalysts were tested in the hydrogenation of hexa-1,5-diene in liquid phase, at 313 K. The addition of silver improved the hex-1-ene fractional selectivity in all cases, but lowered the catalyst activity when the Pd/Ag ratio was about unity. On the other hand a palladium-rich (Pd/Ag=4) bimetallic catalyst exhibited a very good activity and a good selectivity to hex-1-ene as well. The effects of silver addition are ascribed to the dilution of palladium atoms by silver atoms, which prevents the isomerisation of hexa-1,5-diene. Hence, the polyol method, which has been used up to now to prepare metal powders with controlled morphology, appears of interest in the elaboration of supported metal catalysts.Submitted by Suelen Reis (suelen_suzane@hotmail.com) on 2013-01-28T15:19:48Z No. of bitstreams: 1 Sales.pdf: 1268659 bytes, checksum: 338ec80bff1dc0e0f1024ad25bbc5e6f (MD5)Made available in DSpace on 2013-01-28T15:19:48Z (GMT). No. of bitstreams: 1 Sales.pdf: 1268659 bytes, checksum: 338ec80bff1dc0e0f1024ad25bbc5e6f (MD5) Previous issue date: 1998http://dx.doi.org/10.1016/S0926-860X(98)00124-0reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAHexa-1,5-dieneLiquid phase hydrogenationPalladium±silver catalystsPolyol processAlumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenationApplied Catalysis A: Generalinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINALSales.pdfSales.pdfapplication/pdf1268659https://repositorio.ufba.br/bitstream/ri/8194/1/Sales.pdf338ec80bff1dc0e0f1024ad25bbc5e6fMD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/8194/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXTSales.pdf.txtSales.pdf.txtExtracted texttext/plain0https://repositorio.ufba.br/bitstream/ri/8194/3/Sales.pdf.txtd41d8cd98f00b204e9800998ecf8427eMD53ri/81942022-08-08 13:20:03.842oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-08-08T16:20:03Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
dc.title.alternative.pt_BR.fl_str_mv Applied Catalysis A: General
title Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
spellingShingle Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
Sales, Emerson Andrade
Hexa-1,5-diene
Liquid phase hydrogenation
Palladium±silver catalysts
Polyol process
title_short Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
title_full Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
title_fullStr Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
title_full_unstemmed Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
title_sort Alumina-supported Pd, Ag and Pd–Ag catalysts: preparation through the polyol process, characterization and reactivity in hexa-1,5-diene hydrogenation
author Sales, Emerson Andrade
author_facet Sales, Emerson Andrade
Benhamida, Béatrice
Caizergues, Virginie
Lagier, Jean Pierre
Fiévet, Fernand
Bozon Verduraz, François
author_role author
author2 Benhamida, Béatrice
Caizergues, Virginie
Lagier, Jean Pierre
Fiévet, Fernand
Bozon Verduraz, François
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Sales, Emerson Andrade
Benhamida, Béatrice
Caizergues, Virginie
Lagier, Jean Pierre
Fiévet, Fernand
Bozon Verduraz, François
Sales, Emerson Andrade
Benhamida, Béatrice
Caizergues, Virginie
Lagier, Jean Pierre
Fiévet, Fernand
Bozon Verduraz, François
dc.subject.por.fl_str_mv Hexa-1,5-diene
Liquid phase hydrogenation
Palladium±silver catalysts
Polyol process
topic Hexa-1,5-diene
Liquid phase hydrogenation
Palladium±silver catalysts
Polyol process
description Texto completo: acesso restrito. p.273–283
publishDate 1998
dc.date.issued.fl_str_mv 1998
dc.date.accessioned.fl_str_mv 2013-01-28T15:19:48Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/8194
dc.identifier.issn.none.fl_str_mv 0926-860X
dc.identifier.number.pt_BR.fl_str_mv v. 172, n. 2
identifier_str_mv 0926-860X
v. 172, n. 2
url http://www.repositorio.ufba.br/ri/handle/ri/8194
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1016/S0926-860X(98)00124-0
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
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instname_str Universidade Federal da Bahia (UFBA)
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reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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