Production of activated biochar from coconut fi ber for the removal of organic compounds from phenolic

• Autor(a) principal: Bispo, Mozart Daltro
• Data de Publicação: 2018
• Outros Autores: Schneider, Jaderson Kleveston, Oliveira, Diego da Silva, Tomasini, Debora, Maciel, Gabriela Pereira da Silva, Schena, Tiago, Onorevoli, Bruna, Bjerk, Thiago Rodrigues, Jacques, Rosângela Assis, Krause, Laiza Canielas, Caramão, Elina Bastos
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UFRGS
• Texto Completo: http://hdl.handle.net/10183/222185
• topic: Biochar; Fibra de coco; Compostos orgânicos; Compostos fenólicos; Carvão ativado; Cromatografia liquida; Activated carbon; Biochar; Phenolic liquor; Liquid chromatography; Coconut fibers

The biochar is characterized by low surface area and, in order to their use as adsorbent it is possible to use the activation process that allows to liberate and to increase the pores of the surface, increasing its sorption capacity. In the present work the activation of the biochar produced in the pyrolysis of agroindustrial residue (fiber) of the green coconut was studied, being done with sodium carbonate (Na2CO3) at high temperature. Biochar (BC) and activated biochar (ABC) were characterized and ABC was tested for use in the extraction of organic compounds present in the phenolic liquor, produced during the same pyrolysis process. The determination of the textural characteristics was done by N2 adsorption-desorption isotherms, obtaining an area of 1130 m2 g−1 for the ABC, being superior to the area of commercial activated coals, with a total volume of pores of 0.55 cm3 g−1. For the solid phase extraction (SPE) test, 500 mg of ABC were used in cartridges (equal to the commercial ones) obtaining a retention of about 100% of the organic compounds pre-existing in the sample, demonstrating the high adsorptive capacity of the activated biochar produced in this work. Desorption, as expected, had a lower performance than adsorption, being improved using ultrasonic bath, reaching values of the order of 40% recovery.