Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches

Detalhes bibliográficos
Autor(a) principal: Santos, Elisama Vieira dos
Data de Publicação: 2017
Outros Autores: Sáez, Cristina, Cañizares, Pablo Canizares, Silva, Djalma Ribeiro da, Martínez-Huitle, Carlos Alberto, Rodrigo, Manuel Andres
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/jspui/handle/123456789/29774
Resumo: In this research, the treatment of soil spiked with petroleum was studied using a surfactant-aided soil-washing (SASW) process followed by sonolysis (US), photolysis and boron doped diamond electrolysis (BDD-electrolysis) for washing liquid treatment. Results clearly demonstrate that SASW is a very efficient approach in the treatment of soil, removing completely the petrochemical compounds by using dosages about 5 g of extracting surfactant (sodium dodecyl sulfate (SDS)) per kg of soil. The main characteristics of the effluents produced in this soil remediation technology as well as the efficiency of the treatment (US, photolysis and BDD-electrolysis) depend on the dosage of SDS. Depollution of the effluents (degradation and mineralization of the organic matter) is related to the reduction in size of micelles formed by SDS and petroleum, and it depends on the treatment used. US and photolysis were inefficient decontamination processes, while BDD-electrolysis favors the complete depletion of micelles. However, the intensification of the efficiency was attained by synergic degradation effects when UV light irradiation and US were coupled with BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis, respectively. Sulfate (coming from SDS) ions play an important role during the BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis because persulfate and persulfate radicals are produced (by sulfate activation applying US or photolysis), improving the efficiency of the processes
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spelling Santos, Elisama Vieira dosSáez, CristinaCañizares, Pablo CanizaresSilva, Djalma Ribeiro daMartínez-Huitle, Carlos AlbertoRodrigo, Manuel Andres2020-08-03T19:05:49Z2020-08-03T19:05:49Z2017-02-15SANTOS, E.V.; SÁEZ, C.; CAÑIZARES, P.; SILVA, D.R.; MARTÍNEZ-HUITLE, C.A. ; RODRIGO, M.A.. Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches. Chemical Engineering Journal (1996), v. 310, p. 581-588, 2017. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S1385894716306374?via%3Dihub#! Acesso em: 30 jul. 2020. https://doi.org/10.1016/j.cej.2016.05.0151385-8947https://repositorio.ufrn.br/jspui/handle/123456789/2977410.1016/j.cej.2016.05.015ElsevierPetroleumSoil washingSonolysisPhoto-electrolysisSono-electrolysisDiamond electrodeTreatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approachesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleIn this research, the treatment of soil spiked with petroleum was studied using a surfactant-aided soil-washing (SASW) process followed by sonolysis (US), photolysis and boron doped diamond electrolysis (BDD-electrolysis) for washing liquid treatment. Results clearly demonstrate that SASW is a very efficient approach in the treatment of soil, removing completely the petrochemical compounds by using dosages about 5 g of extracting surfactant (sodium dodecyl sulfate (SDS)) per kg of soil. The main characteristics of the effluents produced in this soil remediation technology as well as the efficiency of the treatment (US, photolysis and BDD-electrolysis) depend on the dosage of SDS. Depollution of the effluents (degradation and mineralization of the organic matter) is related to the reduction in size of micelles formed by SDS and petroleum, and it depends on the treatment used. US and photolysis were inefficient decontamination processes, while BDD-electrolysis favors the complete depletion of micelles. However, the intensification of the efficiency was attained by synergic degradation effects when UV light irradiation and US were coupled with BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis, respectively. Sulfate (coming from SDS) ions play an important role during the BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis because persulfate and persulfate radicals are produced (by sulfate activation applying US or photolysis), improving the efficiency of the processesengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNinfo:eu-repo/semantics/openAccessCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/29774/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/29774/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTTreatmentOfEx-situ_Santos_2017.pdf.txtTreatmentOfEx-situ_Santos_2017.pdf.txtExtracted texttext/plain43271https://repositorio.ufrn.br/bitstream/123456789/29774/4/TreatmentOfEx-situ_Santos_2017.pdf.txt10705362794f6b346434dff405d84531MD54THUMBNAILTreatmentOfEx-situ_Santos_2017.pdf.jpgTreatmentOfEx-situ_Santos_2017.pdf.jpgGenerated Thumbnailimage/jpeg1647https://repositorio.ufrn.br/bitstream/123456789/29774/5/TreatmentOfEx-situ_Santos_2017.pdf.jpgebc53e67cead772518510e4732c6d95bMD55123456789/297742023-02-01 17:16:19.528oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2023-02-01T20:16:19Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
title Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
spellingShingle Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
Santos, Elisama Vieira dos
Petroleum
Soil washing
Sonolysis
Photo-electrolysis
Sono-electrolysis
Diamond electrode
title_short Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
title_full Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
title_fullStr Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
title_full_unstemmed Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
title_sort Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches
author Santos, Elisama Vieira dos
author_facet Santos, Elisama Vieira dos
Sáez, Cristina
Cañizares, Pablo Canizares
Silva, Djalma Ribeiro da
Martínez-Huitle, Carlos Alberto
Rodrigo, Manuel Andres
author_role author
author2 Sáez, Cristina
Cañizares, Pablo Canizares
Silva, Djalma Ribeiro da
Martínez-Huitle, Carlos Alberto
Rodrigo, Manuel Andres
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Santos, Elisama Vieira dos
Sáez, Cristina
Cañizares, Pablo Canizares
Silva, Djalma Ribeiro da
Martínez-Huitle, Carlos Alberto
Rodrigo, Manuel Andres
dc.subject.por.fl_str_mv Petroleum
Soil washing
Sonolysis
Photo-electrolysis
Sono-electrolysis
Diamond electrode
topic Petroleum
Soil washing
Sonolysis
Photo-electrolysis
Sono-electrolysis
Diamond electrode
description In this research, the treatment of soil spiked with petroleum was studied using a surfactant-aided soil-washing (SASW) process followed by sonolysis (US), photolysis and boron doped diamond electrolysis (BDD-electrolysis) for washing liquid treatment. Results clearly demonstrate that SASW is a very efficient approach in the treatment of soil, removing completely the petrochemical compounds by using dosages about 5 g of extracting surfactant (sodium dodecyl sulfate (SDS)) per kg of soil. The main characteristics of the effluents produced in this soil remediation technology as well as the efficiency of the treatment (US, photolysis and BDD-electrolysis) depend on the dosage of SDS. Depollution of the effluents (degradation and mineralization of the organic matter) is related to the reduction in size of micelles formed by SDS and petroleum, and it depends on the treatment used. US and photolysis were inefficient decontamination processes, while BDD-electrolysis favors the complete depletion of micelles. However, the intensification of the efficiency was attained by synergic degradation effects when UV light irradiation and US were coupled with BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis, respectively. Sulfate (coming from SDS) ions play an important role during the BDD-electrolysis, US/BDD-electrolysis and photo/BDD-electrolysis because persulfate and persulfate radicals are produced (by sulfate activation applying US or photolysis), improving the efficiency of the processes
publishDate 2017
dc.date.issued.fl_str_mv 2017-02-15
dc.date.accessioned.fl_str_mv 2020-08-03T19:05:49Z
dc.date.available.fl_str_mv 2020-08-03T19:05:49Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.citation.fl_str_mv SANTOS, E.V.; SÁEZ, C.; CAÑIZARES, P.; SILVA, D.R.; MARTÍNEZ-HUITLE, C.A. ; RODRIGO, M.A.. Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches. Chemical Engineering Journal (1996), v. 310, p. 581-588, 2017. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S1385894716306374?via%3Dihub#! Acesso em: 30 jul. 2020. https://doi.org/10.1016/j.cej.2016.05.015
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/jspui/handle/123456789/29774
dc.identifier.issn.none.fl_str_mv 1385-8947
dc.identifier.doi.none.fl_str_mv 10.1016/j.cej.2016.05.015
identifier_str_mv SANTOS, E.V.; SÁEZ, C.; CAÑIZARES, P.; SILVA, D.R.; MARTÍNEZ-HUITLE, C.A. ; RODRIGO, M.A.. Treatment of ex-situ soil-washing fluids polluted with petroleum by anodic oxidation, photolysis, sonolysis and combined approaches. Chemical Engineering Journal (1996), v. 310, p. 581-588, 2017. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S1385894716306374?via%3Dihub#! Acesso em: 30 jul. 2020. https://doi.org/10.1016/j.cej.2016.05.015
1385-8947
10.1016/j.cej.2016.05.015
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dc.publisher.none.fl_str_mv Elsevier
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