Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels.
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFOP |
Texto Completo: | http://www.repositorio.ufop.br/handle/123456789/4909 https://doi.org/10.1016/j.catcom.2012.11.021 |
Resumo: | In this work, a new two-step route to store and transport associated natural gas, promoted by Ni, Fe and Co supported catalyst was presented. Initially, CH4 is converted into carbon deposits (M/C composite), being Fe catalyst the most active catalyst. In Step 2, M/C composite reacts with H2O producing H2, CO and CH4. TPO experiments showed that efficiency and selectivity of oxidation depends on the metal. Ni catalyst produced mainly H2 and CO, while Fe system was more selective to convert carbon into CH4. The formation of C2 and C3 compounds suggests the presence of a Fischer Tropsch like process. |
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Oliveira, Patrícia E. F.Ribeiro, Leandro PassosRosmaninho, Marcelo GonçalvesArdisson, José DomingosDias, AndersonOliveira, Luiz Carlos Alves deLago, Rochel Montero2015-04-01T17:29:16Z2015-04-01T17:29:16Z2013OLIVEIRA, P. E. F. et al. Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts: a new indirect route to store and transport gas hydrocarbon fuels. Catalysis Communications, v. 32, p. 58-61, 2013. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736712004414>. Acesso em: 02 fev. 2015.1566-7367http://www.repositorio.ufop.br/handle/123456789/4909https://doi.org/10.1016/j.catcom.2012.11.021In this work, a new two-step route to store and transport associated natural gas, promoted by Ni, Fe and Co supported catalyst was presented. Initially, CH4 is converted into carbon deposits (M/C composite), being Fe catalyst the most active catalyst. In Step 2, M/C composite reacts with H2O producing H2, CO and CH4. TPO experiments showed that efficiency and selectivity of oxidation depends on the metal. Ni catalyst produced mainly H2 and CO, while Fe system was more selective to convert carbon into CH4. The formation of C2 and C3 compounds suggests the presence of a Fischer Tropsch like process.Natural gasDeposition oxidationSyngas productionCatalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels.info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO periódico Catalysis Communications concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3577170717646.info:eu-repo/semantics/openAccessengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOPLICENSElicense.txtlicense.txttext/plain; charset=utf-82636http://www.repositorio.ufop.br/bitstream/123456789/4909/2/license.txtc2ffdd99e58acf69202dff00d361f23aMD52ORIGINALARTIGO_CatalyticDepositionOxidation.pdfARTIGO_CatalyticDepositionOxidation.pdfapplication/pdf524821http://www.repositorio.ufop.br/bitstream/123456789/4909/1/ARTIGO_CatalyticDepositionOxidation.pdff4f43c420e4d7e66248d9be5b33bb465MD51123456789/49092019-07-04 08:57:25.253oai:localhost: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Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-07-04T12:57:25Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false |
dc.title.pt_BR.fl_str_mv |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
title |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
spellingShingle |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. Oliveira, Patrícia E. F. Natural gas Deposition oxidation Syngas production |
title_short |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
title_full |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
title_fullStr |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
title_full_unstemmed |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
title_sort |
Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts : a new indirect route to store and transport gas hydrocarbon fuels. |
author |
Oliveira, Patrícia E. F. |
author_facet |
Oliveira, Patrícia E. F. Ribeiro, Leandro Passos Rosmaninho, Marcelo Gonçalves Ardisson, José Domingos Dias, Anderson Oliveira, Luiz Carlos Alves de Lago, Rochel Montero |
author_role |
author |
author2 |
Ribeiro, Leandro Passos Rosmaninho, Marcelo Gonçalves Ardisson, José Domingos Dias, Anderson Oliveira, Luiz Carlos Alves de Lago, Rochel Montero |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Oliveira, Patrícia E. F. Ribeiro, Leandro Passos Rosmaninho, Marcelo Gonçalves Ardisson, José Domingos Dias, Anderson Oliveira, Luiz Carlos Alves de Lago, Rochel Montero |
dc.subject.por.fl_str_mv |
Natural gas Deposition oxidation Syngas production |
topic |
Natural gas Deposition oxidation Syngas production |
description |
In this work, a new two-step route to store and transport associated natural gas, promoted by Ni, Fe and Co supported catalyst was presented. Initially, CH4 is converted into carbon deposits (M/C composite), being Fe catalyst the most active catalyst. In Step 2, M/C composite reacts with H2O producing H2, CO and CH4. TPO experiments showed that efficiency and selectivity of oxidation depends on the metal. Ni catalyst produced mainly H2 and CO, while Fe system was more selective to convert carbon into CH4. The formation of C2 and C3 compounds suggests the presence of a Fischer Tropsch like process. |
publishDate |
2013 |
dc.date.issued.fl_str_mv |
2013 |
dc.date.accessioned.fl_str_mv |
2015-04-01T17:29:16Z |
dc.date.available.fl_str_mv |
2015-04-01T17:29:16Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
OLIVEIRA, P. E. F. et al. Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts: a new indirect route to store and transport gas hydrocarbon fuels. Catalysis Communications, v. 32, p. 58-61, 2013. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736712004414>. Acesso em: 02 fev. 2015. |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufop.br/handle/123456789/4909 |
dc.identifier.issn.none.fl_str_mv |
1566-7367 |
dc.identifier.doi.none.fl_str_mv |
https://doi.org/10.1016/j.catcom.2012.11.021 |
identifier_str_mv |
OLIVEIRA, P. E. F. et al. Catalytic carbon deposition-oxidation over Ni, Fe and Co catalysts: a new indirect route to store and transport gas hydrocarbon fuels. Catalysis Communications, v. 32, p. 58-61, 2013. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736712004414>. Acesso em: 02 fev. 2015. 1566-7367 |
url |
http://www.repositorio.ufop.br/handle/123456789/4909 https://doi.org/10.1016/j.catcom.2012.11.021 |
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eng |
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