Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2
Autor(a) principal: | |
---|---|
Data de Publicação: | 2012 |
Tipo de documento: | Tese |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações do UFSM |
Texto Completo: | http://repositorio.ufsm.br/handle/1/4221 |
Resumo: | This work deals with the synthesis and structural analysis of binary and ternary clusters derivatives from mercury bis(phenylselenolate) - Hg(SePh)2. The reaction of Hg(SePh)2 with Mg(II), Fe(II), Co(II) and Ni(II) metal salts led to the formation of a series of binary clusters [M(DPPMO2)3][Hg4X4(SePh)6]·4DMF·H2O and [M(DMF)6][Hg8SeX4(SePh)12]. The reaction of Hg(SePh)2 with Cu(I) phosphine complexes led to the formation of a series of ternary clusters [HgCu2X2(SePh)2(PPh3)4] and [Hg6Cu4(SePh)16]. When Hg(SePh)2 was reacted with Co(II) and Ni(II) thiocyanide complexes, the heterometallic coordination polymers [M(DMF)2(NCS)4(HgSePh)2]n were obtained. Furthermore, the formation of a by-product [Hg3(SePh)5(O2SePh)]n was observed. It is formed by the oxidation of the phenylselenolate ligand. A structural study in the solid state of these compounds was carried out using single crystal X-ray diffraction. Other analytical methodologies such as powder X-ray diffraction, elemental analysis and infrared spectroscopy were also used for the characterization of the compounds. The band gap in the solid state was measured for the obtained clusters compounds through ultraviolet-visible spectroscopy. |
id |
UFSM_58c2fa50e96fa2644b879872aef76b10 |
---|---|
oai_identifier_str |
oai:repositorio.ufsm.br:1/4221 |
network_acronym_str |
UFSM |
network_name_str |
Biblioteca Digital de Teses e Dissertações do UFSM |
repository_id_str |
|
spelling |
2017-05-222017-05-222012-03-30STIELER, Rafael. Synthesis and Structural Analysis of Binary and Ternary Clusters derivatives from Mercury Bis(phenylselenolate) - Hg(SePh)2. 2012. 173 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2012.http://repositorio.ufsm.br/handle/1/4221This work deals with the synthesis and structural analysis of binary and ternary clusters derivatives from mercury bis(phenylselenolate) - Hg(SePh)2. The reaction of Hg(SePh)2 with Mg(II), Fe(II), Co(II) and Ni(II) metal salts led to the formation of a series of binary clusters [M(DPPMO2)3][Hg4X4(SePh)6]·4DMF·H2O and [M(DMF)6][Hg8SeX4(SePh)12]. The reaction of Hg(SePh)2 with Cu(I) phosphine complexes led to the formation of a series of ternary clusters [HgCu2X2(SePh)2(PPh3)4] and [Hg6Cu4(SePh)16]. When Hg(SePh)2 was reacted with Co(II) and Ni(II) thiocyanide complexes, the heterometallic coordination polymers [M(DMF)2(NCS)4(HgSePh)2]n were obtained. Furthermore, the formation of a by-product [Hg3(SePh)5(O2SePh)]n was observed. It is formed by the oxidation of the phenylselenolate ligand. A structural study in the solid state of these compounds was carried out using single crystal X-ray diffraction. Other analytical methodologies such as powder X-ray diffraction, elemental analysis and infrared spectroscopy were also used for the characterization of the compounds. The band gap in the solid state was measured for the obtained clusters compounds through ultraviolet-visible spectroscopy.Este manuscrito apresenta o estudo relacionado à síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio - Hg(SePh)2. A reação de Hg(SePh)2 com sais de metais como Mg(II), Fe(II), Co(II) e Ni(II) levou à formação de uma série de clusters binários [M(DPPMO2)3][Hg4X4(SePh)6]·4DMF·H2O e [M(DMF)6][Hg8SeX4(SePh)12]. A reação de Hg(SePh)2 com fosfino-complexos derivados de Cu(I) levou à formação de uma série de clusters ternários [HgCu2X2(SePh)2(PPh3)4] e [Hg6Cu4(SePh)16]. Quando Hg(SePh)2 foi reagido com tiociano-complexos dos metais de transição Co(II) e Ni(II), foram obtidos os polímeros de coordenação heterometálicos [M(DMF)2(NCS)4(HgSePh)2]n. Observou-se também, ao longo das reações desenvolvidas neste trabalho, a formação do produto secundário [Hg3(SePh)5(O2SePh)]n, originado da oxidação do ligante fenilselenolato. Efetuou-se um estudo estrutural desses compostos no estado sólido, utilizando como ferramenta principal a difração de raios X em monocristal. Outras metodologias de análise como difração de raios X em pó, análise elementar e espectroscopia no infravermelho também foram utilizadas para a caracterização dos compostos. Os clusters obtidos neste trabalho tiveram ainda seu band gap no estado sólido determinado através de espectroscopia no ultravioleta-visível.Conselho Nacional de Desenvolvimento Científico e Tecnológicoapplication/pdfporUniversidade Federal de Santa MariaPrograma de Pós-Graduação em QuímicaUFSMBRQuímicaFenilselenolato de mercúrioDifração de raios XClustersMercury phenylselenolateX-ray diffractionCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICASíntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2Synthesis and structural analysis of binary and ternary clusters derivatives from mercury bis(phenylselenolate) - Hg(SePh)2info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisLang, Ernesto Schulzhttp://lattes.cnpq.br/4481982189769819Bortoluzzi, Adailton Joãohttp://lattes.cnpq.br/6445841478978597Back, Davi Fernandohttp://lattes.cnpq.br/3778138554788107Oliveira, Gelson Noe Manzoni dehttp://lattes.cnpq.br/5103552511601104Giacomelli, Vanessa Schmidthttp://lattes.cnpq.br/0181326876779784http://lattes.cnpq.br/6824260536594075Stieler, Rafael1006000000004003003003003003003000c9d7568-d5c4-466d-b807-0125a7d37b9708683003-3b05-4d5c-8194-bc4d1af2cb7154de7942-f611-4d6f-81b7-f54b7940d6e5f33f5bf0-5193-4fac-992b-192381823da8cdf4f758-2997-4e77-b566-8789f01b4578070561da-7f47-4e71-8a41-6e3759afbf35info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações do UFSMinstname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMORIGINALSTIELER, RAFAEL.pdfapplication/pdf21581362http://repositorio.ufsm.br/bitstream/1/4221/1/STIELER%2c%20RAFAEL.pdfc9c14bdd4604f9238c73862f5e3206efMD51TEXTSTIELER, RAFAEL.pdf.txtSTIELER, RAFAEL.pdf.txtExtracted texttext/plain259245http://repositorio.ufsm.br/bitstream/1/4221/2/STIELER%2c%20RAFAEL.pdf.txt1133afcd9a6c189b63e4a94a1ee43e17MD52THUMBNAILSTIELER, RAFAEL.pdf.jpgSTIELER, RAFAEL.pdf.jpgIM Thumbnailimage/jpeg5054http://repositorio.ufsm.br/bitstream/1/4221/3/STIELER%2c%20RAFAEL.pdf.jpgb3a424fba9bf1d40f27105cf8a41b8c6MD531/42212022-04-12 12:58:32.702oai:repositorio.ufsm.br:1/4221Biblioteca Digital de Teses e Dissertaçõeshttps://repositorio.ufsm.br/ONGhttps://repositorio.ufsm.br/oai/requestatendimento.sib@ufsm.br||tedebc@gmail.comopendoar:2022-04-12T15:58:32Biblioteca Digital de Teses e Dissertações do UFSM - Universidade Federal de Santa Maria (UFSM)false |
dc.title.por.fl_str_mv |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
dc.title.alternative.eng.fl_str_mv |
Synthesis and structural analysis of binary and ternary clusters derivatives from mercury bis(phenylselenolate) - Hg(SePh)2 |
title |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
spellingShingle |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 Stieler, Rafael Fenilselenolato de mercúrio Difração de raios X Clusters Mercury phenylselenolate X-ray diffraction CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
title_full |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
title_fullStr |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
title_full_unstemmed |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
title_sort |
Síntese e análise estrutural de clusters binários e ternários derivados de bis(fenilselenolato) de mercúrio Hg(SePh)2 |
author |
Stieler, Rafael |
author_facet |
Stieler, Rafael |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Lang, Ernesto Schulz |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/4481982189769819 |
dc.contributor.referee1.fl_str_mv |
Bortoluzzi, Adailton João |
dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/6445841478978597 |
dc.contributor.referee2.fl_str_mv |
Back, Davi Fernando |
dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/3778138554788107 |
dc.contributor.referee3.fl_str_mv |
Oliveira, Gelson Noe Manzoni de |
dc.contributor.referee3Lattes.fl_str_mv |
http://lattes.cnpq.br/5103552511601104 |
dc.contributor.referee4.fl_str_mv |
Giacomelli, Vanessa Schmidt |
dc.contributor.referee4Lattes.fl_str_mv |
http://lattes.cnpq.br/0181326876779784 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/6824260536594075 |
dc.contributor.author.fl_str_mv |
Stieler, Rafael |
contributor_str_mv |
Lang, Ernesto Schulz Bortoluzzi, Adailton João Back, Davi Fernando Oliveira, Gelson Noe Manzoni de Giacomelli, Vanessa Schmidt |
dc.subject.por.fl_str_mv |
Fenilselenolato de mercúrio Difração de raios X |
topic |
Fenilselenolato de mercúrio Difração de raios X Clusters Mercury phenylselenolate X-ray diffraction CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Clusters Mercury phenylselenolate X-ray diffraction |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
This work deals with the synthesis and structural analysis of binary and ternary clusters derivatives from mercury bis(phenylselenolate) - Hg(SePh)2. The reaction of Hg(SePh)2 with Mg(II), Fe(II), Co(II) and Ni(II) metal salts led to the formation of a series of binary clusters [M(DPPMO2)3][Hg4X4(SePh)6]·4DMF·H2O and [M(DMF)6][Hg8SeX4(SePh)12]. The reaction of Hg(SePh)2 with Cu(I) phosphine complexes led to the formation of a series of ternary clusters [HgCu2X2(SePh)2(PPh3)4] and [Hg6Cu4(SePh)16]. When Hg(SePh)2 was reacted with Co(II) and Ni(II) thiocyanide complexes, the heterometallic coordination polymers [M(DMF)2(NCS)4(HgSePh)2]n were obtained. Furthermore, the formation of a by-product [Hg3(SePh)5(O2SePh)]n was observed. It is formed by the oxidation of the phenylselenolate ligand. A structural study in the solid state of these compounds was carried out using single crystal X-ray diffraction. Other analytical methodologies such as powder X-ray diffraction, elemental analysis and infrared spectroscopy were also used for the characterization of the compounds. The band gap in the solid state was measured for the obtained clusters compounds through ultraviolet-visible spectroscopy. |
publishDate |
2012 |
dc.date.issued.fl_str_mv |
2012-03-30 |
dc.date.accessioned.fl_str_mv |
2017-05-22 |
dc.date.available.fl_str_mv |
2017-05-22 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
format |
doctoralThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
STIELER, Rafael. Synthesis and Structural Analysis of Binary and Ternary Clusters derivatives from Mercury Bis(phenylselenolate) - Hg(SePh)2. 2012. 173 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2012. |
dc.identifier.uri.fl_str_mv |
http://repositorio.ufsm.br/handle/1/4221 |
identifier_str_mv |
STIELER, Rafael. Synthesis and Structural Analysis of Binary and Ternary Clusters derivatives from Mercury Bis(phenylselenolate) - Hg(SePh)2. 2012. 173 f. Tese (Doutorado em Química) - Universidade Federal de Santa Maria, Santa Maria, 2012. |
url |
http://repositorio.ufsm.br/handle/1/4221 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.cnpq.fl_str_mv |
100600000000 |
dc.relation.confidence.fl_str_mv |
400 300 300 300 300 300 300 |
dc.relation.authority.fl_str_mv |
0c9d7568-d5c4-466d-b807-0125a7d37b97 08683003-3b05-4d5c-8194-bc4d1af2cb71 54de7942-f611-4d6f-81b7-f54b7940d6e5 f33f5bf0-5193-4fac-992b-192381823da8 cdf4f758-2997-4e77-b566-8789f01b4578 070561da-7f47-4e71-8a41-6e3759afbf35 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
dc.publisher.program.fl_str_mv |
Programa de Pós-Graduação em Química |
dc.publisher.initials.fl_str_mv |
UFSM |
dc.publisher.country.fl_str_mv |
BR |
dc.publisher.department.fl_str_mv |
Química |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
dc.source.none.fl_str_mv |
reponame:Biblioteca Digital de Teses e Dissertações do UFSM instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
instname_str |
Universidade Federal de Santa Maria (UFSM) |
instacron_str |
UFSM |
institution |
UFSM |
reponame_str |
Biblioteca Digital de Teses e Dissertações do UFSM |
collection |
Biblioteca Digital de Teses e Dissertações do UFSM |
bitstream.url.fl_str_mv |
http://repositorio.ufsm.br/bitstream/1/4221/1/STIELER%2c%20RAFAEL.pdf http://repositorio.ufsm.br/bitstream/1/4221/2/STIELER%2c%20RAFAEL.pdf.txt http://repositorio.ufsm.br/bitstream/1/4221/3/STIELER%2c%20RAFAEL.pdf.jpg |
bitstream.checksum.fl_str_mv |
c9c14bdd4604f9238c73862f5e3206ef 1133afcd9a6c189b63e4a94a1ee43e17 b3a424fba9bf1d40f27105cf8a41b8c6 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 |
repository.name.fl_str_mv |
Biblioteca Digital de Teses e Dissertações do UFSM - Universidade Federal de Santa Maria (UFSM) |
repository.mail.fl_str_mv |
atendimento.sib@ufsm.br||tedebc@gmail.com |
_version_ |
1791086149641437184 |