Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2020 |
| Outros Autores: | , , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Institucional da UFMG |
| Texto Completo: | https://doi.org/10.1103/PhysRevResearch.2.023408 http://hdl.handle.net/1843/44026 https://orcid.org/0000-0002-9946-5224 https://orcid.org/0000-0002-5978-2735 https://orcid.org/0000-0003-0488-2242 https://orcid.org/0000-0003-0816-0888 https://orcid.org/0000-0003-0195-444X https://orcid.org/0000-0003-4440-3680 https://orcid.org/0000-0002-4236-2806 https://orcid.org/0000-0002-2391-0256 |
Resumo: | CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico |
| id |
UFMG_d20002580f8510dca8fdf407a4bbf2cc |
|---|---|
| oai_identifier_str |
oai:repositorio.ufmg.br:1843/44026 |
| network_acronym_str |
UFMG |
| network_name_str |
Repositório Institucional da UFMG |
| repository_id_str |
|
| spelling |
2022-08-08T12:12:38Z2022-08-08T12:12:38Z2020-06-2922023408-1023408-8https://doi.org/10.1103/PhysRevResearch.2.02340826431564http://hdl.handle.net/1843/44026https://orcid.org/0000-0002-9946-5224https://orcid.org/0000-0002-5978-2735https://orcid.org/0000-0003-0488-2242https://orcid.org/0000-0003-0816-0888https://orcid.org/0000-0003-0195-444Xhttps://orcid.org/0000-0003-4440-3680https://orcid.org/0000-0002-4236-2806https://orcid.org/0000-0002-2391-0256CNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas GeraisCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorFINEP - Financiadora de Estudos e Projetos, Financiadora de Estudos e ProjetosTip-enhanced Raman spectroscopy (TERS) has reached nanometer spatial resolution for measurements performed at ambient conditions and subnanometer resolution at ultrahigh vacuum. Super-resolution (beyond the tip apex diameter) TERS has been obtained mostly in the gap mode configuration, where a conductive substrate localizes the electric fields. Here we present experimental and theoretical TERS to explore the field distribution responsible for spectral enhancement. We use gold tips of 40 ± 10 nm apex diameter to measure TERS on graphene, a spatially delocalized two-dimensional sample, sitting on different substrates: (i) glass, (ii) a thin layer of gold and (iii) a surface covered with 12 nm diameter gold spheres, for which 6 nm resolution is achieved at ambient conditions. The super-resolution is due to the field configuration resulting from the coupled tip-sample-substrate system, exhibiting a nontrivial spatial surface distribution. The field distribution and the symmetry selection rules are different for nongap versus gap mode configurations. This influences the overall enhancement which depends on the Raman mode symmetry and substrate structure.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA ELÉTRICAICX - DEPARTAMENTO DE FÍSICAPhysical Review ResearchEspectroscopia de RamanGrafenoTERSTip-Enhanced Raman SpectroscopyGrapheneNanophotonicsImpact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurementsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://journals.aps.org/prresearch/abstract/10.1103/PhysRevResearch.2.023408Hudson Luiz Silva de MirandaAdo Jorio de VasconcelosCassiano Rabelo e SilvaLuiz Gustavo de Oliveira Lopes CançadoThiago de Lourenço e VasconcelosBruno Santos de OliveiraFlorian SchulzHolger LangeStephanie ReichPatryk Kuschapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/44026/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALImpact of substrate on tip enhanced Raman spectroscopy A comparison between PDFA.pdfImpact of substrate on tip enhanced Raman spectroscopy A comparison between PDFA.pdfapplication/pdf922835https://repositorio.ufmg.br/bitstream/1843/44026/2/Impact%20of%20substrate%20on%20tip%20enhanced%20Raman%20spectroscopy%20A%20comparison%20between%20PDFA.pdff0c8f1af72317101185e171b5d05055fMD521843/440262022-08-08 09:12:38.751oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2022-08-08T12:12:38Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
| dc.title.pt_BR.fl_str_mv |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| title |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| spellingShingle |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements Hudson Luiz Silva de Miranda TERS Tip-Enhanced Raman Spectroscopy Graphene Nanophotonics Espectroscopia de Raman Grafeno |
| title_short |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| title_full |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| title_fullStr |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| title_full_unstemmed |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| title_sort |
Impact of substrate on Tip-Enhanced Raman Spectroscopy: a comparison between field-distribution simulations and graphene measurements |
| author |
Hudson Luiz Silva de Miranda |
| author_facet |
Hudson Luiz Silva de Miranda Ado Jorio de Vasconcelos Cassiano Rabelo e Silva Luiz Gustavo de Oliveira Lopes Cançado Thiago de Lourenço e Vasconcelos Bruno Santos de Oliveira Florian Schulz Holger Lange Stephanie Reich Patryk Kusch |
| author_role |
author |
| author2 |
Ado Jorio de Vasconcelos Cassiano Rabelo e Silva Luiz Gustavo de Oliveira Lopes Cançado Thiago de Lourenço e Vasconcelos Bruno Santos de Oliveira Florian Schulz Holger Lange Stephanie Reich Patryk Kusch |
| author2_role |
author author author author author author author author author |
| dc.contributor.author.fl_str_mv |
Hudson Luiz Silva de Miranda Ado Jorio de Vasconcelos Cassiano Rabelo e Silva Luiz Gustavo de Oliveira Lopes Cançado Thiago de Lourenço e Vasconcelos Bruno Santos de Oliveira Florian Schulz Holger Lange Stephanie Reich Patryk Kusch |
| dc.subject.por.fl_str_mv |
TERS Tip-Enhanced Raman Spectroscopy Graphene Nanophotonics |
| topic |
TERS Tip-Enhanced Raman Spectroscopy Graphene Nanophotonics Espectroscopia de Raman Grafeno |
| dc.subject.other.pt_BR.fl_str_mv |
Espectroscopia de Raman Grafeno |
| description |
CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico |
| publishDate |
2020 |
| dc.date.issued.fl_str_mv |
2020-06-29 |
| dc.date.accessioned.fl_str_mv |
2022-08-08T12:12:38Z |
| dc.date.available.fl_str_mv |
2022-08-08T12:12:38Z |
| dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/44026 |
| dc.identifier.doi.pt_BR.fl_str_mv |
https://doi.org/10.1103/PhysRevResearch.2.023408 |
| dc.identifier.issn.pt_BR.fl_str_mv |
26431564 |
| dc.identifier.orcid.pt_BR.fl_str_mv |
https://orcid.org/0000-0002-9946-5224 https://orcid.org/0000-0002-5978-2735 https://orcid.org/0000-0003-0488-2242 https://orcid.org/0000-0003-0816-0888 https://orcid.org/0000-0003-0195-444X https://orcid.org/0000-0003-4440-3680 https://orcid.org/0000-0002-4236-2806 https://orcid.org/0000-0002-2391-0256 |
| url |
https://doi.org/10.1103/PhysRevResearch.2.023408 http://hdl.handle.net/1843/44026 https://orcid.org/0000-0002-9946-5224 https://orcid.org/0000-0002-5978-2735 https://orcid.org/0000-0003-0488-2242 https://orcid.org/0000-0003-0816-0888 https://orcid.org/0000-0003-0195-444X https://orcid.org/0000-0003-4440-3680 https://orcid.org/0000-0002-4236-2806 https://orcid.org/0000-0002-2391-0256 |
| identifier_str_mv |
26431564 |
| dc.language.iso.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartof.pt_BR.fl_str_mv |
Physical Review Research |
| dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
| dc.publisher.initials.fl_str_mv |
UFMG |
| dc.publisher.country.fl_str_mv |
Brasil |
| dc.publisher.department.fl_str_mv |
ENG - DEPARTAMENTO DE ENGENHARIA ELÉTRICA ICX - DEPARTAMENTO DE FÍSICA |
| publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
| dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFMG instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
| instname_str |
Universidade Federal de Minas Gerais (UFMG) |
| instacron_str |
UFMG |
| institution |
UFMG |
| reponame_str |
Repositório Institucional da UFMG |
| collection |
Repositório Institucional da UFMG |
| bitstream.url.fl_str_mv |
https://repositorio.ufmg.br/bitstream/1843/44026/1/License.txt https://repositorio.ufmg.br/bitstream/1843/44026/2/Impact%20of%20substrate%20on%20tip%20enhanced%20Raman%20spectroscopy%20A%20comparison%20between%20PDFA.pdf |
| bitstream.checksum.fl_str_mv |
fa505098d172de0bc8864fc1287ffe22 f0c8f1af72317101185e171b5d05055f |
| bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 |
| repository.name.fl_str_mv |
Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG) |
| repository.mail.fl_str_mv |
|
| _version_ |
1797971414035202048 |