Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/41520 |
Resumo: | In this work, the rheological, mechanical and morphological behavior of immiscible blend poly (methyl methacrylate) with elastomeric particles (PMMAelast) and post-consumer poly (ethylene terephthalate) (PET) with and without the use of the interfacial compatibilizer poly (methyl methacrylate-co-glycidyl methacrylate-co-ethyl acrylate) (MGE) was studied. The significant increase in torque presented in rheological analyses has shown a indication of chemical reactions between the epoxy group of MGE with end groups of PET chains and also with the elastomeric phase of PMMAelast. The increased concentration of PET yielded an increase in maximum strength and elasticity modulus and a decrease in elongation at break. The PMMAelast/PET binary blend (50/50 wt%) and PMMAelast/PET/MGE compatibilized blend (65/30/5 wt%) showed pronounced results in elongation at break compared to PMMAelast, whereas, in the first results were due to the evidence of a co-continuous morphological structure and in the second, due to the efficiency of the dual reactive interfacial compatibilization of PMMAelast/PET blends. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses showed that PMMAelast/PET/MGE blends exhibit complex phase morphology due to the presence of elastomeric particles in the PMMAelast copolymer and in the use of MGE terpolymer |
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Ito, Edson NoriyukiReinaldo, Juciklécia da SilvaNascimento, Maria Carolina Burgos Costa doHage Junior, Elias2021-10-01T14:46:23Z2021-10-01T14:46:23Z2015-10REINALDO, Juciklécia da Silva; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki; HAGE JUNIOR, Elias. Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization. Polímeros, [S.L.], v. 25, n. 5, p. 451-460, out. 2015. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500006&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/0104-1428.1924.0104-14281678-5169https://repositorio.ufrn.br/handle/123456789/4152010.1590/0104-1428.1924SciELOAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessPMMA copolymerPost-consumer PETMorphologyReactive extrusionRheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilizationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleIn this work, the rheological, mechanical and morphological behavior of immiscible blend poly (methyl methacrylate) with elastomeric particles (PMMAelast) and post-consumer poly (ethylene terephthalate) (PET) with and without the use of the interfacial compatibilizer poly (methyl methacrylate-co-glycidyl methacrylate-co-ethyl acrylate) (MGE) was studied. The significant increase in torque presented in rheological analyses has shown a indication of chemical reactions between the epoxy group of MGE with end groups of PET chains and also with the elastomeric phase of PMMAelast. The increased concentration of PET yielded an increase in maximum strength and elasticity modulus and a decrease in elongation at break. The PMMAelast/PET binary blend (50/50 wt%) and PMMAelast/PET/MGE compatibilized blend (65/30/5 wt%) showed pronounced results in elongation at break compared to PMMAelast, whereas, in the first results were due to the evidence of a co-continuous morphological structure and in the second, due to the efficiency of the dual reactive interfacial compatibilization of PMMAelast/PET blends. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses showed that PMMAelast/PET/MGE blends exhibit complex phase morphology due to the presence of elastomeric particles in the PMMAelast copolymer and in the use of MGE terpolymerengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/41520/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52ORIGINALRheologicalMechanicalMorphological_ITO_2015.pdfRheologicalMechanicalMorphological_ITO_2015.pdfapplication/pdf3350385https://repositorio.ufrn.br/bitstream/123456789/41520/1/RheologicalMechanicalMorphological_ITO_2015.pdf9e35f9e75d9906261fd04125caef35b7MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/41520/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/415202021-10-01 11:46:24.232oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-10-01T14:46:24Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
title |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
spellingShingle |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization Ito, Edson Noriyuki PMMA copolymer Post-consumer PET Morphology Reactive extrusion |
title_short |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
title_full |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
title_fullStr |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
title_full_unstemmed |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
title_sort |
Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization |
author |
Ito, Edson Noriyuki |
author_facet |
Ito, Edson Noriyuki Reinaldo, Juciklécia da Silva Nascimento, Maria Carolina Burgos Costa do Hage Junior, Elias |
author_role |
author |
author2 |
Reinaldo, Juciklécia da Silva Nascimento, Maria Carolina Burgos Costa do Hage Junior, Elias |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Ito, Edson Noriyuki Reinaldo, Juciklécia da Silva Nascimento, Maria Carolina Burgos Costa do Hage Junior, Elias |
dc.subject.por.fl_str_mv |
PMMA copolymer Post-consumer PET Morphology Reactive extrusion |
topic |
PMMA copolymer Post-consumer PET Morphology Reactive extrusion |
description |
In this work, the rheological, mechanical and morphological behavior of immiscible blend poly (methyl methacrylate) with elastomeric particles (PMMAelast) and post-consumer poly (ethylene terephthalate) (PET) with and without the use of the interfacial compatibilizer poly (methyl methacrylate-co-glycidyl methacrylate-co-ethyl acrylate) (MGE) was studied. The significant increase in torque presented in rheological analyses has shown a indication of chemical reactions between the epoxy group of MGE with end groups of PET chains and also with the elastomeric phase of PMMAelast. The increased concentration of PET yielded an increase in maximum strength and elasticity modulus and a decrease in elongation at break. The PMMAelast/PET binary blend (50/50 wt%) and PMMAelast/PET/MGE compatibilized blend (65/30/5 wt%) showed pronounced results in elongation at break compared to PMMAelast, whereas, in the first results were due to the evidence of a co-continuous morphological structure and in the second, due to the efficiency of the dual reactive interfacial compatibilization of PMMAelast/PET blends. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses showed that PMMAelast/PET/MGE blends exhibit complex phase morphology due to the presence of elastomeric particles in the PMMAelast copolymer and in the use of MGE terpolymer |
publishDate |
2015 |
dc.date.issued.fl_str_mv |
2015-10 |
dc.date.accessioned.fl_str_mv |
2021-10-01T14:46:23Z |
dc.date.available.fl_str_mv |
2021-10-01T14:46:23Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
REINALDO, Juciklécia da Silva; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki; HAGE JUNIOR, Elias. Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization. Polímeros, [S.L.], v. 25, n. 5, p. 451-460, out. 2015. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500006&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/0104-1428.1924. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/41520 |
dc.identifier.issn.none.fl_str_mv |
0104-1428 1678-5169 |
dc.identifier.doi.none.fl_str_mv |
10.1590/0104-1428.1924 |
identifier_str_mv |
REINALDO, Juciklécia da Silva; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki; HAGE JUNIOR, Elias. Rheological, mechanical and morphological properties of poly(methyl methacrylate)/poly(ethylene terephthalate) blend with dual reactive interfacial compatibilization. Polímeros, [S.L.], v. 25, n. 5, p. 451-460, out. 2015. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282015000500006&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/0104-1428.1924. 0104-1428 1678-5169 10.1590/0104-1428.1924 |
url |
https://repositorio.ufrn.br/handle/123456789/41520 |
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eng |
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eng |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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SciELO |
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SciELO |
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