The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)

Bibliographic Details
Main Author: Oliveira, Adriano Bof de
Publication Date: 2013
Other Authors: Beck, Johannes, Daniels, Jörg, Santos, Jaciara Nascimento, Feitosa, Bárbara Regina Santos
Format: Article
Language: eng
Source: Repositório Institucional da UFS
Download full: https://ri.ufs.br/handle/riufs/636
Summary: The reaction of 1-aminoanthraquinone with 7,7',8,8'-tetracyanoquinodimethane yielded the title charge-transfer complex, C14H9NO2·C12H4N4. The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, molecules are stacked into columns along the a-axis direction. Pairs of N-HN and N-HO interactions connect the molecules perpendicular to the stacking direction. Additionally, an intramolecular N-HO hydrogen-bond interaction is observed for 1-aminoanthraquinone.
id UFS-2_d1f8fd47d2cd7d6a604f6741f68c642b
oai_identifier_str oai:ufs.br:riufs/636
network_acronym_str UFS-2
network_name_str Repositório Institucional da UFS
repository_id_str
spelling Oliveira, Adriano Bof deBeck, JohannesDaniels, JörgSantos, Jaciara NascimentoFeitosa, Bárbara Regina Santos2013-07-13T00:12:34Z2013-07-13T00:12:34Z2013-02OLIVEIRA, A. B. et al. The charge-transfer complex 1-aminoanthraquinone-7,7',8,8'-tetracyanoquinodimethane (1/1). Acta Crystallographica Section E, Chester, v. 69, n. 2, p. o301-o301, fev. 2013. Disponível em: <http://journals.iucr.org/e/issues/2013/02/00/bt6884/index.html>. Acesso em: 12 jul. 2013.1600-5368https://ri.ufs.br/handle/riufs/636Creative Commons Attribution LicenceThe reaction of 1-aminoanthraquinone with 7,7',8,8'-tetracyanoquinodimethane yielded the title charge-transfer complex, C14H9NO2·C12H4N4. The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, molecules are stacked into columns along the a-axis direction. Pairs of N-HN and N-HO interactions connect the molecules perpendicular to the stacking direction. Additionally, an intramolecular N-HO hydrogen-bond interaction is observed for 1-aminoanthraquinone.International Union of CrystallographyComplexo de transferência de carga1-AminoanthraquinoneC14H9NO2·C12H4N4.The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTHUMBNAILCharge-TransferComplex.pdf.jpgCharge-TransferComplex.pdf.jpgGenerated Thumbnailimage/jpeg1705https://ri.ufs.br/jspui/bitstream/riufs/636/4/Charge-TransferComplex.pdf.jpg7a1fe3d917ca86259bc01dc528009158MD54ORIGINALCharge-TransferComplex.pdfCharge-TransferComplex.pdfapplication/pdf576276https://ri.ufs.br/jspui/bitstream/riufs/636/1/Charge-TransferComplex.pdfe0f5162aaaae5902c70a74fda29b56bfMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://ri.ufs.br/jspui/bitstream/riufs/636/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTCharge-TransferComplex.pdf.txtCharge-TransferComplex.pdf.txtExtracted texttext/plain22829https://ri.ufs.br/jspui/bitstream/riufs/636/3/Charge-TransferComplex.pdf.txtef0ec91760bae2c487f11729be11a6d9MD53riufs/6362013-07-13 02:00:08.72oai:ufs.br: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Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2013-07-13T05:00:08Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false
dc.title.pt_BR.fl_str_mv The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
title The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
spellingShingle The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
Oliveira, Adriano Bof de
Complexo de transferência de carga
1-Aminoanthraquinone
C14H9NO2·C12H4N4.
title_short The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
title_full The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
title_fullStr The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
title_full_unstemmed The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
title_sort The charge-transfer complex 1-amino-anthraquinone-7,7',8,8'-tetra-cyano-quinodimethane (1/1)
author Oliveira, Adriano Bof de
author_facet Oliveira, Adriano Bof de
Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
author_role author
author2 Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Oliveira, Adriano Bof de
Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
dc.subject.por.fl_str_mv Complexo de transferência de carga
1-Aminoanthraquinone
C14H9NO2·C12H4N4.
topic Complexo de transferência de carga
1-Aminoanthraquinone
C14H9NO2·C12H4N4.
description The reaction of 1-aminoanthraquinone with 7,7',8,8'-tetracyanoquinodimethane yielded the title charge-transfer complex, C14H9NO2·C12H4N4. The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, molecules are stacked into columns along the a-axis direction. Pairs of N-HN and N-HO interactions connect the molecules perpendicular to the stacking direction. Additionally, an intramolecular N-HO hydrogen-bond interaction is observed for 1-aminoanthraquinone.
publishDate 2013
dc.date.accessioned.fl_str_mv 2013-07-13T00:12:34Z
dc.date.available.fl_str_mv 2013-07-13T00:12:34Z
dc.date.issued.fl_str_mv 2013-02
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv OLIVEIRA, A. B. et al. The charge-transfer complex 1-aminoanthraquinone-7,7',8,8'-tetracyanoquinodimethane (1/1). Acta Crystallographica Section E, Chester, v. 69, n. 2, p. o301-o301, fev. 2013. Disponível em: <http://journals.iucr.org/e/issues/2013/02/00/bt6884/index.html>. Acesso em: 12 jul. 2013.
dc.identifier.uri.fl_str_mv https://ri.ufs.br/handle/riufs/636
dc.identifier.issn.none.fl_str_mv 1600-5368
dc.identifier.license.pt_BR.fl_str_mv Creative Commons Attribution Licence
identifier_str_mv OLIVEIRA, A. B. et al. The charge-transfer complex 1-aminoanthraquinone-7,7',8,8'-tetracyanoquinodimethane (1/1). Acta Crystallographica Section E, Chester, v. 69, n. 2, p. o301-o301, fev. 2013. Disponível em: <http://journals.iucr.org/e/issues/2013/02/00/bt6884/index.html>. Acesso em: 12 jul. 2013.
1600-5368
Creative Commons Attribution Licence
url https://ri.ufs.br/handle/riufs/636
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFS
instname:Universidade Federal de Sergipe (UFS)
instacron:UFS
instname_str Universidade Federal de Sergipe (UFS)
instacron_str UFS
institution UFS
reponame_str Repositório Institucional da UFS
collection Repositório Institucional da UFS
bitstream.url.fl_str_mv https://ri.ufs.br/jspui/bitstream/riufs/636/4/Charge-TransferComplex.pdf.jpg
https://ri.ufs.br/jspui/bitstream/riufs/636/1/Charge-TransferComplex.pdf
https://ri.ufs.br/jspui/bitstream/riufs/636/2/license.txt
https://ri.ufs.br/jspui/bitstream/riufs/636/3/Charge-TransferComplex.pdf.txt
bitstream.checksum.fl_str_mv 7a1fe3d917ca86259bc01dc528009158
e0f5162aaaae5902c70a74fda29b56bf
8a4605be74aa9ea9d79846c1fba20a33
ef0ec91760bae2c487f11729be11a6d9
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)
repository.mail.fl_str_mv repositorio@academico.ufs.br
_version_ 1799759332039983104

Similar Items