Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet
Autor(a) principal: | |
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Data de Publicação: | 2006 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/32389 |
Resumo: | High-frequency pulsed plasma (HFPP) was applied to produce hydrogen by reforming natural gas. The process is based on the molecular dissociation of the gas into different ionized species, such as H+ and H+2 . The plasma was generated applying a pulsed voltage in an atmosphere of methane. The efficiency of the system was optimized by adjusting the frequency of the pulsed plasma aiming at maximum selectivity to hydrogen. The reforming of natural gas was accompanied by the simultaneous storage of hydrogen in a hollow cathode set-up made of titanium. Hydrogen contents higher than 900 ppm (in weight%) were stored in the Ti cathode. The efficiency of the method was compatible to industrial applications. Pyrolitic carbon condensed on the lower walls of the reactor but did not interfere with the kinetics of hydrogen absorption. In fact, the carbon produced in such manner could be considered a byproduct of the process and can be used as natural gas adsorbent once adequately activated |
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Silva, C. F. daIshikawa, TomazSantos, Sydney FerreiraAlves Júnior, ClodomiroMartinelli, Antonio Eduardo2021-05-05T12:23:56Z2021-05-05T12:23:56Z2006-01DASILVA, C; ISHIKAWA, T; SANTOS, S; ALVESJR, C; A MARTINELLI,. Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet. International Journal of Hydrogen Energy, [S.L.], v. 31, n. 1, p. 49-54, jan. 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0360319905000704?via%3Dihub. Acesso em: 19 nov. 2020. http://dx.doi.org/10.1016/j.ijhydene.2005.03.007.0360-3199https://repositorio.ufrn.br/handle/123456789/3238910.1016/j.ijhydene.2005.03.007ElsevierHydrogen storageHigh-frequency pulsed plasmaNatural gasMethaneProduction of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheetinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleHigh-frequency pulsed plasma (HFPP) was applied to produce hydrogen by reforming natural gas. The process is based on the molecular dissociation of the gas into different ionized species, such as H+ and H+2 . The plasma was generated applying a pulsed voltage in an atmosphere of methane. The efficiency of the system was optimized by adjusting the frequency of the pulsed plasma aiming at maximum selectivity to hydrogen. The reforming of natural gas was accompanied by the simultaneous storage of hydrogen in a hollow cathode set-up made of titanium. Hydrogen contents higher than 900 ppm (in weight%) were stored in the Ti cathode. The efficiency of the method was compatible to industrial applications. Pyrolitic carbon condensed on the lower walls of the reactor but did not interfere with the kinetics of hydrogen absorption. In fact, the carbon produced in such manner could be considered a byproduct of the process and can be used as natural gas adsorbent once adequately activatedengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNinfo:eu-repo/semantics/openAccessCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/32389/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/32389/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/323892023-02-07 17:27:26.725oai:https://repositorio.ufrn.br:123456789/32389Tk9OLUVYQ0xVU0lWRSBESVNUUklCVVRJT04gTElDRU5TRQoKCkJ5IHNpZ25pbmcgYW5kIGRlbGl2ZXJpbmcgdGhpcyBsaWNlbnNlLCBNci4gKGF1dGhvciBvciBjb3B5cmlnaHQgaG9sZGVyKToKCgphKSBHcmFudHMgdGhlIFVuaXZlcnNpZGFkZSBGZWRlcmFsIFJpbyBHcmFuZGUgZG8gTm9ydGUgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgb2YKcmVwcm9kdWNlLCBjb252ZXJ0IChhcyBkZWZpbmVkIGJlbG93KSwgY29tbXVuaWNhdGUgYW5kIC8gb3IKZGlzdHJpYnV0ZSB0aGUgZGVsaXZlcmVkIGRvY3VtZW50IChpbmNsdWRpbmcgYWJzdHJhY3QgLyBhYnN0cmFjdCkgaW4KZGlnaXRhbCBvciBwcmludGVkIGZvcm1hdCBhbmQgaW4gYW55IG1lZGl1bS4KCmIpIERlY2xhcmVzIHRoYXQgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBpdHMgb3JpZ2luYWwgd29yaywgYW5kIHRoYXQKeW91IGhhdmUgdGhlIHJpZ2h0IHRvIGdyYW50IHRoZSByaWdodHMgY29udGFpbmVkIGluIHRoaXMgbGljZW5zZS4gRGVjbGFyZXMKdGhhdCB0aGUgZGVsaXZlcnkgb2YgdGhlIGRvY3VtZW50IGRvZXMgbm90IGluZnJpbmdlLCBhcyBmYXIgYXMgaXQgaXMKdGhlIHJpZ2h0cyBvZiBhbnkgb3RoZXIgcGVyc29uIG9yIGVudGl0eS4KCmMpIElmIHRoZSBkb2N1bWVudCBkZWxpdmVyZWQgY29udGFpbnMgbWF0ZXJpYWwgd2hpY2ggZG9lcyBub3QKcmlnaHRzLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBvYnRhaW5lZCBhdXRob3JpemF0aW9uIGZyb20gdGhlIGhvbGRlciBvZiB0aGUKY29weXJpZ2h0IHRvIGdyYW50IHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdCB0aGlzIG1hdGVyaWFsIHdob3NlIHJpZ2h0cyBhcmUgb2YKdGhpcmQgcGFydGllcyBpcyBjbGVhcmx5IGlkZW50aWZpZWQgYW5kIHJlY29nbml6ZWQgaW4gdGhlIHRleHQgb3IKY29udGVudCBvZiB0aGUgZG9jdW1lbnQgZGVsaXZlcmVkLgoKSWYgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBiYXNlZCBvbiBmdW5kZWQgb3Igc3VwcG9ydGVkIHdvcmsKYnkgYW5vdGhlciBpbnN0aXR1dGlvbiBvdGhlciB0aGFuIHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBmdWxmaWxsZWQgYW55IG9ibGlnYXRpb25zIHJlcXVpcmVkIGJ5IHRoZSByZXNwZWN0aXZlIGFncmVlbWVudCBvciBhZ3JlZW1lbnQuCgpUaGUgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZG8gUmlvIEdyYW5kZSBkbyBOb3J0ZSB3aWxsIGNsZWFybHkgaWRlbnRpZnkgaXRzIG5hbWUgKHMpIGFzIHRoZSBhdXRob3IgKHMpIG9yIGhvbGRlciAocykgb2YgdGhlIGRvY3VtZW50J3MgcmlnaHRzCmRlbGl2ZXJlZCwgYW5kIHdpbGwgbm90IG1ha2UgYW55IGNoYW5nZXMsIG90aGVyIHRoYW4gdGhvc2UgcGVybWl0dGVkIGJ5CnRoaXMgbGljZW5zZQo=Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2023-02-07T20:27:26Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
title |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
spellingShingle |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet Silva, C. F. da Hydrogen storage High-frequency pulsed plasma Natural gas Methane |
title_short |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
title_full |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
title_fullStr |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
title_full_unstemmed |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
title_sort |
Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet |
author |
Silva, C. F. da |
author_facet |
Silva, C. F. da Ishikawa, Tomaz Santos, Sydney Ferreira Alves Júnior, Clodomiro Martinelli, Antonio Eduardo |
author_role |
author |
author2 |
Ishikawa, Tomaz Santos, Sydney Ferreira Alves Júnior, Clodomiro Martinelli, Antonio Eduardo |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Silva, C. F. da Ishikawa, Tomaz Santos, Sydney Ferreira Alves Júnior, Clodomiro Martinelli, Antonio Eduardo |
dc.subject.por.fl_str_mv |
Hydrogen storage High-frequency pulsed plasma Natural gas Methane |
topic |
Hydrogen storage High-frequency pulsed plasma Natural gas Methane |
description |
High-frequency pulsed plasma (HFPP) was applied to produce hydrogen by reforming natural gas. The process is based on the molecular dissociation of the gas into different ionized species, such as H+ and H+2 . The plasma was generated applying a pulsed voltage in an atmosphere of methane. The efficiency of the system was optimized by adjusting the frequency of the pulsed plasma aiming at maximum selectivity to hydrogen. The reforming of natural gas was accompanied by the simultaneous storage of hydrogen in a hollow cathode set-up made of titanium. Hydrogen contents higher than 900 ppm (in weight%) were stored in the Ti cathode. The efficiency of the method was compatible to industrial applications. Pyrolitic carbon condensed on the lower walls of the reactor but did not interfere with the kinetics of hydrogen absorption. In fact, the carbon produced in such manner could be considered a byproduct of the process and can be used as natural gas adsorbent once adequately activated |
publishDate |
2006 |
dc.date.issued.fl_str_mv |
2006-01 |
dc.date.accessioned.fl_str_mv |
2021-05-05T12:23:56Z |
dc.date.available.fl_str_mv |
2021-05-05T12:23:56Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
DASILVA, C; ISHIKAWA, T; SANTOS, S; ALVESJR, C; A MARTINELLI,. Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet. International Journal of Hydrogen Energy, [S.L.], v. 31, n. 1, p. 49-54, jan. 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0360319905000704?via%3Dihub. Acesso em: 19 nov. 2020. http://dx.doi.org/10.1016/j.ijhydene.2005.03.007. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/32389 |
dc.identifier.issn.none.fl_str_mv |
0360-3199 |
dc.identifier.doi.none.fl_str_mv |
10.1016/j.ijhydene.2005.03.007 |
identifier_str_mv |
DASILVA, C; ISHIKAWA, T; SANTOS, S; ALVESJR, C; A MARTINELLI,. Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet. International Journal of Hydrogen Energy, [S.L.], v. 31, n. 1, p. 49-54, jan. 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0360319905000704?via%3Dihub. Acesso em: 19 nov. 2020. http://dx.doi.org/10.1016/j.ijhydene.2005.03.007. 0360-3199 10.1016/j.ijhydene.2005.03.007 |
url |
https://repositorio.ufrn.br/handle/123456789/32389 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
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reponame:Repositório Institucional da UFRN instname:Universidade Federal do Rio Grande do Norte (UFRN) instacron:UFRN |
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