Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/30575 |
Resumo: | The use of niobium containing materials' has gained much attention of the scientific community in the late years due its various applications in diverse fields. NbC is a highly versatile material. Copper addition may alter several of its properties, such as morphology, crystal structure etc. as well as enhance its catalytic behavior. Nanostructured NbC with copper addition synthesis' presented here had the precursor [(NH4 )3[NbO(C2O4)3]xH2O] as starting material, which was doped with Cu(NO3)2at 5% and 10% (molar) ratios. Doped NbC was obtained via gas solid reaction in fixed bed reactor at lower temperature (980°C) and with shorter reaction time (2h) than traditional methods. Reaction products' were characterized by XRD, crystal sizes were estimated according to HWL method, and SEM, XRF, BET and laser particle size analysis were performed. XRD indicated the formation of NbC and Cu phases with cubic crystal structure of ~20nm. SEM showed slight morphological change upon increasing copper content, indicating a less porous structure, which is consistent with BET data (43.7m2/g for 5%Cu-NbC and 37m 2/g for the 10% Cu-NbC). Crystal size calculations showed that increasing dopant content particle sizes were also increased, probably due to the presence of the dopant, in some extent, in the crystal structure |
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Borges, Filipe Martel MagalhãesSouto, Maria Veronilda MacedoAraujo, Camila Pacelly Brandão deLima, Maria José SantosGomes, Uilame UmbelinoSouza, Carlson Pereira de2020-11-13T15:02:38Z2020-11-13T15:02:38Z2018-02-26SOUTO, Maria Veronilda Macedo; ARAUJO, Camila Pacelly Brandão de; LIMA, Maria José Santos; BORGES, Filipe Martel Magalhães; GOMES, Uilame Umbelino; SOUZA, Carlson Pereira de. Synthesis and Characterization of Niobium Carbide with Copper Addition Obtained Via Gas Solid Reaction. Materials Research, [S.L.], v. 21, n. 3, p. 3-3, 26 fev. 2018. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000300003. Acesso em: 14 set. 2020. http://dx.doi.org/10.1590/1980-5373-mr-2016-1108.1516-14391980-5373https://repositorio.ufrn.br/handle/123456789/3057510.1590/1980-5373-MR-2016-1108ABM, ABC, ABPolAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessNiobium carbideGas solid reactionCopperFixed bed reactorSynthesis and characterization of niobium carbide with copper addition obtained via gas solid reactioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe use of niobium containing materials' has gained much attention of the scientific community in the late years due its various applications in diverse fields. NbC is a highly versatile material. Copper addition may alter several of its properties, such as morphology, crystal structure etc. as well as enhance its catalytic behavior. Nanostructured NbC with copper addition synthesis' presented here had the precursor [(NH4 )3[NbO(C2O4)3]xH2O] as starting material, which was doped with Cu(NO3)2at 5% and 10% (molar) ratios. Doped NbC was obtained via gas solid reaction in fixed bed reactor at lower temperature (980°C) and with shorter reaction time (2h) than traditional methods. Reaction products' were characterized by XRD, crystal sizes were estimated according to HWL method, and SEM, XRF, BET and laser particle size analysis were performed. XRD indicated the formation of NbC and Cu phases with cubic crystal structure of ~20nm. SEM showed slight morphological change upon increasing copper content, indicating a less porous structure, which is consistent with BET data (43.7m2/g for 5%Cu-NbC and 37m 2/g for the 10% Cu-NbC). Crystal size calculations showed that increasing dopant content particle sizes were also increased, probably due to the presence of the dopant, in some extent, in the crystal structureengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALSynthesisCharacterization_BORGES_2018.pdfSynthesisCharacterization_BORGES_2018.pdfapplication/pdf2301603https://repositorio.ufrn.br/bitstream/123456789/30575/1/SynthesisCharacterization_BORGES_2018.pdf7c42f47d11a72572a0c60a8895964f73MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/30575/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/30575/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTSynthesisCharacterization_BORGES_2018.pdf.txtSynthesisCharacterization_BORGES_2018.pdf.txtExtracted texttext/plain25922https://repositorio.ufrn.br/bitstream/123456789/30575/4/SynthesisCharacterization_BORGES_2018.pdf.txt128a6453f38a18084c52f1fa75d8a091MD54THUMBNAILSynthesisCharacterization_BORGES_2018.pdf.jpgSynthesisCharacterization_BORGES_2018.pdf.jpgGenerated Thumbnailimage/jpeg1621https://repositorio.ufrn.br/bitstream/123456789/30575/5/SynthesisCharacterization_BORGES_2018.pdf.jpg17dabb3aa1aecef7264eed60591a1adaMD55123456789/305752020-11-15 05:07:04.282oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2020-11-15T08:07:04Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
title |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
spellingShingle |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction Borges, Filipe Martel Magalhães Niobium carbide Gas solid reaction Copper Fixed bed reactor |
title_short |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
title_full |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
title_fullStr |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
title_full_unstemmed |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
title_sort |
Synthesis and characterization of niobium carbide with copper addition obtained via gas solid reaction |
author |
Borges, Filipe Martel Magalhães |
author_facet |
Borges, Filipe Martel Magalhães Souto, Maria Veronilda Macedo Araujo, Camila Pacelly Brandão de Lima, Maria José Santos Gomes, Uilame Umbelino Souza, Carlson Pereira de |
author_role |
author |
author2 |
Souto, Maria Veronilda Macedo Araujo, Camila Pacelly Brandão de Lima, Maria José Santos Gomes, Uilame Umbelino Souza, Carlson Pereira de |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Borges, Filipe Martel Magalhães Souto, Maria Veronilda Macedo Araujo, Camila Pacelly Brandão de Lima, Maria José Santos Gomes, Uilame Umbelino Souza, Carlson Pereira de |
dc.subject.por.fl_str_mv |
Niobium carbide Gas solid reaction Copper Fixed bed reactor |
topic |
Niobium carbide Gas solid reaction Copper Fixed bed reactor |
description |
The use of niobium containing materials' has gained much attention of the scientific community in the late years due its various applications in diverse fields. NbC is a highly versatile material. Copper addition may alter several of its properties, such as morphology, crystal structure etc. as well as enhance its catalytic behavior. Nanostructured NbC with copper addition synthesis' presented here had the precursor [(NH4 )3[NbO(C2O4)3]xH2O] as starting material, which was doped with Cu(NO3)2at 5% and 10% (molar) ratios. Doped NbC was obtained via gas solid reaction in fixed bed reactor at lower temperature (980°C) and with shorter reaction time (2h) than traditional methods. Reaction products' were characterized by XRD, crystal sizes were estimated according to HWL method, and SEM, XRF, BET and laser particle size analysis were performed. XRD indicated the formation of NbC and Cu phases with cubic crystal structure of ~20nm. SEM showed slight morphological change upon increasing copper content, indicating a less porous structure, which is consistent with BET data (43.7m2/g for 5%Cu-NbC and 37m 2/g for the 10% Cu-NbC). Crystal size calculations showed that increasing dopant content particle sizes were also increased, probably due to the presence of the dopant, in some extent, in the crystal structure |
publishDate |
2018 |
dc.date.issued.fl_str_mv |
2018-02-26 |
dc.date.accessioned.fl_str_mv |
2020-11-13T15:02:38Z |
dc.date.available.fl_str_mv |
2020-11-13T15:02:38Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SOUTO, Maria Veronilda Macedo; ARAUJO, Camila Pacelly Brandão de; LIMA, Maria José Santos; BORGES, Filipe Martel Magalhães; GOMES, Uilame Umbelino; SOUZA, Carlson Pereira de. Synthesis and Characterization of Niobium Carbide with Copper Addition Obtained Via Gas Solid Reaction. Materials Research, [S.L.], v. 21, n. 3, p. 3-3, 26 fev. 2018. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000300003. Acesso em: 14 set. 2020. http://dx.doi.org/10.1590/1980-5373-mr-2016-1108. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/30575 |
dc.identifier.issn.none.fl_str_mv |
1516-1439 1980-5373 |
dc.identifier.doi.none.fl_str_mv |
10.1590/1980-5373-MR-2016-1108 |
identifier_str_mv |
SOUTO, Maria Veronilda Macedo; ARAUJO, Camila Pacelly Brandão de; LIMA, Maria José Santos; BORGES, Filipe Martel Magalhães; GOMES, Uilame Umbelino; SOUZA, Carlson Pereira de. Synthesis and Characterization of Niobium Carbide with Copper Addition Obtained Via Gas Solid Reaction. Materials Research, [S.L.], v. 21, n. 3, p. 3-3, 26 fev. 2018. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392018000300003. Acesso em: 14 set. 2020. http://dx.doi.org/10.1590/1980-5373-mr-2016-1108. 1516-1439 1980-5373 10.1590/1980-5373-MR-2016-1108 |
url |
https://repositorio.ufrn.br/handle/123456789/30575 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
publisher.none.fl_str_mv |
ABM, ABC, ABPol |
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reponame:Repositório Institucional da UFRN instname:Universidade Federal do Rio Grande do Norte (UFRN) instacron:UFRN |
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Universidade Federal do Rio Grande do Norte (UFRN) |
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UFRN |
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UFRN |
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Repositório Institucional da UFRN |
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Repositório Institucional da UFRN |
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