Treatment of materials contaminated with polychlorinated biphenyls (Pcbs): comparison of traditional method and supercritical fluid extraction

• Autor(a) principal: Silva, Dannielle Janainne da
• Data de Publicação: 2012
• Outros Autores: Pietri, Felipe V., Moraes, José Ermirio F., Bazito, Reinaldo Camino, Courtial, Camila Gambini Pereira
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UFRN
• Texto Completo: https://repositorio.ufrn.br/handle/123456789/32545
• topic: Polychlorinated Biphenyls; Extraction; Soil; Wood

The objective of this study was to develop an experimental methodology for the extraction of polychlorinated biphenyls (PCBs) from contaminated soil and wood material using the Soxhlet extraction method and supercritical fluid techno- logy. The sample PCB contents were quantified using Gas Chromatography-Mass Spectrometry (GC/MS). Conven- tional extractions of PCBs from soil samples showed higher extraction yields for samples with the highest initial PCB levels and longest extraction times. Specific PCBs yielded 74.0% - 78.3% removal using ethanol as the solvent. 91.0% - 94.3% removal of the total PCB content was achieved using hexane as the solvent. Supercritical fluid extraction of soil samples resulted in 50.0% - 70.5% removal for specific PCBs and 57.3% removal of the total PCB content. For wood, the use of Soxhlet extraction resulted in 87.0% - 94.0% removal for specific PCBs and 95.0% - 96.3% removal of the total PCB content. Supercritical fluid extraction of wood samples resulted in 91.1% - 95.0% removal of specific PCBs and 95.1 % of the total PCB content