Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/32270 |
Resumo: | Silver chloride (AgCl) particles were produced by sonochemistry synthesis. The effect of the variables such as the time of synthesis, amount of surfactant and reagent in the photocatalytic property of AgCl have were all investigated. AgCl particles became well known for their high photocatalytic activity and their plasmonic properties because of the metallic silver on their surface. In this study, AgCl particles were prepared with sodium chloride (NaCl), polyvinylpyrrolidone and silver nitrate (AgNO3), using a full 23 factorial design and three central points, resulting in 11 experiments. The synthesis was carried out using ultrasonic tip at time intervals of 5, 20 and 35 min. It was used X-ray diffraction, scanning electron microscopy with field emission (SEM-FEG), UV–Vis degradation test and photoluminescence to characterize the particles. The experimental design not only used variables present in the photocatalytic ability of the particles, but also provided a mathematical model. The (ANOVA) analysis of variance was used to confirm this model. Thus the values predicted could be observed. It is provided a response surface that characterizes the optimization zone of the photocatalytic activity of the AgCl particles to better visualize the information about its effects |
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Paskocimas, Carlos AlbertoAndrade Neto, Nivaldo Freire deGarcia, Laurênia Martins PereiraSilva, Elson Longo daLi, Maximo SiuDelmonte, Maurício Roberto BomioMotta, Fabiana Villela da2021-04-19T14:09:59Z2021-04-19T14:09:59Z2017-05-03ANDRADE NETO, N. F.; GARCIA, L. M. P.; LONGO, E.; LI, M. S.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design. Journal of Materials Science: Materials in Electronics, [S.L.], v. 28, n. 16, p. 12273-12281, 3 maio 2017. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-017-7044-x. Acesso em: 11 dez. 2020. http://dx.doi.org/10.1007/s10854-017-7044-x.0957-45221573-482Xhttps://repositorio.ufrn.br/handle/123456789/3227010.1007/s10854-017-7044-xSpringerAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessPhotoluminescencePhotocatalytic propertiesAg/AgClSonochemistryStatistical experimental designPhotoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental designinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleSilver chloride (AgCl) particles were produced by sonochemistry synthesis. The effect of the variables such as the time of synthesis, amount of surfactant and reagent in the photocatalytic property of AgCl have were all investigated. AgCl particles became well known for their high photocatalytic activity and their plasmonic properties because of the metallic silver on their surface. In this study, AgCl particles were prepared with sodium chloride (NaCl), polyvinylpyrrolidone and silver nitrate (AgNO3), using a full 23 factorial design and three central points, resulting in 11 experiments. The synthesis was carried out using ultrasonic tip at time intervals of 5, 20 and 35 min. It was used X-ray diffraction, scanning electron microscopy with field emission (SEM-FEG), UV–Vis degradation test and photoluminescence to characterize the particles. The experimental design not only used variables present in the photocatalytic ability of the particles, but also provided a mathematical model. The (ANOVA) analysis of variance was used to confirm this model. Thus the values predicted could be observed. It is provided a response surface that characterizes the optimization zone of the photocatalytic activity of the AgCl particles to better visualize the information about its effectsengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdfPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdfapplication/pdf3091385https://repositorio.ufrn.br/bitstream/123456789/32270/1/PhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdffe29ac29287abcd267bc66e512639a7dMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/32270/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/32270/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.txtPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.txtExtracted texttext/plain29268https://repositorio.ufrn.br/bitstream/123456789/32270/4/PhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.txt320313ff371c5afb478f89d4796c6076MD54THUMBNAILPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.jpgPhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.jpgGenerated Thumbnailimage/jpeg1793https://repositorio.ufrn.br/bitstream/123456789/32270/5/PhotoluminescencePhotocatalytic_PASKOCIMAS_2017.pdf.jpg0298dccb2f881151b6452e6659e845fdMD55123456789/322702021-12-16 09:50:51.664oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-12-16T12:50:51Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
title |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
spellingShingle |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design Paskocimas, Carlos Alberto Photoluminescence Photocatalytic properties Ag/AgCl Sonochemistry Statistical experimental design |
title_short |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
title_full |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
title_fullStr |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
title_full_unstemmed |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
title_sort |
Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design |
author |
Paskocimas, Carlos Alberto |
author_facet |
Paskocimas, Carlos Alberto Andrade Neto, Nivaldo Freire de Garcia, Laurênia Martins Pereira Silva, Elson Longo da Li, Maximo Siu Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
author_role |
author |
author2 |
Andrade Neto, Nivaldo Freire de Garcia, Laurênia Martins Pereira Silva, Elson Longo da Li, Maximo Siu Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Paskocimas, Carlos Alberto Andrade Neto, Nivaldo Freire de Garcia, Laurênia Martins Pereira Silva, Elson Longo da Li, Maximo Siu Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
dc.subject.por.fl_str_mv |
Photoluminescence Photocatalytic properties Ag/AgCl Sonochemistry Statistical experimental design |
topic |
Photoluminescence Photocatalytic properties Ag/AgCl Sonochemistry Statistical experimental design |
description |
Silver chloride (AgCl) particles were produced by sonochemistry synthesis. The effect of the variables such as the time of synthesis, amount of surfactant and reagent in the photocatalytic property of AgCl have were all investigated. AgCl particles became well known for their high photocatalytic activity and their plasmonic properties because of the metallic silver on their surface. In this study, AgCl particles were prepared with sodium chloride (NaCl), polyvinylpyrrolidone and silver nitrate (AgNO3), using a full 23 factorial design and three central points, resulting in 11 experiments. The synthesis was carried out using ultrasonic tip at time intervals of 5, 20 and 35 min. It was used X-ray diffraction, scanning electron microscopy with field emission (SEM-FEG), UV–Vis degradation test and photoluminescence to characterize the particles. The experimental design not only used variables present in the photocatalytic ability of the particles, but also provided a mathematical model. The (ANOVA) analysis of variance was used to confirm this model. Thus the values predicted could be observed. It is provided a response surface that characterizes the optimization zone of the photocatalytic activity of the AgCl particles to better visualize the information about its effects |
publishDate |
2017 |
dc.date.issued.fl_str_mv |
2017-05-03 |
dc.date.accessioned.fl_str_mv |
2021-04-19T14:09:59Z |
dc.date.available.fl_str_mv |
2021-04-19T14:09:59Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
ANDRADE NETO, N. F.; GARCIA, L. M. P.; LONGO, E.; LI, M. S.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design. Journal of Materials Science: Materials in Electronics, [S.L.], v. 28, n. 16, p. 12273-12281, 3 maio 2017. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-017-7044-x. Acesso em: 11 dez. 2020. http://dx.doi.org/10.1007/s10854-017-7044-x. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/32270 |
dc.identifier.issn.none.fl_str_mv |
0957-4522 1573-482X |
dc.identifier.doi.none.fl_str_mv |
10.1007/s10854-017-7044-x |
identifier_str_mv |
ANDRADE NETO, N. F.; GARCIA, L. M. P.; LONGO, E.; LI, M. S.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Photoluminescence and photocatalytic properties of Ag/AgCl synthesized by sonochemistry: statistical experimental design. Journal of Materials Science: Materials in Electronics, [S.L.], v. 28, n. 16, p. 12273-12281, 3 maio 2017. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-017-7044-x. Acesso em: 11 dez. 2020. http://dx.doi.org/10.1007/s10854-017-7044-x. 0957-4522 1573-482X 10.1007/s10854-017-7044-x |
url |
https://repositorio.ufrn.br/handle/123456789/32270 |
dc.language.iso.fl_str_mv |
eng |
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eng |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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Springer |
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Springer |
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Universidade Federal do Rio Grande do Norte (UFRN) |
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UFRN |
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UFRN |
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Repositório Institucional da UFRN |
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Repositório Institucional da UFRN |
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